Selective ether cleavage synthesis of liquid crystals
    3.
    发明授权
    Selective ether cleavage synthesis of liquid crystals 有权
    液晶的选择性醚裂解合成

    公开(公告)号:US07147800B2

    公开(公告)日:2006-12-12

    申请号:US10746109

    申请日:2003-12-24

    摘要: A method for making platform molecules comprising: reacting 4-alkoxy benzoyl chloride with R2-hydroquinone under first conditions effective to produce bis 1,4[4-alkoxy-benzoyloxy]-R2-phenylene comprising bis terminal alkoxy groups wherein R2 is a bulky organic group; and, subjecting the bis 1,4[4-alkoxy-benzoyloxy]-R2-phenylene to second conditions effective to selectively cleave the bis terminal alkoxy groups to produce a solution comprising complexes comprising diphenolic platform molecules comprising bis terminal hydroxyl groups, the second conditions also being effective to precipitate the complexes out of the solution.

    摘要翻译: 一种制备平台分子的方法,包括:在有效产生双1,4 [4-烷氧基 - 苯甲酰氧基] -R 2'的第一条件下使4-烷氧基苯甲酰氯与R 2 - 氢醌反应, 其中R 2是大体积的有机基团; 并且使双1,4- [4-烷氧基 - 苯甲酰氧基] -R 2 - 亚苯具有有效选择性地切割双末端烷氧基的第二条件,以产生包含二酚平台分子的络合物的溶液,所述二酚平台分子包含 双末端羟基,第二个条件也有效地将络合物从溶液中沉淀出来。

    Composites made using functionalized nanoparticles
    4.
    发明授权
    Composites made using functionalized nanoparticles 失效
    使用官能化纳米粒子制成的复合材料

    公开(公告)号:US06743936B1

    公开(公告)日:2004-06-01

    申请号:US09692690

    申请日:2000-10-19

    IPC分类号: C07F902

    摘要: There are disclosed amphoteric nano-sized metal oxide particles functionalized with silyl esters of a phosphonate and composites thereof with an acrylate-based monomer, including liquid crystal monomers photopolymerizable at ambient temperature. Also disclosed are the method making such functionalized particular by reacting a metal oxide with a silyl ester of a phosphonate in the presence of a non-aqueous solvent and in an inert atmosphere and the method of making the composites wherein the functionalized particles are admixed with an acrylate-based matrix monomer, including liquid crystal monomers photopolymerizable at ambient temperature. Further disclosed is the method of dental repair wherein the composites are applied to a tooth and photopolymerized.

    摘要翻译: 公开了用膦酸酯的甲硅烷基酯和其与丙烯酸酯类单体的复合材料官能化的两性纳米尺寸金属氧化物颗粒,包括在环境温度下可光聚合的液晶单体。 还公开了通过使金属氧化物与膦酸酯的甲硅烷基酯在非水溶剂和惰性气氛的存在下反应而进行官能化的方法,以及制备复合物的方法,其中官能化颗粒与 丙烯酸酯基基体单体,包括在环境温度下可光聚合的液晶单体。 进一步公开了牙科修复方法,其中将复合材料应用于牙齿并进行光聚合。

    Functionalized nanoparticles
    5.
    发明授权
    Functionalized nanoparticles 失效
    官能化纳米粒子

    公开(公告)号:US06696585B1

    公开(公告)日:2004-02-24

    申请号:US09667370

    申请日:2000-09-22

    IPC分类号: C07F908

    摘要: There are disclosed amphoteric nano-sized metal oxide particles functionalized with silyl esters of a phosphonate and composites thereof with an acrylate-based monomer, including liquid crystal monomers photopolymerizable at ambient temperature. Also disclosed are the method making such functionalized particular by reacting a metal oxide with a silyl ester of a phosphonate in the presence of a non-aqueous solvent and in an inert atmosphere and the method of making the composites wherein the functionalized particles are admixed with an acrylate-based matrix monomer, including liquid crystal monomers photopolymerizable at ambient temperature. Further disclosed is the method of dental repair wherein the composites are applied to a tooth and photopolymerized.

    摘要翻译: 公开了用膦酸酯的甲硅烷基酯和其与丙烯酸酯类单体的复合材料官能化的两性纳米尺寸金属氧化物颗粒,包括在环境温度下可光聚合的液晶单体。 还公开了通过使金属氧化物与膦酸酯的甲硅烷基酯在非水溶剂和惰性气氛的存在下反应而进行官能化的方法,以及制备复合物的方法,其中官能化颗粒与 丙烯酸酯基基体单体,包括在环境温度下可光聚合的液晶单体。 进一步公开了牙科修复方法,其中将复合材料应用于牙齿并进行光聚合。