Abstract:
Ionomer particles with an inner area and an outer area are provided. The outer area has an oxidic matrix with cations selected by observing the following conditions. Only two different types of cations must be present that belong to one of the following groups (a) to (d), and these two types of cations must be selected from two different ones of the groups (a) to (d): (a) ions of the elements of the second main group and bivalent ions of the transition elements and the lanthanides; (b) ions of the elements of the third main group with the exception of boron and trivalent ions of the transition elements and the lanthanides; (c) ions of the elements of the fourth main group with exception of carbon and tetravalent ions of the transition elements and the lanthanides (d) ions of the elements of the fifth main group, selected from ions of antimony and bismuth and pentavalent ions of the transition elements. Particles of the composition ZrO2—Y2O3, ZrO2—Al2O3, BaToO3, Al6Si2O13 are not contained.
Abstract:
Methods, systems, and apparatuses for downhole sampling are presented. The sampling system includes a control unit and a housing to engage a conduit. The housing at least partially encloses at least one formation sampler to collect a formation sample. The formation sampler is stored in a sampler carousel. A sampler propulsion system forces the formation sampler into the formation. The propulsion system is in communication with the control unit.
Abstract:
The invention relates to semipermeable membranes comprising organically modified silicic-acid polycondensates, to a process for preparing them and to their use in gas exchange and in separation techniques, especially in gas separation, dialysis, pervaporation, and other filtration. The membranes of the invention can be flat or tubular and can be manufactured by conventional methods from viscous liquids obtained by hydrolytic polycondensation of organically modified, hydrolyzable silicon compounds containing C═C double bonds. The membranes are cured by addition polymerization and/or polyaddition of the C═C double bonds.
Abstract:
The present invention pertains to a method for encapsulating a liquid or pasty substance in a cross-linked encapsulation material, characterized in that the liquid or pasty substance and an inorganic at least partially condensed and organic polymerizable inorganic-organic hybrid material are co-extruded as a cross-linkable precursor material of the encapsulation material through a nozzle, such that the cross-linkable precursor material surrounds the liquid or pasty substance, whereupon the co-extruded material is passed through a zone, in which a cross-linking of the precursor material is brought about. In preferred embodiments, the precursor material for the encapsulation material may be produced from or using silanes of the formula (I) RaR1bSiX4-a-b (I) by means of hydrolytic condensation, wherein the substituents R, R1 and X may each be the same or different and wherein R represents an organic radical that is bound to silicon via carbon and that can be cross-linked by heat or actinic radiation, R1 represents a radical that is bound to silicon via carbon and that cannot be organically cross-linked, X is a group that can be hydrolyzed under hydrolysis conditions or that can be separated from the silicon, or is OH, a is 1 or 2, b is 0 or 1, and a+b may be 1 or 2. Inorganic hollow spheres or hollow fibers can optionally be produced by burning the organic components of the capsules or fibers obtained in this manner and evaporating the content.
Abstract:
The present invention relates to silanes with the formula (I) RaQbSiX4-a-b (I) wherein the radicals and indices have the following meaning: R is optionally the same or different and identifies a straight-chain, branched-chain and/or cyclic alkyl, alkenyl, aryl, alkylaryl or arylalkyl group or a straight-chain or branched and/or cyclic organic radical with at least one organically polymerizable group, wherein the carbon chains can each be interrupted by one or more oxygen or sulfur atoms or carboxyl or carbonamide or amino groups or can hold one or more groups selected from carboxylic acid groups, carbonamide groups, amino groups, hydroxy groups and mercapto groups, at one of the ends of said carbon chains, Q is (C6H3)(OR1)2 or R3(C6H3)(OR1)2, where R1 indicates hydrogen or a C1C4- alkyl group, and R3 is a substituted or unsubstituted carbon chain that is interrupted by either one or by multiple groups selected from —O—, —NH—, —NHC(O)—, —C(O)NH—, —C(O)NHC(O)—, —NHC(O)NH—, —C(O)O—, —NHC(O)O—, —C(O)—, —OC(O)NHC(O)O—, —S—, —S(O)—, —C(S)—, —C(O)S—, —C(S)NH—, —NHC(S)NH—, and/or is bonded to the radical (C6H3)(OR1)2 by way of one of said groups and/or comprises at least 7 carbon atoms in the chain. X is a group that can enter into a hydrolytic condensation reaction, forming Si—O—Si bridges, a is 0, 1 or 2, b is 1 or 2, and a+b together is 1, 2 or 3. Also, the invention relates to organically modified crystalline silica (hetereo)(partial) condensates that can be produced from silanes of formula (I), among other things, and that can be cured into an organic polymer in the presence of organically polymerizable groups. The crystalline silica (hetereo)(partial) condensates and polymers of the invention are suitable as adhesives, in particular for wet applications.
Abstract:
The invention relates to inorganic hollow fibers, to a spinning mass and to a method for producing the same as well as to the use thereof for material transports, for the exchange of gases and in separation procedures. The hollow fibers according to the invention are obtainable by processing a spinning mass to a hollow fiber according to general methods, by curing said fiber thermally, via radiation induction or via chemical induction, and by removing the organic components via pyrolysis. The spinning mass is obtained by hydrolytic polycondensation of hydrolyzable compounds of silicon, aluminum, titanium and zirconium and optionally of co-condensable compounds of the elements Li, Na, Mg, Ca, Sr, Ba, Zn, Sn or Pb. The hydrolytic polycondensation is performed by adding water or moisture. If desired, monomers or oligomers which may undergo co-polymerization or (poly)addition, curing catalysts, pore generating additives or compounds of the elements Li, Na, Mg, Ca, Sr, Ba, Zn, Sn and Pb which are soluble in the reaction medium are added to the spinning mass.
Abstract:
The invention relates to an oxygenator membrane based on organically modified silicic-acid polycondensates into a process for preparation thereof. The oxygenator membrane is obtainable by processing a viscous to resinous liquid by conventional methods to form a membrane, drying this membrane, if desired, and subjecting it to curing induced thermally and/or radiatively and/or chemically. The viscous to resinous liquid is obtained by hydrolytic polycondensation of one or more compounds of the general formula I and/or II and/or III and/or IV and/or of precondensates derived from these compound by hydrolytic condensation and, if desired, of one or more compounds of the general formula V, and, if desired, by addition of one or more monomers and/or oligomers which are capable of undergoing addition copolymerization and/or (poly)addition reaction and/or of one or more curing catalysts.