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    Solid polyurethane elastomers which exhibit reduced dimensional shrinkage
    1.
    发明授权
    Solid polyurethane elastomers which exhibit reduced dimensional shrinkage 失效
    固体聚氨酯弹性体的尺寸收缩率降低

    公开(公告)号：US08188208B2

    公开(公告)日：2012-05-29

    申请号：US11035591

    申请日：2005-01-13

    申请人： Stephen J. Harasin ,  William D. Keller, Jr.

    发明人： Stephen J. Harasin ,  William D. Keller, Jr.

    IPC分类号： C08G18/28

    CPC分类号： C08G18/4841 ,  C08G18/10 ,  C08G2120/00 ,  C08G18/6685

    摘要： This invention relates to solid elastomers which exhibit reduced dimensional shrinkage, and to a process for the production of these elastomers. These elastomers comprise the reaction product of a polyisocyanate component or prepolymer, with an isocyanate-reactive component comprising a high molecular weight component having an EO cap having less than 17% by wt., a chain extender and optionally, a crosslinker, in the presence of at least one catalysts. These solid elastomers are produced via the reaction injection molding process in a closed mold, preferably at an isocyanate index of about 70 to about 130.

    摘要翻译： 本发明涉及显示出减小的尺寸收缩率的固体弹性体以及生产这些弹性体的方法。 这些弹性体包括多异氰酸酯组分或预聚物与异氰酸酯反应性组分的反应产物，其包含具有小于17重量％的EO盖的高分子量组分，扩链剂和任选的交联剂， 的至少一种催化剂。 这些固体弹性体通过在闭合模具中的反应注射成型方法制备，优选异氰酸酯指数为约70至约130。

    Process for the production of molded products using internal mold release agents
    3.
    发明授权
    Process for the production of molded products using internal mold release agents 失效

    公开(公告)号：US4868224A

    公开(公告)日：1989-09-19

    申请号：US260650

    申请日：1988-10-21

    申请人： Stephen J. Harasin ,  Michael F. Hurley ,  Timothy J. Kelly ,  Kenneth J. Naleppa ,  Neil H. Nodelman ,  Donald W. Schumacher ,  Gregory H. Slocum ,  David F. Sounik

    发明人： Stephen J. Harasin ,  Michael F. Hurley ,  Timothy J. Kelly ,  Kenneth J. Naleppa ,  Neil H. Nodelman ,  Donald W. Schumacher ,  Gregory H. Slocum ,  David F. Sounik

    IPC分类号： C08G18/50 ,  C08G18/80 ,  C08K5/098

    CPC分类号： C08G18/8051 ,  C08G18/5024 ,  C08K5/098

    摘要： The present invention is directed to a process for producing a molded product comprising(A) reacting:(i) an organic polyisocyanate having an isocyanate group content of from 5 to 45% by weight, preferably from 15 to 35% by weight, and most preferably from 20 to 35% by weight, prepared by reacting:(a) an organic di- and/or polyisocyanate, and(b) an active hydrogen containing fatty acid ester prepared by reacting an alcohol or polyol with an aliphatic, saturated or unsaturated fatty acid, said ester being characterized in that at least one aliphatic acid which contains more than 8 carbon atoms is built into the molecule, said ester further characterized as having an acid number of from 0 to 100 and a hydroxyl number of from 0 to 150 with at least one of said numbers being greater than zero, said ester having an average molecular weight of from 500 to 5000,(ii) an isocyanate reactive component comprising:(a) from about 0.5 to about 10% by weight based on the weight of components (ii)(b) and (ii)(c), of a zinc carboxylate containing from 8 to 24 carbon atoms per carboxylate group,(b) from about 0.3 to 100% by weight, preferably from 0.5 to 95% by weight, more preferably from 5 to 45% by weight, and most preferably from 10 to 35% by weight, based on the weight of components (ii)(b) and (ii)(c), of a compatibilizer which compatibilizes said carboxylate in component (ii), and(c) 0 to about 99.5% by weight, preferably from 5 to 99.5% by weight, more preferably from 55 to 95% by weight, and most preferably from 65 to 90% by weight, based on the weight of components (ii)(b), and (ii)(c), of at least one active hydrogen containing compound other than said compatibilizer,at an isocyanate index of from about 90 to about 400 and preferably from about 95 to about 115, in a closed mold,(B) allowing the components to react, and(C) removing the product from the mold.

    Rim polyurethane or polyurea compositions containing internal mold release agents
    4.
    发明授权
    Rim polyurethane or polyurea compositions containing internal mold release agents 失效
    含有内部脱模剂的环氧聚氨酯或聚脲组合物

    公开(公告)号：US4764540A

    公开(公告)日：1988-08-16

    申请号：US114262

    申请日：1987-11-04

    申请人： John E. Dewhurst ,  Stephen J. Harasin ,  Mark C. Cekoric ,  Saad M. Abouzahr

    发明人： John E. Dewhurst ,  Stephen J. Harasin ,  Mark C. Cekoric ,  Saad M. Abouzahr

    IPC分类号： B29C33/60 ,  B29C67/24 ,  C08G18/38 ,  C08G18/65 ,  C08K5/29 ,  C08L75/00 ,  C08G18/14

    CPC分类号： C08K5/29 ,  B29C33/60 ,  C08G18/3825 ,  C08G18/6535 ,  C08L75/00 ,  B29C67/246 ,  B29K2075/00 ,  C08G2120/00 ,  C08G2125/00

    摘要： The present invention is directed to a process for the production of optionally cellular, polyurethane elastomer moldings or optionally cellular, rigid structural polyurethanes by reacting a reaction mixture containing(i) a polyisocyanate,(ii) a high molecular weight polymer having at least two isocyanate-reactive groups and having a molecular weight of 400 to about 10,000,(iii) about 5 to 50% by weight, based on the weight of component (ii) of a chain-extender having at least two isocyanate-reactive groups and(iv) about 0.05 to 10 weight percent, based on the weight of components (ii) and (iii) of a salt based on a carboxy functional siloxane and an amidine group-containing compound of the formula ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are straight or branched, saturated or unsaturated hydrocarbon chains having up to 30 carbon atoms which may optionally be substituted by ether groups, ester groups, amide groups or amidine groups and may also optionally be terminated by isocyanate-reactive groups such as hydroxyl or amino groups,R.sub.4 corresponds to the definition of R.sub.1, R.sub.2 and R.sub.3, but may additionally represent an aromatic substituent having 6 to 15 carbon atoms or may represent the group --NR.sub.2 R.sub.3 andR.sub.1, R.sub.2, R.sub.3 and R.sub.4 may, with one or both of the amidine nitrogens, also form a heterocyclic ring.The present invention is also directed to the amidine group-containing salt (iv) and to a isocyanate-reactive composition based on components (ii), (iii) and (iv).

    摘要翻译： 本发明涉及通过使含有（i）多异氰酸酯的反应混合物，（ii）具有至少两种异氰酸酯的高分子量聚合物的反应混合物反应生产任选细胞的聚氨酯弹性体模制品或任选的细胞刚性结构聚氨酯​​的方法 基于具有至少两个异氰酸酯反应性基团的增链剂组分（ii）的重量，（iv）约5-50重量％的分子量为约400至约10,000，（iii）约5至50重量％ ）基于羧基官能硅氧烷和含脒基的化合物（I）的盐的组分（ii）和（iii）的重量计约0.05至10重量％，其中R1，R2 并且R 3是具有至多30个碳原子的直链或支链饱和或不饱和烃链，其可以任选地被醚基，酯基，酰胺基或脒基取代，并且还可以任选被异氰酸酯反应 诸如羟基或氨基的基团R4对应于R 1，R 2和R 3的定义，但也可以另外表示具有6至15个碳原子的芳族取代基或可以表示基团-NR 2 R 3，并且R 1，R 2，R 3和R 4可以 与一个或两个脒鎓氮也形成杂环。 本发明还涉及含脒基盐（iv）和基于组分（ii），（iii）和（iv）的异氰酸酯反应性组合物。

    IMR having synergistic effect with stabilizing system additives and catalyst package
    5.
    发明授权
    IMR having synergistic effect with stabilizing system additives and catalyst package 有权
    IMR具有与稳定体系添加剂和催化剂包装的协同效应

    公开(公告)号：US06448364B1

    公开(公告)日：2002-09-10

    申请号：US09811030

    申请日：2001-03-16

    申请人： Jan L. R. Clatty ,  Michael T. Wellman ,  Stephen J. Harasin

    发明人： Jan L. R. Clatty ,  Michael T. Wellman ,  Stephen J. Harasin

    IPC分类号： C08G1832

    CPC分类号： C08G18/6677 ,  C08G18/225 ,  C08G18/6685 ,  C08G2120/00 ,  C08G2125/00 ,  C08G2130/00

    摘要： This invention relates to a process for the production of a polyurethane elastomer by reacting a reaction mixture comprising (A) an isocyanate-reactive component having a molecular weight of 400 to 12,000, a functionality of about 2 to about 8 and being capped with 13 to 21% by weight of ethylene oxide, wherein the isocyanate-reactive groups are hydroxyl groups, amine groups or mixtures thereof; (B) an isocyanate-reactive component comprising (1) an isocyanate-reactive component containing at least two hydroxyl groups and having a molecular weight of from 62 to 399, and (2) an isocyanate-reactive component selected from the group consisting of (a) an isocyanate-reactive group containing tertiary amine polyether corresponding to a specific formula, (b) at least one organic amine compound containing at least two amine groups which are reactive with isocyanate groups; (C) potassium halide; (D) an internal mold release agent; (E) at least one catalyst, and (F) a polyisocyanate component.

    摘要翻译： 本发明涉及一种制备聚氨酯弹性体的方法，该反应混合物包含（A）分子量为400至12,000的异氰酸酯反应性组分，官能度为约2至约8并被封端的反应混合物， 21重量％的环氧乙烷，其中异氰酸酯反应性基团是羟基，胺基或其混合物; （B）异氰酸酯反应性组分，其包含（1）含有至少两个羟基并且分子量为62至399的异氰酸酯反应性组分，和（2）选自（ a）含有对应于特定式的叔胺聚醚的异氰酸酯反应性基团，（b）至少一种含有至少两个与异氰酸酯基团反应的胺基的有机胺化合物; （C）卤化钾; （D）内部脱模剂; （E）至少一种催化剂，和（F）多异氰酸酯组分。

    Rim polyurethane compositions containing internal mold release agents
    7.
    发明授权
    Rim polyurethane compositions containing internal mold release agents 失效
    含有内部脱模剂的轮胎聚氨酯组合物

    公开(公告)号：US4847307A

    公开(公告)日：1989-07-11

    申请号：US229897

    申请日：1988-08-08

    申请人： John E. Dewhurst ,  Stephen J. Harasin

    发明人： John E. Dewhurst ,  Stephen J. Harasin

    IPC分类号： B29C33/60 ,  B29C67/24 ,  C08G18/38 ,  C08G18/65 ,  C08K5/29 ,  C08L75/00

    CPC分类号： C08K5/29 ,  B29C33/60 ,  C08G18/3825 ,  C08G18/6535 ,  C08L75/00 ,  B29C67/246 ,  B29K2075/00 ,  C08G2120/00 ,  C08G2125/00

    摘要： The present invention is directed to a process for the production of optionally cellular, polyurethane elastomer moldings or optionally cellular, rigid structural polyurethanes by reacting a reaction mixture containing(i) a polyisocyanate,(ii) a high molecular weight polymer having at least two hydroxy groups and having a molecular weight of 400 to about 10,000,(iii) about 5 to 50% by weight, based on the weight of component (ii) of a chain-extender having at least two hydroxy groups and(iv) about 0.05 to 10 weight percent, based on the weight of components (ii) and (iii) of a salt based on a carboxy functional siloxane and an amidine group-containing compound of the formula ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are straight or branched, saturated or unsaturated hydrocarbon chains having up to 30 carbon atoms which may optionally be substituted by ether groups, ester groups, amide groups or amidine groups and may also optionally be terminated by isocyanate-reactive groups such as hydroxyl or amino groups, R.sub.4 corresponds to the definition of R.sub.1, R.sub.2 and R.sub.3, but may additionally represent an aromatic substituent having 6 to 15 carbon atoms or may represent the group --NR.sub.2 R.sub.3 and R.sub.1, R.sub.2, R.sub.3 and R.sub.4 may, with one or both of the amidine nitrogens, also form a heterocyclic ring.The present invention is also directed to the amidine group-containing salt (iv) and to a polyol composition based on components (ii), (iii) and (iv).

    摘要翻译： 本发明涉及通过使包含（i）多异氰酸酯的反应混合物，（ii）具有至少两个羟基的高分子量聚合物的反应混合物来生产任选细胞的聚氨酯弹性体模制品或任选的细胞刚性结构聚氨酯​​的方法 基团，其分子量为400至约10,000，（iii）约5-50重量％，基于具有至少两个羟基的增链剂组分（ⅱ）的重量，和（iv）约0.05至 基于羧基官能硅氧烷和含有脒基的化合物（I）的盐的组分（ii）和（iii）的重量，10重量％，其中R 1，R 2和R 3是直的 或具有至多30个碳原子的支链，饱和或不饱和烃链，其可以任选被醚基，酯基，酰胺基或脒基取代，并且还可以任选地被异氰酸酯反应性基团例如氢 X或氨基，R 4对应于R 1，R 2和R 3的定义，但可以另外表示具有6至15个碳原子的芳族取代基或可以表示基团-NR 2 R 3，并且R 1，R 2，R 3和R 4可以与一个或多个 两个脒氮都形成杂环。 本发明还涉及含脒基盐（iv）和基于组分（ii），（iii）和（iv）的多元醇组合物。

    Rim polyurethane compositions containing internal mold release agents
    10.
    发明授权
    Rim polyurethane compositions containing internal mold release agents 失效
    含有内部脱模剂的轮胎聚氨酯组合物

    公开(公告)号：US4789688A

    公开(公告)日：1988-12-06

    申请号：US146075

    申请日：1988-01-20

    申请人： John E. Dewhurst ,  Stephen J. Harasin

    发明人： John E. Dewhurst ,  Stephen J. Harasin

    IPC分类号： B29C33/60 ,  B29C67/24 ,  C08G18/38 ,  C08G18/65 ,  C08K5/29 ,  C08L75/00 ,  C08G18/30

    CPC分类号： C08K5/29 ,  B29C33/60 ,  C08G18/3825 ,  C08G18/6535 ,  C08L75/00 ,  B29C67/246 ,  B29K2075/00 ,  C08G2120/00 ,  C08G2125/00

    摘要： The present invention is directed to a process for the production of optionally cellular, polyurethane elastomer moldings or optionally cellular, rigid structural polyurethanes by reacting a reaction mixture containing(i) a polyisocyanate,(ii) a high molecular weight polymer having at least two hydroxy groups and having a molecular weight of 400 to about 10,000,(iii) about 5 to 50% by weight, based on the weight of component (ii) of a chain-extender having at least two hydroxy groups and(iv) about 0.05 to 10 weight percent, based on the weight of components (ii) and (iii) of a salt based on a carboxy functional siloxane and an amidine group-containing compound of the formula ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are straight or branched, saturated or unsaturated hydrocarbon chains having up to 30 carbon atoms which may optionally be substituted by ether groups, ester groups, amide groups or amidine groups and may also optionally be terminated by isocyanate-reactive groups such as hydroxyl or amino groups,R.sub.4 corresponds to the definition of R.sub.1, R.sub.2 and R.sub.3, but may additionally represent an aromatic substituent having 6 to 15 carbon atoms or may represent the group --NR.sub.2 R.sub.3 andR.sub.1, R.sub.2, R.sub.3 and R.sub.4 may, with one or both of the amidine nitrogens, also form a heterocyclic ring.The present invention is also directed to the amidine group-containing salt (iv) and to a polyol composition based on components (ii), (iii) and (iv).

    摘要翻译： 本发明涉及通过使包含（i）多异氰酸酯的反应混合物，（ii）具有至少两个羟基的高分子量聚合物的反应混合物来生产任选细胞的聚氨酯弹性体模制品或任选的细胞刚性结构聚氨酯​​的方法 基团，其分子量为400至约10,000，（iii）约5-50重量％，基于具有至少两个羟基的增链剂组分（ⅱ）的重量，和（iv）约0.05至 基于羧基官能硅氧烷和含有脒基的化合物（I）的盐的组分（ii）和（iii）的重量，10重量％，其中R 1，R 2和R 3是直的 或具有至多30个碳原子的支链，饱和或不饱和烃链，其可以任选被醚基，酯基，酰胺基或脒基取代，并且还可以任选地被异氰酸酯反应性基团例如氢 X或氨基，R 4对应于R 1，R 2和R 3的定义，但可以另外表示具有6至15个碳原子的芳族取代基或可以表示基团-NR 2 R 3，并且R 1，R 2，R 3和R 4可以与一个或多个 两个脒氮都形成杂环。 本发明还涉及含脒基盐（iv）和基于组分（ii），（iii）和（iv）的多元醇组合物。