Methods for the production of sulfurized diphenyloxides and compositions made therefrom
    1.
    发明授权
    Methods for the production of sulfurized diphenyloxides and compositions made therefrom 失效
    生产硫化二苯醚及其制备的组合物的方法

    公开(公告)号:US06444623B1

    公开(公告)日:2002-09-03

    申请号:US09473556

    申请日:1999-12-29

    IPC分类号: C10M11102

    摘要: The present invention relates to methods for production of sulfurized diphenyloxides wherein a diphenyloxide is reacted with elemental sulfur in the presence of solid acid catalyst. The solid acid catalyst can be a zeolite or a catalytic amount of a Friedel-Crafts compound. The present invention further relates to a composition containing between about 40 and about 80 weight percent diphenyloxide; no more than about 15 weight percent diphenyloxide thiol; between about 5 and about 45 weight percent phenoxathiin; and between about 3 and about 50 weight percent total of bis(diphenyloxide) sulfide, diphenyloxide phenoxathiin sulfide, and bis(phenoxathiin) sulfide.

    摘要翻译: 本发明涉及在固体酸催化剂存在下使二苯醚与元素硫反应生产硫化二苯醚的方法。 固体酸催化剂可以是沸石或催化量的Friedel-Crafts化合物。 本发明还涉及含有约40至约80重量%二苯醚的组合物; 不超过约15重量%的二苯醚硫醇; 约5至约45重量%的吩霉素; 和双(二苯醚)硫化物,二苯氧基苯硫硫脲硫化物和双(苯氧硫杂)硫化物的总计约3至约50重量%。

    Preparation of alkylated diphenyl oxides
    4.
    发明授权
    Preparation of alkylated diphenyl oxides 失效
    烷基化二苯醚的制备

    公开(公告)号:US06407292B1

    公开(公告)日:2002-06-18

    申请号:US09474354

    申请日:1999-12-29

    IPC分类号: C07C4105

    CPC分类号: C07C43/30

    摘要: A continuous process for the manufacture of alkylated diphenyl compounds such as diphenyl ether and diphenyl sulfides by alkylating a diphenyl compound such as diphenyl ether with an olefinic alkylating agent by passing a continuous flow of the diphenyl compound and the olefin over a solid particulate catalyst which comprises a molecular sieve of the MCM-22 family. The process is flexible. By adjusting feed compositions, products of different compositions and wide range of properties are produced.

    摘要翻译: 通过使连续流动的二苯基化合物和烯烃在固体颗粒催化剂上使烷基化二苯基化合物如二苯醚和二苯基硫化物通过烯烃烷基化剂烷基化二苯基化合物的连续方法,所述固体颗粒催化剂包含 MCM-22家族的分子筛。 这个过程很灵活。 通过调整饲料组成,生产不同成分的产品和广泛的性能。

    Production of high octane gasoline
    8.
    发明授权
    Production of high octane gasoline 失效
    生产高辛烷值汽油

    公开(公告)号:US4828677A

    公开(公告)日:1989-05-09

    申请号:US115309

    申请日:1987-11-02

    IPC分类号: C10G47/16 C10G65/12 C10G69/02

    CPC分类号: C10G65/12 C10G47/16 C10G69/02

    摘要: A moderate pressure hydrocracking process in which a highly aromatic, substantially dealkylated feedstock is processed directly to high octane gasoline by hydrocracking over a monofunctional acidic cracking catalyst, preferably comprising a large pore size, crystalline alumino-silicate zeolite hydrocracking catalyst such as zeolite Y. The feedstock which is preferably a light cycle oil obtained from catalytic cracking with an aromatic content of at least 50, usually at least 60 percent and an API gravity not more than 25. The hydrocracking typically operates at 600-1000 psig at moderate to high conversion levels to mazimize the production of monocyclic aromatics which provide the requiste octane value to the product gasoline.

    摘要翻译: 中等压力加氢裂化方法,其中高度芳族的,基本上脱烷基化的原料通过在优选包含大孔径的结晶铝硅酸盐沸石加氢裂化催化剂如沸石Y的单官能酸性裂化催化剂上加氢裂化直接加工成高辛烷值汽油。 原料,其优选是由芳烃含量为至少50,通常至少为60%,API重量不超过25的催化裂化获得的轻循环油。加氢裂化通常以中等至高转化率的600-1000psig操作 使生产的单环芳族化合物,为产品汽油提供必需的辛烷值。

    Crude oil upgrading process
    9.
    发明授权
    Crude oil upgrading process 失效
    原油升级过程

    公开(公告)号:US4784746A

    公开(公告)日:1988-11-15

    申请号:US41188

    申请日:1987-04-22

    IPC分类号: C10G9/00

    CPC分类号: C10G9/00

    摘要: A crude oil is upgraded by thermal treatment at a temperature of at least 400.degree. C. under at least autogenous pressure and preferably from 100 to 1000 psig for about 20 to 30 minutes in order to increase the proportion of distillable components in the crude. The improvement is attributed to alkylation of lower molecular weight components, especially aromatics, by alkyl groups derived from the high boiling component of the crude. The process reduces the nondistillable residue and enables subsequent processing to be carried out with lower gas and coke make. The process may be operated with a whole crude or a topped crude as feed.

    摘要翻译: 原油通过在至少400℃的温度下至少自生压力,优选100至1000psig的温度下升级约20至30分钟来升级,以增加粗品中可馏出组分的比例。 改进归因于通过衍生自粗品的高沸点组分的烷基将低分子量组分,特别是芳族化合物烷基化。 该方法减少了不可补充的残留物,并且可以用较低的气体和焦炭进行后续处理。 该方法可以以整个原油或顶部原油作为进料进行操作。