公开(公告)号：US06541085B2

公开(公告)日：2003-04-01

申请号：US09923979

申请日：2001-08-07

申请人： Noriyuki Isobe ,  Tetsuji Hirano ,  Kouichiro Kurachi ,  Nobuhiro Ogawa

发明人： Noriyuki Isobe ,  Tetsuji Hirano ,  Kouichiro Kurachi ,  Nobuhiro Ogawa

IPC分类号： B29D2200

CPC分类号： C08K5/0016 ,  C08G69/14 ,  C08G69/16 ,  C08L77/02 ,  H01L21/76819 ,  Y10T428/13 ,  Y10T428/139 ,  Y10T428/2913 ,  Y10T428/2967 ,  Y10T428/2969 ,  C08L23/00

摘要： Disclosed is a member of nylon 12 having a relative viscosity of from 1.9 to 3.5 when measured in 98% sulfuric acid at a concentration of 10 g/dm3 and at 25° C. and a melt flow rate of 0.1 g/10 min. or more when measured at 235° C. under a load of 2,160 g, wherein said relative viscosity and said melt flow rate have a relationship of the following formula (I): 2.87×103 exp (−3.48 &eegr;r)≦MFR≦3.25×104 exp (−3.48 &eegr;r)  (I) wherein &eegr;r is relative viscosity and MFR is melt flow rate. The nylon 12 has excellent extrusion moldability and creep characteristics, fatigue characteristics and the like mechanical properties and is suited for tubular molds. A nylon 12 composition comprising the nylon 12 having the above-described specific relationship between &eegr;r and MFR and a plasticizer is also disclosed.

摘要翻译： 公开了当在98％硫酸中以10g / dm 3的浓度和25℃和0.1g / 10min的熔体流动速率测量时，相对粘度为1.9至3.5的尼龙12的构件。 或更高，其中在235℃下，在2,160克的载荷下测量，其中所述相对粘度和所述熔体流动速率具有下式（I）的关系：其中etar是相对粘度，MFR是熔体流动速率。 尼龙12具有优异的挤出成型性和蠕变特性，疲劳特性等机械性能，适用于管状模具。 还公开了包含具有上述etar和MFR之间的特定关系的尼龙12和增塑剂的尼龙12组合物。

公开(公告)号：US4946887A

公开(公告)日：1990-08-07

申请号：US260109

申请日：1988-10-20

申请人： Hiroshi Takino ,  Satoshi Iwama ,  Riichiro Ohara ,  Noriyuki Isobe ,  Hiroyuki Tobori ,  Makoto Komai

发明人： Hiroshi Takino ,  Satoshi Iwama ,  Riichiro Ohara ,  Noriyuki Isobe ,  Hiroyuki Tobori ,  Makoto Komai

IPC分类号： B60C1/00 ,  C08L9/00

CPC分类号： C08L9/00 ,  B60C1/0016 ,  C08L9/06 ,  Y10S152/905

摘要： A tire tread rubber composition having a two-peak tan.delta. characterized in that the temperature distribution curve for loss tangent (tan.delta.) has two peaks in the range from -120.degree. C. to +100.degree. C. is useful as a tire tread rubber composition.

摘要翻译： 具有双峰tanδ的轮胎胎面橡胶组合物，其特征在于损耗角正切（tanδ）的温度分布曲线在-120℃至+100℃的范围内具有两个峰值，可用作轮胎胎面 橡胶组成。

公开(公告)号：US06294644B1

公开(公告)日：2001-09-25

申请号：US09262225

申请日：1999-03-04

申请人： Noriyuki Isobe ,  Tetsuji Hirano ,  Kouichiro Kurachi ,  Nobuhiro Ogawa

发明人： Noriyuki Isobe ,  Tetsuji Hirano ,  Kouichiro Kurachi ,  Nobuhiro Ogawa

IPC分类号： C08G6928

CPC分类号： C08K5/0016 ,  C08G69/14 ,  C08G69/16 ,  C08L77/02 ,  H01L21/76819 ,  Y10T428/13 ,  Y10T428/139 ,  Y10T428/2913 ,  Y10T428/2967 ,  Y10T428/2969 ,  C08L23/00

摘要： Disclosed is a member of nylon 12 having a relative viscosity of from 1.9 to 3.5 when measured in 98% sulfuric acid at a concentration of 10 g/dm3 and at 25° C. and a melt flow rate of 0.1 g/10 min. or more when measured at 235° C. under a load of 2,160 g, wherein said relative viscosity and said melt flow rate have a relationship of the following formula (I): 2.87×103 exp (−3.48 &eegr;r)≦MFR≦3.25×104 exp (−3.48 &eegr;r)  (I) wherein &eegr;r is relative viscosity and MFR is melt flow rate. The nylon 12 has excellent extrusion moldability and creep characteristics, fatigue characteristics and the like mechanical properties and is suited for tubular molds. A nylon 12 composition comprising the nylon 12 having the above-described specific relationship between &eegr;r and MFR and a plasticizer is also disclosed.

摘要翻译： 公开了当在98％硫酸中以10g / dm 3的浓度和25℃和0.1g / 10min的熔体流动速率测量时，相对粘度为1.9至3.5的尼龙12的构件。 或更高，其中在235℃下，在2,160克的载荷下测量，其中所述相对粘度和所述熔体流动速率具有下式（I）的关系：其中etar是相对粘度，MFR是熔体流动速率。 尼龙12具有优异的挤出成型性和蠕变特性，疲劳特性等机械性能，适用于管状模具。 还公开了包含具有上述etar和MFR之间的特定关系的尼龙12和增塑剂的尼龙12组合物。

公开(公告)号：US5789529A

公开(公告)日：1998-08-04

申请号：US660583

申请日：1996-06-11

申请人： Takenobu Matsumura ,  Noriyuki Isobe ,  Kanzou Tabata ,  Satoshi Kotera

发明人： Takenobu Matsumura ,  Noriyuki Isobe ,  Kanzou Tabata ,  Satoshi Kotera

IPC分类号： C08K5/00 ,  C08L77/02 ,  C08K69/08 ,  C08L77/00

CPC分类号： C08K5/0016 ,  C08L77/02

摘要： A polyamide resin composition comprising: (A) 100 parts by weight of at least one member selected from a polyamide-11 resin and a polyamide-12 resin; optionally (B) from 3 to 30 parts by weight of a modified polyolefin resin; and (C) from 3 to 25 parts by weight of a plasticizer mixture comprising a plasticizer (C1) and a plasticizer (C2). The modified polyolefin resin (B) is either a modified polyolefin (B1) which is a copolymer of an olefin comprising at least one of ethylene and propylene, with an .alpha.,.beta.-unsaturated carboxylic acid or a derivative thereof, or a modified polyolefin (B2) which is a graft polymer obtained by grafting an .alpha.,.beta.-unsaturated carboxylic acid or a derivative thereof onto a copolymer of an olefin comprising at least one of ethylene and propylene. The plasticizer (C1) has a solidifying point of -40.degree. C. or lower and is at least one member selected from the group consisting of phthalic esters, fatty acid esters, polyhydric alcohol esters, phosphoric esters, trimellitic esters, and epoxy plasticizers, and the plasticizer (C2) is at least one member selected from the group consisting of benzenesulfonic acid alkylamides, toluenesulfonic acid alkylamides, and alkyl hydroxybenzoates.

摘要翻译： 一种聚酰胺树脂组合物，其包含：（A）100重量份选自聚酰胺-11树脂和聚酰胺-12树脂中的至少一种; 任选地（B）3至30重量份的改性聚烯烃树脂; 和（C）3至25重量份的包含增塑剂（C1）和增塑剂（C2）的增塑剂混合物。 改性聚烯烃树脂（B）是改性聚烯烃（B1），其是包含乙烯和丙烯中的至少一种的烯烃与α，β-不饱和羧酸或其衍生物或改性聚烯烃（ B2），其是通过将α，β-不饱和羧酸或其衍生物接枝到包含至少一种乙烯和丙烯的烯烃的共聚物上获得的接枝聚合物。 增塑剂（C1）的固化点为-40℃以下，为选自邻苯二甲酸酯，脂肪酸酯，多元醇酯，磷酸酯，偏苯三酸酯，环氧增塑剂中的至少一种， 并且增塑剂（C2）是选自苯磺酸烷基酰胺，甲苯磺酸烷基酰胺和羟基苯甲酸烷基酯中的至少一种。

公开(公告)号：US4929507A

公开(公告)日：1990-05-29

申请号：US172962

申请日：1988-03-23

申请人： Yoshio Nishihara ,  Noriyuki Isobe ,  Satoshi Kotera

发明人： Yoshio Nishihara ,  Noriyuki Isobe ,  Satoshi Kotera

IPC分类号： C09D183/16

CPC分类号： C09D183/16 ,  Y10T428/31663

摘要： A heat-resistant paint comprising a dispersion or solution of a polymetallocarbosilane and an inorganic filler in an organic solvent,wherein said polymetallocarbosilane is an organometallic polymer having a number average molecular weight of 400 to 50,000 comprising(A) carbosilane bond units of the formula ##STR1## wherein R.sub.1 and R.sub.2 may be identical or different and each represents a lower alkyl group, phenyl group or a hydrogen atom, and(B) metalloxane bond units of the formula(M--O) wherein M represents at least one element selected from the group consisting of Ti, Zr, Cr and Mo,wherein said inorganic filler is at least one material selected from the group consisting of oxides, borates, phosphates, silicates, silicides, borides, nitrides and carbides; andwherein said inorganic filler is present in an amount of 10 to 900 parts by weight per 100 parts by weight of said polymetallocarbosilane.

摘要翻译： 1.一种耐热涂料，其特征在于，在有机溶剂中含有多元羧酸硅烷和无机填充剂的分散液或溶液，其中所述聚碳硅烷是数均分子量为400〜500的有机金属聚合物，其包含式（A） 其中R 1和R 2可以相同或不同，并且各自表示低级烷基，苯基或氢原子，和（B）式（MO）的金属氧化物键单元，其中M表示选自下列基团中的至少一种元素 由Ti，Zr，Cr和Mo组成，其中所述无机填料是选自氧化物，硼酸盐，磷酸盐，硅酸盐，硅化物，硼化物，氮化物和碳化物中的至少一种材料; 并且其中所述无机填料的存在量为每100重量份所述聚碳酸氢硅烷10至900重量份。

公开(公告)号：US06855787B2

公开(公告)日：2005-02-15

申请号：US10617663

申请日：2003-07-14

申请人： Atsushi Funaki ,  Naoko Sumi ,  Eiichi Nishi ,  Noriyuki Isobe ,  Tomoharu Nishioka ,  Koji Nakamura

发明人： Atsushi Funaki ,  Naoko Sumi ,  Eiichi Nishi ,  Noriyuki Isobe ,  Tomoharu Nishioka ,  Koji Nakamura

IPC分类号： B60K15/01 ,  B32B1/08 ,  B32B27/28 ,  B32B27/30 ,  B32B27/34 ,  C08F259/08 ,  C08L51/00 ,  F16L11/04 ,  F16L11/11 ,  F16L11/127 ,  F16L11/15 ,  C08F214/18 ,  B29D22/00

CPC分类号： B32B1/08 ,  B32B27/08 ,  B32B27/28 ,  B32B27/34 ,  B32B2270/00 ,  B32B2323/043 ,  B32B2323/046 ,  B32B2367/00 ,  B32B2398/20 ,  B32B2597/00 ,  C08F259/08 ,  C08L51/003 ,  F16L11/127 ,  F16L11/15 ,  Y10T428/1317 ,  Y10T428/139 ,  Y10T428/1393 ,  C08L2666/02

摘要： A multi-layer hose having a multi-layer structure comprising an inner layer (I) made of a fluorocopolymer and an outer layer (II) made of a polyamide resin, wherein the fluorocopolymer constituting the inner layer (I) is a fluorocopolymer which comprises polymerized units (a) based on tetrafluoroethylene, polymerized units (b) based on ethylene and polymerized units (c) based on itaconic anhydride and/or citraconic anhydride, wherein the molar ratio of (a)/(b) is from 20/80 to 80/20 and the molar ratio of (c)/((a)+(b)) is from 1/10,000 to 5/100 and which has a volume flow rate of from 1 to 1,000 mm3/sec., and the polyamide resin constituting the outer layer (II) is polyamide 11 and/or polyamide 12, which satisfies a condition of (terminal amino group concentration)/(terminal carboxyl group concentration)>1.

摘要翻译： 一种具有多层结构的多层软管，包括由含氟共聚物制成的内层（I）和由聚酰胺树脂制成的外层（II），其中构成内层（I）的含氟共聚物是含氟共聚物，其包含 基于四氟乙烯的聚合单元（a），基于乙烯的聚合单元（b）和基于衣康酸酐和/或柠康酸酐的聚合单元（c），其中（a）/（b）的摩尔比为20/80 至80/20，（c）/（（a）+（b））的摩尔比为1 / 10,000〜5/100，体积流量为1〜1000mm 3 / sec。 构成外层（II）的聚酰胺树脂是满足（末端氨基浓度）/（末端羧基浓度）> 1的条件的聚酰胺11和/或聚酰胺12。

公开(公告)号：US06656553B2

公开(公告)日：2003-12-02

申请号：US10265328

申请日：2002-10-07

申请人： Eiichi Nishi ,  Masako Nagashima ,  Noriyuki Isobe ,  Tomoharu Nishioka ,  Yoshiro Iwata

发明人： Eiichi Nishi ,  Masako Nagashima ,  Noriyuki Isobe ,  Tomoharu Nishioka ,  Yoshiro Iwata

IPC分类号： B32B108

CPC分类号： B32B27/08 ,  B29C47/0023 ,  B29C47/065 ,  B29C47/26 ,  B32B1/08 ,  B32B27/32 ,  B32B27/34 ,  F16L11/04 ,  F16L2011/047 ,  Y10T428/1352 ,  Y10T428/1393 ,  Y10T428/31725 ,  Y10T428/3175

摘要： A hose for fuel having a laminated structure comprising an inner layer (A) made of a ethylene/tetrafluoroethylene copolymer adhesive to a polyamide resin and an outer layer (B) made of a polyamide resin, is formed. Such a hose for fuel is excellent in interlaminar adhesive strength and also excellent in antistatic properties and fuel permeation-preventing properties, and particularly, the dependency of the interlaminar adhesive strength on the take-up speed during the co-extrusion molding, is small.

摘要翻译： 一种具有层叠结构的燃料用软管，其特征在于，包括由聚酰胺树脂的乙烯/四氟乙烯共聚物粘合剂构成的内层（A）和由聚酰胺树脂构成的外层（B）。 这种用于燃料的软管在层间粘合强度方面是优异的，并且还具有优异的抗静电特性和防止燃料渗透的性能，特别是在共挤出成型期间，层间粘合强度对卷取速度的依赖性很小。

公开(公告)号：US4908401A

公开(公告)日：1990-03-13

申请号：US287257

申请日：1988-12-21

申请人： Riichiro Ohara ,  Satoshi Iwama ,  Eiji Ida ,  Noriyuki Isobe

发明人： Riichiro Ohara ,  Satoshi Iwama ,  Eiji Ida ,  Noriyuki Isobe

IPC分类号： B60C1/00 ,  C08K3/04 ,  C08L9/06 ,  C08L21/00 ,  C08L23/00 ,  C08L51/00 ,  C08L51/02 ,  C08L53/02 ,  C08L77/00 ,  C08L101/00 ,  C09C1/50

CPC分类号： C08L9/06 ,  B60C1/0016 ,  C08K3/04 ,  C08L21/00 ,  C08L53/02 ,  C08L53/025 ,  C09C1/50 ,  C01P2006/12 ,  C01P2006/19 ,  C01P2006/60 ,  C08L7/00 ,  C08L9/00

摘要： A rubber composition comprising 40 to 100 parts by weight of carbon black per 100 parts by weight of a rubber component,(a) the rubber composition being characterized in that the rubber component contains, in 100 parts by weight thereof, at least 20 parts by weight of a block copolymer prepared by solution polymerization and comprising one unit of butadiene rubber portion and one unit of random-copolymerized styrene-butadiene rubber portion, the butadiene rubber portion having a vinyl content of 15 to 50%, the styrene-butadiene rubber portion having a vinyl content of 20 to 70% and a styrene content of 30 to 60%, the block copolymer having in its entirety a vinyl content of 15 to 60% and a styrene content of 5 to 30% at least 40% of the copolymer being coupled with a tin compound so that the coupled copolymer has a butadiene rubber terminal, the coupled copolymer having only a single Tg at a temperature of up to -60.degree. C.,0 to 80 parts by weight of natural rubber, synthetic polyisoprene rubber, synthetic polybutadiene rubber, synthetic styrene-butadiene rubber, modified products of thers rubbers, or mixtures thereof;(b) the rubber composition being further characterized in that the carbon black has a specific surface area value (N.sub.2 SA) withinthe range of 75 ot 105 as determiend by the nitrogen adsorption method and is at least 15 in the difference between N.sub.2 SA and the iodine adsorption value (IA) thereof, up to 5 in the difference between N.sub.2 SA and the specific surface area valve (CTAB) thereof as determined by the cetyltrimethylammonium bromide adsorption method, 90 to 110 in tint strength and up to -3 in the measured tint strength minus the calculated tint stength (.DELTA.tint).

摘要翻译： 一种橡胶组合物，其包含每100重量份橡胶组分40至100重量份的炭黑，（a）所述橡胶组合物的特征在于，所述橡胶组分在100重量份中包含至少20重量份 通过溶液聚合制备的嵌段共聚物的重量，包含一个单元的丁二烯橡胶部分和一个单位的无规共聚苯乙烯 - 丁二烯橡胶部分，丁二烯橡胶部分的乙烯基含量为15-50％，丁苯橡胶部分 乙烯基含量为20〜70％，苯乙烯含量为30〜60％，嵌段共聚物全部为乙烯基含量为15〜60％，苯乙烯含量为5〜30％，共聚物的至少40％ 与锡化合物偶联，使得偶联共聚物具有丁二烯橡胶末端，偶联共聚物在至多-60℃的温度下仅具有单一Tg，0至80重量份的天然橡胶，合成聚异氰酸酯 铑橡胶，合成聚丁二烯橡胶，合成苯乙烯 - 丁二烯橡胶，其他橡胶的改性产物，或其混合物; （b）所述橡胶组合物的特征还在于，所述炭黑具有在75°105范围内的比表面积值（N2SA），通过氮吸附法测定，并且在N2SA与碘吸附之间的差异中至少为15 值（IA），通过十六烷基三甲基溴化铵吸附法测定的N2SA与比表面积阀（CTAB）之间的差异最多为5，色调强度为90至110，测得的色调强度减至-3 计算出的色调长度（DELTA色调）。

公开(公告)号：US4808659A

公开(公告)日：1989-02-28

申请号：US939058

申请日：1986-12-08

申请人： Yoshio Nishihara ,  Noriyuki Isobe ,  Satoshi Kotera

发明人： Yoshio Nishihara ,  Noriyuki Isobe ,  Satoshi Kotera

IPC分类号： C09J183/04 ,  C09J183/16 ,  C08J3/02 ,  C08G77/04

CPC分类号： C09J183/04 ,  C09J183/16

摘要： An adhesive composition comprising (1) a polymetallocarbosilane or a polycarbosilane and (2) a silicone resin. The adhesive composition further comprises an inorganic filler.

摘要翻译： 一种粘合剂组合物，其包含（1）多元羧酸硅烷或聚碳硅烷和（2）有机硅树脂。 粘合剂组合物还包含无机填料。

公开(公告)号：US06538099B2

公开(公告)日：2003-03-25

申请号：US09923970

申请日：2001-08-07

申请人： Noriyuki Isobe ,  Tetsuji Hirano ,  Kouichiro Kurachi ,  Nobuhiro Ogawa

发明人： Noriyuki Isobe ,  Tetsuji Hirano ,  Kouichiro Kurachi ,  Nobuhiro Ogawa

IPC分类号： C08G7300

CPC分类号： C08K5/0016 ,  C08G69/14 ,  C08G69/16 ,  C08L77/02 ,  H01L21/76819 ,  Y10T428/13 ,  Y10T428/139 ,  Y10T428/2913 ,  Y10T428/2967 ,  Y10T428/2969 ,  C08L23/00

摘要： Disclosed is a member of nylon 12 having a relative viscosity of from 1.9 to 3.5 when measured in 98% sulfuric acid at a concentration of 10 g/dm3 and at 25° C. and a melt flow rate of 0.1 g/10 min. or more when measured at 235° C. under a load of 2,160 g, wherein said relative viscosity and said melt flow rate have a relationship of the following formula (I): 2.87×103 exp(−3.48 &eegr;r)≦MFR≦3.25×104 exp(−3.48 &eegr;r)  (I) wherein &eegr;r is relative viscosity and MFR is melt flow rate. The nylon 12 has excellent extrusion moldability and creep characteristics, fatigue characteristics and the like mechanical properties and is suited for tubular molds. A nylon 12 composition comprising the nylon 12 having the above-described specific relationship between &eegr;r and MFR and a plasticizer is also disclosed.

摘要翻译： 公开了当在98％硫酸中以10g / dm 3的浓度和25℃和0.1g / 10min的熔体流动速率测量时，相对粘度为1.9至3.5的尼龙12的构件。 或更高，其中在235℃下，在2,160克的载荷下测量，其中所述相对粘度和所述熔体流动速率具有下式（I）的关系：其中etar是相对粘度，MFR是熔体流动速率。 尼龙12具有优异的挤出成型性和蠕变特性，疲劳特性等机械性能，适用于管状模具。 还公开了包含具有上述etar和MFR之间的特定关系的尼龙12和增塑剂的尼龙12组合物。