摘要:
A process is disclosed for rendering shaped aramid and polybenzimidazole articles water repellent by grafting fluorinated compounds to the surface of the articles. The resulting grafted polymer and shaped articles made from the grafted polymer are also disclosed.
摘要:
A process for preparing shaped articles of manufacture such as fibers, films and coatings from aromatic polyamide anions in liquid sulfoxides; anisotropic solutions of aromatic polyamide anions useful for the preparation of shaped articles having anistropic properties; isotropic solutions comprising the potassium salt of the polyamide anion; and methods for regulating solution viscosity by control of the degree to which the aromatic polyamide anions are deprotonated.
摘要:
Novel catalysts for polyester production by esterification and/or transesterification are MoS.sub.2 or WS.sub.2 which have been intercalated by alkali metals cations, especially lithium cations, and then contacted with an alcohol or a polyol, a preferred polyol being a glycol which is one of the monomeric units in the polyester produced.
摘要:
Quaternary ammonium polyarylamides are provided that are useful in articles of manufacture that require minimal ionic impurities. The polyarylamides are produced by reacting certain polyamides together with quaternary ammonium bases of the formula R.sup.4.sub.4 N.sup.+ X.sup.-, wherein each R.sup.4 is independently selected from hydrocarbyl or substituted hydrocarbyl, provided that at least one of the R.sup.4 groups contains at least one beta hydrogen atom. There is also provided the process for producing the polyarylamides, the process for making articles of manufacture from the polyarylamides, and a process for modifying the surfaces of such polyamides.
摘要:
A method is disclosed for metallizing polymers comprising generating anionic sites on the structures, contacting same with the cation of the metal and then reducing the metal cation to metal at the anionic sites or treating the metal cations to form a semiconductor. The metallized polymers are useful as electrical conductors or semiconductors.
摘要:
Conductive fibers of a combination of aramid and polyvinyl pyrrolidone (PVP) are disclosed having a strongly bonded metal coating applied by electroless plating. PVP increases adhesion of the fiber surface to the electroless plating. The preferred aramid is poly(p-phenylene terephthalamide).
摘要:
Quaternary ammonium polyarylamides are provided that are useful in articles of manufacture that require minimal ionic impurities. The polyarylamides are produced by reacting certain polyamides together with quaternary ammonium bases of the formula R.sup.4.sub.4 N.sup.+ X.sup.-, wherein each R.sup.4 is independently selected from hydrocarbyl or substituted hydrocarbyl, provided that at least one of the R.sup.4 groups contains at least one beta hydrogen atom. There is also provided the process for producing the polyarylamides, the process for making articles of manufacture from the polyarylamides, and a process for modifying the surfaces of such polyamides.
摘要:
Disclosed herein is a process for the production of polyester which involves heating a polymerizable monomer or oligomer in an inert liquid which does not dissolve or swell the monomer, oligomer, or polyester product, while boiling the inert liquid and codistilling the low molecular weight byproduct of the polymerization.
摘要:
A method is disclosed for metallizing polymers comprising generating anionic sites on the structures, contacting same with the cation of the metal and then reducing the metal cation to metal at the anionic sites or treating the metal cations to form a semiconductor. The metallized polymers are useful as electrical conductors or semiconductors.
摘要:
A new polypropylene terephthalate composition is provided. The polypropylene terephthalate is comprised of 1,3-propanediol and terephthalate. The 1,3-propanediol is produced by the bioconversion of a fermentatble carbon source, preferable glucose. The resulting polypropylene terephthalate is distinguished from petrochemically produced polymer on the basis of dual carbon-isotopic fingerprinting which indicates both the source and the age of the carbon.