摘要:
A process for the continuous production of a thermoplastic molding composition containing a mixture of a TPU and a thermoplastic (co)polymer is disclosed. The process comprises(i) introducing into an extruder via a first feed point component I) with at least 3% by weight, with respect to component I), of at least one member selected from the group consisting of components A), B) and C), and(ii) metering in the balance of said A), B) and C) into said extruder via one or more subsequent feed points,(iii) extruding components I) and II) under conditions sufficient to cause A), B) and C) reaction to form TPU, and(iv) upon the completion of said reaction, removing the resulting mixture of TPU and (co)polymer from the extruder,wherein component I) comprises 1 to 60% by weight, with respect to the total mixture, of a thermoplastic (co)polymer, and wherein component II) comprises 99 to 40% by weight, with respect to the total mixture, of the polyurethane-forming components including A) an organic diisocyanate, B) a linear polyol having terminal hydroxyl groups and a number average molecular weight of 500 to 5000, and C) a chain extender having a molecular weight of 60 to 500, and wherein the molar ratio of NCO groups in A) to the groups which react with NCO in B) and C) is in the range of 0.9 to 1.2.
摘要:
A process for the continuous production of a thermoplastic molding composition containing a mixture of a TPU and a thermoplastic (co)polymer is disclosed. The process comprises (i) introducing into an extruder via a first feed point component I) with at least 3% by weight, with respect to component I), of at least one member selected from the group consisting of components A), B) and C), and(ii) metering in the balance of said A), B) and C) into said extruder via one or more subsequent feed points, (iii) extruding components I) and II) under conditions sufficient to cause A), B) and C) reaction to form TPU, and (iv) upon the completion of said reaction, removing the resulting mixture of TPU and (co)polymer from the extruder, wherein component I) comprises 1 to 60% by weight, with respect to the total mixture, of a thermoplastic (co)polymer, and wherein component II) comprises 99 to 40% by weight, with respect to the total mixture, of the polyurethane-forming components including A) an organic diisocyanate, B) a linear polyol having terminal hydroxyl groups and a number average molecular weight of 500 to 5000, and C) a chain extender having a molecular weight of 60 to 500, and wherein the molar ratio of NCO groups in A) to the groups which react with NCO in B) and C) is in the range of 0.9 to 1.2.
摘要:
A process for the continuous production of a thermoplastic molding composition containing a mixture of TPU and a (co)polymer is disclosed. The process comprises (a) introducing into an extruder under time and temperature conditions sufficient to bring about the formation of thermoplastic polyurethane a (co)polymer, and polyurethane-forming components comprising A) an organic diisocyanate, B) a linear polyol having terminal hydroxyl groups and a molecular weight of 500 to 5000, and C) a chain extender having a molecular weight of 60 to 500, and upon completing the formation of said polyurethane (b) discharging the resulting TPU/(co)polymer mixture from the extruder. Importantly, the (co)polymer contains a flow enhancer and the molar ratio of the NCO groups in A) to the groups which react with NCO in B) and C) is 0.9 to 1.2.
摘要:
A thermoplastic molding composition comprising a thermoplastic polyurethane and a wax mixture is disclosed. The polyurethane is a product of an organic diisocyanate, a linear, hydroxyl-terminated polyol and a diol or diamine chain extender. The wax mixture contains a first mixture of an ester of a C.sub.10-45 aliphatic carboxylic acid and a diol, and an alkali metal or alkaline earth metal salt of a C.sub.10-45 aliphatic carboxylic acids, and at least one member selected from the group consisting of fatty acid ester, fatty acid amide, fatty acid ester amide and polyethylene wax.
摘要:
Thermoplastically processable polyurethane elastomers are prepared by A) mixing one or more substantially linear polyols with a diisocyanate, B) reacting the resultant mixture substantially completely in a reactor at temperatures of >100.degree. C. to form a prepolymer, C) mixing the prepolymer with low molecular weight chain extenders, D) applying the reaction mixture prepared in stage C) to a support and allowing the mixture to react thereon to solidification.
摘要:
Thermoplastically processable polyurethane elastomers are produced by a process of A) mixing one or more substantially linear macrodiols with a diisocyanate, B) reacting the resultant mixture in a reactor at temperatures of >100.degree. C. to form a prepolymer, C) mixing the prepolymer with one or more low molecular weight chain extenders, and D) reacting the mixture prepared in stage C) to complete conversion in a high-shear, high-viscosity reactor.
摘要:
The present invention relates to a process for the preparation of plastics containing thermoplastic polyurethanes and optionally other components comprising (a) melting and homogenizing a thermoplastic polyurethane in an extruder, and (b) adding an isocyanate to said extruder containing the melted and homogenized thermoplastic polyurethane.
摘要:
The present invention relates to a process for the preparation of plastics containing thermoplastic polyurethanes and optionally other components comprising (a) melting and homogenizing a thermoplastic polyurethane in an extruder, and (b) adding an isocyanate to said extruder containing the melted and homogenized thermoplastic polyurethane.
摘要:
Composite membranes of a macroporous filler-containing membrane of at least two incompatible polymers and a pore-free polyurethane membrane applied there to exhibit an improved action in the removal of benzenes optionally suhstituted by lower alkyl radicals, hydroxyl, chlorine or bromine from their mixtures with aliphatic and/or cycloaliphatic hydrocarbons, alcohols, ethers, ketones and/or carboxylic acid esters or from effluent.