摘要:
A moderate pressure hydrocracking process in which a highly aromatic, substantially dealkylated feedstock having a boiling point in the range between 300.degree. and 650.degree. F. is processed directly to high octane gasoline by hydrocracking over a catalyst, preferably comprising a large pore size, crystalline alumino-silicate zeolite hydrocracking catalyst such as zeolite Y together with a hydrogenation-dehydrogenation component. The feedstock which is preferably a light cut light cycle oil has an aromatic content of at least 50, usually at least 60 percent and an API gravity not more than 25. The hydrocracking typically operates at 600-1000 psig at moderate to high conversion levels to maximize the production of monocyclic aromatics which provide the requisite octane value to the product gasoline.
摘要:
A moderate pressure hydrocracking process in which a highly aromatic, substantially dealkylated feedstock having a boiling point in the range between 300.degree. and 650.degree. F. is processed directly to high octane gasoline by hydrocracking over a catalyst, preferably comprising a large pore size, crystalline alumino-silicate zeolite hydrocracking catalyst such as zeolite Y together with a hydrogenation-dehydrogenation component. The feedstock which is preferably a light cut light cycle oil has an aromatic content of at least 50, usually at least 60 percent and an API gravity not more than 25. The hydrocracking typically operates at 600-1000 psig at moderate to high conversion levels to maximize the production of monocyclic aromatics which provide the requisite octane value to the product gasoline.
摘要:
A moderate pressure hydrocracking process in which a highly aromatic, substantially dealkylated feedstock having a boiling point in the range between 300.degree. and 650.degree. F. is processed directly to high octane gasoline by hydrocracking over a catalyst, preferably comprising a large pore size, crystalline alumino-silicate zeolite hydrocracking catalyst such as zeolite Y together with a hydrogenation-dehydrogenation component. The feedstock which is preferably a light cut light cycle oil has an aromatic content of at least 50, usually at least 60 percent and an API gravity not more than 25. The hydrocracking typically operates at 600-1000 psig at moderate to high conversion levels to maximize the production of monocyclic aromatics which provide the requisite octane value to the product gasoline.
摘要:
A moderate pressure hydrocracking process in which a highly aromatic, substantially dealkylated feedstock is processed directly to high octane gasoline by hydrocracking over a monofunctional acidic cracking catalyst, preferably comprising a large pore size, crystalline alumino-silicate zeolite hydrocracking catalyst such as zeolite Y. The feedstock which is preferably a light cycle oil obtained from catalytic cracking with an aromatic content of at least 50, usually at least 60 percent and an API gravity not more than 25. The hydrocracking typically operates at 600-1000 psig at moderate to high conversion levels to mazimize the production of monocyclic aromatics which provide the requiste octane value to the product gasoline.
摘要:
A moderate pressure hydrocracking process is disclosed in which substantially dealkylated heavy distillate feedstocks are processed directly to high octane gasoline over a catalyst, preferably comprising a crystalline silicate zeolite hydrocracking component having a Constraint Index less than 2. The bottoms fraction produced from the contacting may be passed to an FCC unit for further processing. In another embodiment, the substantially dealkylated heavy distillate feedstock may be fractionated into a lighter boiling stream and a heavier boiling stream for better ease of processing.
摘要:
A moderate pressure hydrocracking process in which a highly aromatic, substantially dealkylated feedstock is processed directly to high octane gasoline by hydrocracking over a catalyst, preferably comprising a large pore size, crystalline alumino-silicate zeolite hydrocracking catalyst such as zeolite Y together with a hydrogenation-dehydrogenation component. The feedstock which is preferably a light cycle oil has an aromatic content of at least 50, usually at least 60 percent and an API gravity not more than 25. The hydrocracking typically operates at 600-1000 psig at moderate to high conversion leavels to maximize the production of monocyclic aromatics which provide the requisite octane value to the product gasoline. The unconverted products from the hydrocracker are recyclied to the catalytic cracking unit to obtain further improvements in gasoline yield and octane.
摘要:
An improved process is described for converting propane to more valuable hydrocarbons such as butanes and C.sub.5.sup.+ aliphatics over an acidic catalyst having the structure of ZSM-5 by adding a mono- olefin to the propane feed.
摘要:
The present invention relates to methods for production of sulfurized diphenyloxides wherein a diphenyloxide is reacted with elemental sulfur in the presence of solid acid catalyst. The solid acid catalyst can be a zeolite or a catalytic amount of a Friedel-Crafts compound. The present invention further relates to a composition containing between about 40 and about 80 weight percent diphenyloxide; no more than about 15 weight percent diphenyloxide thiol; between about 5 and about 45 weight percent phenoxathiin; and between about 3 and about 50 weight percent total of bis(diphenyloxide) sulfide, diphenyloxide phenoxathiin sulfide, and bis(phenoxathiin) sulfide.
摘要:
A hydrocracking process in which improved selectivity for the production of distillate range (165.degree. C.-343.degree. C.) products is obtained by the use of a catalyst containing a highly siliceous large pore zeolite as the acidic component. Suitable zeolites include zeolites, Y, ZSM-20 and beta with structural silica:alumina ratios of at least 50:1.
摘要:
The present invention provides a method and system for efficiently producing hydrogen that can be supplied to a fuel cell. The method and system of the present invention produces hydrogen in a reforming reactor using a hydrocarbon stream and water vapor stream as reactants. The hydrogen produced is purified in a hydrogen separating membrane to form a retentate stream and purified hydrogen stream. The purified hydrogen can then be fed to a fuel cell where electrical energy is produced and a fuel cell exhaust stream containing water vapor and oxygen depleted air is emitted. In one embodiment of the present invention, a means and method is provided for recycling a portion of the retentate stream to the reforming reactor for increased hydrogen yields. In another embodiment, a combustor is provided for combusting a second portion of the retentate stream to provide heat to the reforming reaction or other reactants. In a preferred embodiment, the combustion is carried out in the presence of at least a portion of the oxygen depleted air stream from the fuel cell. Thus, the system and method of the present invention advantageously uses products generated from the system to enhance the overall efficiency of the system.