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公开(公告)号：US11840668B2
公开(公告)日：2023-12-12
申请号：US18149179
申请日：2023-01-03
发明人： Ivan Greager , Roger Harris , Rudolph Havenga , Neil King
CPC分类号： C10G2/31 , C01B3/24 , C10G45/58 , C10G47/00 , C25B1/04 , C25B9/17 , C01B2203/0205 , C01B2203/025 , C01B2203/04 , C01B2203/062 , C10G2300/1003 , C10G2300/1011 , C10G2300/1022 , C10G2400/04 , C10G2400/08
摘要： An integrated process for the production of a useful liquid hydrocarbon product comprises: feeding a gasification zone with an oxygen-containing feed and a first carbonaceous feedstock comprising waste materials and/or biomass, gasifying the first carbonaceous feedstock in the gasification zone to produce first synthesis gas, partially oxidising the first synthesis gas in a partial oxidation zone to generate partially oxidised synthesis gas, combining at least a portion of the first synthesis gas and/or the partially oxidised synthesis gas and at least a portion of electrolysis hydrogen obtained from an electrolyser in an amount to achieve the desired hydrogen to carbon monoxide molar ratio of from about 1.5:1 to about 2.5:1, and to generate a blended synthesis gas, wherein the electrolyser operates using green electricity; and subjecting at least a portion of the blended synthesis gas to a conversion process effective to produce the liquid hydrocarbon product.
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公开(公告)号：US20230382821A1
公开(公告)日：2023-11-30
申请号：US18032088
申请日：2021-10-08
CPC分类号： C07C1/0485 , C01B3/323 , C25B1/02 , C25B15/081 , C01B2203/80 , C01B2203/025 , C01B2203/0233 , C01B2203/0244 , C01B2203/062 , C01B2203/0475 , C01B2203/0485
摘要： The present invention provides integrated process for the production of a useful liquid hydrocarbon product comprising the steps of: feeding a gasification zone with an oxygen-containing feed and a first carbonaceous feedstock comprising waste materials and/or biomass, gasifying the first carbonaceous feedstock in the gasification zone to produce a first synthesis gas, partially oxidising the first synthesis gas in a partial oxidation zone to generate partially oxidised synthesis gas, combining at least a portion of the first synthesis gas and/or the partially oxidised synthesis gas and at least a portion of electrolysis hydrogen obtained from an electrolyser in an amount to achieve the desired hydrogen to carbon monoxide molar ratio of from about 1.5:1 to about 2.5:1, which is higher than that of the first synthesis gas, and to generate a blended synthesis gas, wherein the electrolyser operates using green electricity; and subjecting at least a portion of the blended synthesis gas to a conversion process effective to produce the liquid hydrocarbon product.
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公开(公告)号：US20230227741A1
公开(公告)日：2023-07-20
申请号：US18175798
申请日：2023-02-28
发明人： Ivan Philip Greager , Roger Allen Harris , Neil Alexander King , Soumitra R. Deshmukh , Zheyan Qiu
IPC分类号： C10J3/48 , C10J3/46 , C10K1/00 , C10K3/00 , C10G2/00 , C10K1/10 , C10K1/12 , C10K1/08 , C10K1/16 , C01B3/12 , C10K3/02 , C10K3/04
CPC分类号： C10J3/48 , C01B3/12 , C10G2/30 , C10J3/463 , C10K1/003 , C10K1/004 , C10K1/12 , C10K1/16 , C10K1/085 , C10K1/102 , C10K3/04 , C10K3/005 , C10K3/026 , C10J2300/092 , C10J2300/0909 , C10J2300/0946 , C10J2300/0976 , C10J2300/1612 , C10J2300/1659 , C10J2300/1687 , C10J2300/1838 , C10J2300/1892
摘要： A process for the manufacture of a useful product from carbonaceous feedstock of fluctuating compositional characteristics, the process comprising the steps of: continuously providing the carbonaceous feedstock of fluctuating compositional characteristics to a gasification zone; gasifying the carbonaceous feedstock in the gasification zone to obtain raw synthesis gas; sequentially removing ammoniacal, sulphurous and carbon dioxide impurities from the raw synthesis gas to form desulphurised gas and recovering carbon dioxide in substantially pure form; converting at least a portion of the desulphurised synthesis gas to a useful product. Despite having selected a more energy intensive sub-process i.e. physical absorption for removal of acid gas impurities, the overall power requirement of the facility is lower on account of lower steam requirements and thereby leading to a decrease in the carbon intensity score for the facility.
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公开(公告)号：US20230117401A1
公开(公告)日：2023-04-20
申请号：US17917941
申请日：2021-04-09
发明人： Heinz J. ROBOTA , Ravi ARORA , Robert J. LUZENSKI , Jason R. ROBINSON , Brendan R. WHITE , Thomas YUSCHAK , Paul W. NEAGLE , Kai Tod Paul JAROSCH , Bin YANG
摘要： Spent catalyst (500) is removed from process microchannels (310) of a Fischer-Tropsch reactor by directing a jet of air (4) from an air knife (1) through slots of a protecting member (2). The air knife is traversed across successive rows of process microchannels (310) in direction A. The spacer member (2) protects an internal microchannel architecture (315) of the process microchannels against damage by the air jet (4) which may approach or exceed sonic velocity as it is directed into the process microchannels.
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公开(公告)号：US11578281B2
公开(公告)日：2023-02-14
申请号：US17203706
申请日：2021-03-16
发明人： Ivan Philip Greager , Roger Allen Harris , Neil Alexander King , Soumitra R. Deshmukh , Zheyan Qiu , Ashish Gupta
摘要： A process for the manufacture of a useful product from carbonaceous feedstock of fluctuating compositional characteristics, comprising the steps of: continuously providing the carbonaceous feedstock of fluctuating compositional characteristics to a gasification zone; gasifying the carbonaceous feedstock in the gasification zone to obtain raw synthesis gas; recovering at least part of the raw synthesis gas from the gasification zone and supplying at least part of the recovered raw synthesis gas to a partial oxidation zone; equilibrating the H2:CO ratio of the raw synthesis gas in the partial oxidation zone to obtain equilibrated synthesis gas; recovering at least part of the equilibrated synthesis gas from the partial oxidation zone and treating the gas to remove impurities and generate a fine synthesis gas; and converting the optionally adjusted fine synthesis gas into the useful product in a further chemical reaction requiring a usage ratio.
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公开(公告)号：US20170327444A1
公开(公告)日：2017-11-16
申请号：US15664078
申请日：2017-07-31
发明人： Andre STEYNBERG , Roy LIPSKI
CPC分类号： C07C29/1518 , C01B3/382 , C01B3/48 , C01B13/0251 , C01B2203/0233 , C01B2203/0238 , C01B2203/0244 , C01B2203/025 , C01B2203/0283 , C01B2203/0405 , C01B2203/0415 , C01B2203/043 , C01B2203/061 , C01B2203/062 , C01B2203/0822 , C01B2203/1241 , C07C2/84 , C07C27/06 , C10G2/00 , Y02P20/128 , C07C11/04
摘要： The present technology is directed to processes involving formation of hydrocarbons and oxygenated hydrocarbons through use of oxygen supplied by ion transport membranes. More particularly, the present technology relates in part to a process involving steam reforming and subsequent production of a synthetic product where carbon dioxide and/or hydrogen downstream of the process is reclaimed to generate the synthetic product. The present technology also relates in part to an ethylene formation process involving a viral-templated coupling catalyst in the presence of an ion transport membrane.
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公开(公告)号：US20220177796A1
公开(公告)日：2022-06-09
申请号：US17541517
申请日：2021-12-03
发明人： Ivan Philip GREAGER , Roger Allen HARRIS , Martin HOPKINS , Neil Alexander KING , Malcolm John WARD
摘要： The present invention provides a process for obtaining solid recovered fuel and synthesis gas from a waste-based feedstock, comprising the steps of: I. converting the feedstock into a solid recovered fuel by means of a number of parameters pertaining to waste sorting, selection, comminution and/or screening; II. gasifying under suitable reaction conditions at least a portion of the solid recovered fuel to produce synthesis gas and by-product(s); and III. optionally cleaning at least a portion of the synthesis gas to produce clean synthesis gas and wastewater, wherein one or more of the solid recovered fuel, synthesis gas, and by-product(s) of the gasification are analysed during operation of the process, and wherein data from said analysis is used to control one or more parameters of step I) in order to influence reaction conditions in step II, and optionally step III).
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公开(公告)号：US20220112429A1
公开(公告)日：2022-04-14
申请号：US17499408
申请日：2021-10-12
发明人： Ivan GREAGER , Roger HARRIS , Rudolph HAVENGA , Neil KING
摘要： An integrated process for the production of a useful liquid hydrocarbon product comprises: feeding a gasification zone with an oxygen-containing feed and a first carbonaceous feedstock comprising waste materials and/or biomass, gasifying the first carbonaceous feedstock in the gasification zone to produce first synthesis gas, partially oxidising the first synthesis gas in a partial oxidation zone to generate partially oxidised synthesis gas, combining at least a portion of the first synthesis gas and/or the partially oxidised synthesis gas and at least a portion of electrolysis hydrogen obtained from an electrolyser in an amount to achieve the desired hydrogen to carbon monoxide molar ratio of from about 1.5:1 to about 2.5:1, and to generate a blended synthesis gas, wherein the electrolyser operates using green electricity; and subjecting at least a portion of the blended synthesis gas to a conversion process effective to produce the liquid hydrocarbon product.
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公开(公告)号：US20210292204A1
公开(公告)日：2021-09-23
申请号：US17204231
申请日：2021-03-17
发明人： Graham LEA
摘要： In a process for treating wastewater from a combined gasification and Fischer-Tropsch (F-T) process, feedstock derived from Municipal Solid Waste or the like is gasified in a reactor (R) and treated in a cleanup unit (C) which generates a first wastewater stream (1st WWT STREAM) containing salts and inorganic pollutants. The first wastewater stream is treated in a treatment unit (T1) to remove inorganic pollutants derived from the syngas. The treatment comprises a) degassing, and subsequently b) neutralising the first wastewater stream before treatment in a Dissolved Air Flotation unit (72c) and filtering in a moving sand bed or similar (72d) to remove solids, and a stripping process to remove ammonia. A second wastewater stream (2nd WWT Stream) containing organic pollutants but being low in salts arises from the F-T process and is treated separately to allow recycling within the F-T process.
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公开(公告)号：US09950975B2
公开(公告)日：2018-04-24
申请号：US15664078
申请日：2017-07-31
发明人： Andre Steynberg , Roy Lipski
CPC分类号： C07C29/1518 , C01B3/382 , C01B3/48 , C01B13/0251 , C01B2203/0233 , C01B2203/0238 , C01B2203/0244 , C01B2203/025 , C01B2203/0283 , C01B2203/0405 , C01B2203/0415 , C01B2203/043 , C01B2203/061 , C01B2203/062 , C01B2203/0822 , C01B2203/1241 , C07C2/84 , C07C27/06 , C10G2/00 , Y02P20/128 , C07C11/04
摘要： The present technology is directed to processes involving formation of hydrocarbons and oxygenated hydrocarbons through use of oxygen supplied by ion transport membranes. More particularly, the present technology relates in part to a process involving steam reforming and subsequent production of a synthetic product where carbon dioxide and/or hydrogen downstream of the process is reclaimed to generate the synthetic product. The present technology also relates in part to an ethylene formation process involving a viral-templated coupling catalyst in the presence of an ion transport membrane.
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