公开(公告)号：US6001207A

公开(公告)日：1999-12-14

申请号：US966602

申请日：1997-11-10

申请人： Howard H. Enlow ,  Scott W. Huffer ,  Frederick Young ,  William J. Buehne

发明人： Howard H. Enlow ,  Scott W. Huffer ,  Frederick Young ,  William J. Buehne

IPC分类号： B32B27/08 ,  B32B38/12 ,  B44C1/165 ,  B05D1/06 ,  B32B31/00 ,  B29B1/165

CPC分类号： B32B27/08 ,  B32B38/12 ,  Y10S428/937 ,  Y10S977/89

摘要： A process for making a thermoformable conductive plastic laminate for use in making plastic parts adapted for electrostatic spray painting of a uniform high quality paint finish includes forming a matte release coated casting sheet, casting an electrically conductive polymer in thin film form on the casting sheet, drying to form a conductive primer coat, and transfer-laminating the conductive coating to a thin, thermoformable plastic face sheet. The matte release coat has a fine particulate filler that transfers a micro-roughened matte surface to the conductive primer coat. The conductive primer includes a polyester resin containing a fine particulate conductive material such as carbon black and, preferably, an anti-blocking agent such as fumed silica. The primer coated face sheet can be thermoformed and bonded to a underlying plastic substrate panel. The conductive primer has sufficient elongation and maintains uniform electrical surface conductivity and film thickness throughout the transfer-laminating, thermoforming and substrate panel-cladding process. The uniform surface resistivity of the conductive primer film is sufficient to permit electrostatic spray painting of the finished contoured panel and in one embodiment produces a Class "A" quality exterior automotive paint finish on the resulting panel.

摘要翻译： 制造用于制造适于静电喷涂均匀的高质量涂漆的塑料部件的可热成型导电塑料层压体的方法包括形成无光泽涂布的流延片，在铸片上铸造薄膜形式的导电聚合物， 干燥以形成导电底漆，并将导电涂层转移层压到薄的可热成形的塑料面板上。 无光泽脱模涂层具有细微的颗粒填料，将微粗糙的无光泽表面转移到导电底漆涂层。 导电底漆包括含有细颗粒导电材料如碳黑的聚酯树脂，以及优选的防粘连剂如热解法二氧化硅。 底漆涂布的面板可以热成型并结合到下面的塑料基板。 导电底漆具有足够的伸长率，并且在整个转移层压，热成型和衬底面板包层过程中均具有均匀的电表面导电性和膜厚度。 导电底漆膜的均匀表面电阻足以允许成品轮廓面板的静电喷涂，并且在一个实施例中，在所得面板上产生“A”级外部汽车漆面。

公开(公告)号：US09188889B2

公开(公告)日：2015-11-17

申请号：US12846998

申请日：2010-07-30

申请人： Linwood G. Koger ,  William J. Buehne ,  Le-Hoa Hong ,  Iliana Velazquez ,  Tamara L. McCartney ,  Wendy Shuttleworth ,  Anahit Tataryan ,  Vikaas Gupta

发明人： Linwood G. Koger ,  William J. Buehne ,  Le-Hoa Hong ,  Iliana Velazquez ,  Tamara L. McCartney ,  Wendy Shuttleworth ,  Anahit Tataryan ,  Vikaas Gupta

IPC分类号： B32B33/00 ,  B32B27/36 ,  G03G7/00 ,  B32B7/12 ,  B32B27/08 ,  B32B27/20 ,  B32B29/00 ,  G09F3/02 ,  G09F3/10

CPC分类号： G03G7/0013 ,  B32B7/06 ,  B32B7/12 ,  B32B27/08 ,  B32B27/20 ,  B32B27/36 ,  B32B29/00 ,  B32B2255/10 ,  B32B2255/20 ,  B32B2264/102 ,  B32B2307/406 ,  B32B2307/41 ,  B32B2307/75 ,  B32B2519/00 ,  B41M5/504 ,  B41M5/508 ,  B41M5/5218 ,  B41M2205/34 ,  G03G7/00 ,  G03G7/0053 ,  G03G7/008 ,  G03G7/0086 ,  G09F3/02 ,  G09F3/10 ,  G09F2003/0201 ,  G09F2003/0241 ,  Y10T428/14

摘要： A multilayer laminate such as a label assembly having high opacity and desirable appearance characteristics is described. The laminate includes a facestock layer, an adhesive layer, and a liner layer. The facestock layer includes a print-receiving top coat layer that includes a combination of titanium dioxide and one or more optical brighteners. The combination of these materials avoids build up of static charges upon laser printing on the facestock.

摘要翻译： 描述了具有高不透明度和理想外观特征的多层层压体，例如标签组件。 层压体包括面层，粘合剂层和衬里层。 面层包括印刷接收面涂层，其包括二氧化钛和一种或多种荧光增白剂的组合。 这些材料的组合避免了在面材上激光打印时产生静电荷。

公开(公告)号：US20140272153A1

公开(公告)日：2014-09-18

申请号：US14203998

申请日：2014-03-11

申请人： William J. Buehne

发明人： William J. Buehne

IPC分类号： C09D127/16

CPC分类号： C09D127/16 ,  C08K5/12 ,  C08L27/16 ,  C08L33/10 ,  C08L2205/02 ,  C08L2205/03

摘要： Polymeric compositions comprising polyvinylidene fluoride and one or more acrylic components are described. The compositions can be formed into films which do not require a carrier or other backing. Also described are methods for forming the films and applications for the films.

摘要翻译： 描述了包含聚偏二氟乙烯和一种或多种丙烯酸组分的聚合物组合物。 组合物可以形成不需要载体或其它背衬的膜。 还描述了用于形成膜的方法和用于膜的方法。

公开(公告)号：US20140113117A1

公开(公告)日：2014-04-24

申请号：US14059964

申请日：2013-10-22

申请人： William J. Buehne

发明人： William J. Buehne

IPC分类号： E04C2/20

CPC分类号： E04C2/20 ,  B32B2264/10 ,  B32B2264/102 ,  B32B2264/105 ,  B32B2307/416 ,  B32B2307/712 ,  E04F13/0866 ,  Y10T428/24802 ,  Y10T428/24901 ,  Y10T428/24975 ,  Y10T428/265 ,  Y10T428/31699 ,  Y10T428/31928 ,  Y10T428/31935

摘要： The present invention relates to a plastic panel construction with improved resistance to heat build. An outdoor weatherable panel comprises a substrate having an upper surface, a decorative layer disposed about the upper surface of the substrate, and a size coat layer disposed between the decorative layer and the substrate, where the size coat layer comprises an additive that is reflective to infrared radiation, ultraviolet radiation, or both. The additive can be a color pigment, a white pigment, a metallic pigment, or a combination of two of more thereof. The modified size coat layer provides a construction with excellent properties and improved resistance to heat build.

摘要翻译： 本发明涉及一种具有改进的抗热构造性能的塑料面板结构。 室外耐候性面板包括具有上表面的基板，围绕基板的上表面设置的装饰层以及设置在装饰层和基板之间的尺寸涂层，其中尺寸涂层包括反射至 红外辐射，紫外线辐射或两者。 添加剂可以是彩色颜料，白色颜料，金属颜料或其中两种以上的组合。 改性尺寸涂层提供了具有优异性能和改进的耐热性能的结构。

公开(公告)号：US20120240973A1

公开(公告)日：2012-09-27

申请号：US13512612

申请日：2010-12-15

申请人： William J. Buehne

发明人： William J. Buehne

IPC分类号： B32B27/08 ,  B32B27/30 ,  H01L31/18 ,  H01L31/02 ,  H01L31/042

CPC分类号： C08F214/262 ,  C08L27/16 ,  C08L33/04 ,  C09D127/16 ,  H01L31/049 ,  Y02E10/50 ,  Y10T428/3154 ,  C08L2666/06

摘要： Backsheets and coating compositions for forming such are described which are useful in photovoltaic modules. Various coating compositions are described which provide improved properties for the backsheet.

摘要翻译： 描述了用于形成这样的底片和涂料组合物，其可用于光伏模块。 描述了为底片提供改进的性能的各种涂料组合物。

公开(公告)号：US5518786A

公开(公告)日：1996-05-21

申请号：US278722

申请日：1994-07-21

申请人： John R. Johnson ,  Keith L. Truog ,  Howard H. Enlow ,  William J. Buehne ,  Frederick Young

发明人： John R. Johnson ,  Keith L. Truog ,  Howard H. Enlow ,  William J. Buehne ,  Frederick Young

IPC分类号： B05D7/24 ,  B05D1/28 ,  B05D7/00 ,  B05D7/14 ,  B32B7/12 ,  B32B27/00 ,  B32B27/20 ,  B32B27/22 ,  B32B27/30 ,  B32B27/36 ,  B32B37/00 ,  C09J7/02

CPC分类号： B32B37/02 ,  B05D1/286 ,  B05D7/57 ,  B29C63/0047 ,  B29K2995/0022 ,  B32B2037/243 ,  B32B2307/402 ,  B32B2307/406 ,  B32B2307/71 ,  B32B2309/027 ,  B32B2327/06 ,  B32B2327/12 ,  B32B2333/08 ,  B32B2605/003 ,  B32B37/12 ,  B32B37/203 ,  Y10T428/1424 ,  Y10T428/1471 ,  Y10T428/1476 ,  Y10T428/1486 ,  Y10T428/2848 ,  Y10T428/2852

摘要： A flexible decorative sheet for use in surfacing an automobile body panel includes a first polyester carrier sheet having a high gloss surface, a clear coat of a weatherable optically-clear polymer containing fluorocarbon resin and an acrylic resin coated on the surface of the first carrier sheet, a tie coat on the clear coat, and a color coat containing a chlorinated polymer with dispersed pigments cast on the tie coat and dried. A pressure-sensitive adhesive layer is formed on a second polyester carrier sheet and then laminated to the exposed face of the color coat to form a pressure-sensitive, adhesive-backed composite paint coat between the outer carrier sheets which form protective removable backing sheets for the resulting laminate. The decorative sheet is applied to a substrate panel by pressure-sensitive adhesive bonding techniques, with the clear coat serving as a glossy, weatherable protective outer layer for the underlying color coat. The PVC-containing color coat enhances room temperature elongation of the finished film to enable application of the laminate to three-dimensionally contoured surfaces. The resulting paint finish has a defect-free, weatherable and durable outer surface with high gloss and high distinctness of image, meeting requirements for exterior automotive use.

摘要翻译： 用于表面车身板的柔性装饰板包括具有高光泽表面的第一聚酯载体片，包含氟碳树脂的耐候性光学透明聚合物的透明涂层和涂覆在第一载体片表面上的丙烯酸树脂 ，透明涂层上的连接涂层，以及含有分散颜料的氯化聚合物的颜色涂层，并涂布在连接层上并干燥。 在第二聚酯载体片材上形成压敏粘合剂层，然后层压到着色涂层的暴露面上，以在外部载体片材之间形成压敏粘合剂背衬的复合涂料涂层，其形成用于 得到的层压板。 通过压敏粘合技术将装饰片施加到基板上，其中透明涂层用作底层彩色涂层的光滑，耐候性保护外层。 含PVC的彩色涂层提高了成品薄膜的室温伸长率，从而能够将层压体应用于三维轮廓表面。 所得的漆面具有无缺陷，耐候性和耐用的外表面，具有高光泽度和高清晰度的图像，满足汽车外部使用的要求。

公开(公告)号：US5490893A

公开(公告)日：1996-02-13

申请号：US316818

申请日：1994-10-03

申请人： Howard H. Enlow ,  Scott W. Huffer ,  Frederick Young ,  William J. Buehne

发明人： Howard H. Enlow ,  Scott W. Huffer ,  Frederick Young ,  William J. Buehne

IPC分类号： B05D1/04 ,  B32B27/08 ,  B32B37/20 ,  B32B38/12 ,  B44C1/165

CPC分类号： B32B37/203 ,  B05D1/045 ,  B32B27/08 ,  B32B2307/302 ,  B32B2307/408 ,  B32B38/12 ,  Y10S428/934 ,  Y10T428/31551 ,  Y10T428/31554 ,  Y10T428/31562 ,  Y10T428/31565 ,  Y10T428/31576 ,  Y10T428/3158 ,  Y10T428/31587 ,  Y10T428/31786 ,  Y10T428/31797 ,  Y10T428/31935

摘要： A process for making a thermoformable conductive plastic laminate for use in making plastic parts adapted for electrostatic spray painting of a uniform high quality paint finish includes forming a matte release coated casting sheet, casting an electrically conductive polymer in thin film form on the casting sheet, drying to form a conductive primer coat, and transfer-laminating the conductive coating to a thin, thermoformable plastic face sheet. The matte release coat has a fine particulate filler that transfers a micro-roughened matte surface to the conductive primer coat. The conductive primer includes a polyester resin containing a fine particulate conductive material such as carbon black and, preferably, an anti-blocking agent such as fumed silica. The primer coated face sheet can be thermoformed and bonded to a underlying plastic substrate panel. The conductive primer has sufficient elongation and maintains uniform electrical surface conductivity and film thickness throughout the transfer-laminating, thermoforming and substrate panel-cladding process. The uniform surface resistivity of the conductive primer film is sufficient to permit electrostatic spray painting of the finished contoured panel and in one embodiment produces a Class "A" quality exterior automotive paint finish on the resulting panel.

公开(公告)号：US09200448B2

公开(公告)日：2015-12-01

申请号：US14059964

申请日：2013-10-22

申请人： William J. Buehne

发明人： William J. Buehne

IPC分类号： E04C2/20 ,  E04F13/08

CPC分类号： E04C2/20 ,  B32B2264/10 ,  B32B2264/102 ,  B32B2264/105 ,  B32B2307/416 ,  B32B2307/712 ,  E04F13/0866 ,  Y10T428/24802 ,  Y10T428/24901 ,  Y10T428/24975 ,  Y10T428/265 ,  Y10T428/31699 ,  Y10T428/31928 ,  Y10T428/31935

摘要： The present invention relates to a plastic panel construction with improved resistance to heat build. An outdoor weatherable panel comprises a substrate having an upper surface, a decorative layer disposed about the upper surface of the substrate, and a size coat layer disposed between the decorative layer and the substrate, where the size coat layer comprises an additive that is reflective to infrared radiation, ultraviolet radiation, or both. The additive can be a color pigment, a white pigment, a metallic pigment, or a combination of two of more thereof. The modified size coat layer provides a construction with excellent properties and improved resistance to heat build.

摘要翻译： 本发明涉及一种具有改进的抗热构造性能的塑料面板结构。 室外耐候性面板包括具有上表面的基板，围绕基板的上表面设置的装饰层以及设置在装饰层和基板之间的尺寸涂层，其中尺寸涂层包括反射至 红外辐射，紫外线辐射或两者。 添加剂可以是彩色颜料，白色颜料，金属颜料或其中两种以上的组合。 改性尺寸涂层提供了具有优异性能和改进的耐热性能的结构。

公开(公告)号：US20110123753A1

公开(公告)日：2011-05-26

申请号：US12846998

申请日：2010-07-30

申请人： Linwood G. KOGER ,  William J. BUEHNE ,  Le-Hoa HONG ,  Iliana VELAZQUEZ ,  Tamara L. McCARTNEY ,  Wendy SHUTTLEWORTH ,  Anahit TATARYAN ,  Vikaas GUPTA

发明人： Linwood G. KOGER ,  William J. BUEHNE ,  Le-Hoa HONG ,  Iliana VELAZQUEZ ,  Tamara L. McCARTNEY ,  Wendy SHUTTLEWORTH ,  Anahit TATARYAN ,  Vikaas GUPTA

IPC分类号： B32B33/00 ,  B32B27/36

CPC分类号： G03G7/0013 ,  B32B7/06 ,  B32B7/12 ,  B32B27/08 ,  B32B27/20 ,  B32B27/36 ,  B32B29/00 ,  B32B2255/10 ,  B32B2255/20 ,  B32B2264/102 ,  B32B2307/406 ,  B32B2307/41 ,  B32B2307/75 ,  B32B2519/00 ,  B41M5/504 ,  B41M5/508 ,  B41M5/5218 ,  B41M2205/34 ,  G03G7/00 ,  G03G7/0053 ,  G03G7/008 ,  G03G7/0086 ,  G09F3/02 ,  G09F3/10 ,  G09F2003/0201 ,  G09F2003/0241 ,  Y10T428/14

摘要： A multilayer laminate such as a label assembly having high opacity and desirable appearance characteristics is described. The laminate includes a facestock layer, an adhesive layer, and a liner layer. The facestock layer includes a print-receiving top coat layer that includes a combination of titanium dioxide and one or more optical brighteners. The combination of these materials avoids build up of static charges upon laser printing on the facestock.

摘要翻译： 描述了具有高不透明度和理想外观特征的多层层压体，例如标签组件。 层压体包括面层，粘合剂层和衬里层。 面层包括印刷接收面涂层，其包括二氧化钛和一种或多种荧光增白剂的组合。 这些材料的组合避免了在面材上激光打印时产生静电荷。

公开(公告)号：US5686186A

公开(公告)日：1997-11-11

申请号：US487488

申请日：1995-06-07

申请人： Howard H. Enlow ,  Scott W. Huffer ,  Frederick Young ,  William J. Buehne

发明人： Howard H. Enlow ,  Scott W. Huffer ,  Frederick Young ,  William J. Buehne

IPC分类号： B05D1/04 ,  B32B27/08 ,  B32B37/20 ,  B32B38/12 ,  B32B27/00

CPC分类号： B32B37/203 ,  B05D1/045 ,  B32B27/08 ,  B32B2307/302 ,  B32B2307/408 ,  B32B38/12 ,  Y10S428/934 ,  Y10T428/31551 ,  Y10T428/31554 ,  Y10T428/31562 ,  Y10T428/31565 ,  Y10T428/31576 ,  Y10T428/3158 ,  Y10T428/31587 ,  Y10T428/31786 ,  Y10T428/31797 ,  Y10T428/31935

摘要： A process for making a thermoformable conductive plastic laminate for use in making plastic parts adapted for electrostatic spray painting of a uniform high quality paint finish includes forming a matte release coated casting sheet, casting an electrically conductive polymer in thin film form on the casting sheet, drying to form a conductive primer coat, and transfer-laminating the conductive coating to a thin, thermoformable plastic face sheet. The matte release coat has a fine particulate filler that transfers a micro-toughened matte surface to the conductive primer coat. The conductive primer includes a polyester resin containing a fine particulate conductive material such as carbon black and, preferably, an anti-blocking agent such as fumed silica. The primer coated face sheet can be thermoformed and bonded to a underlying plastic substrate panel. The conductive primer has sufficient elongation and maintains uniform electrical surface conductivity and film thickness throughout the transfer-laminating, thermoforming and substrate panel-cladding process. The uniform surface resistivity of the conductive primer film is sufficient to permit electrostatic spray painting of the finished contoured panel and in one embodiment produces a Class "A" quality exterior automotive paint finish on the resulting panel.

摘要翻译： 制造用于制造适于静电喷涂均匀的高质量涂漆的塑料部件的可热成型导电塑料层压体的方法包括形成无光泽涂布的流延片，在铸片上铸造薄膜形式的导电聚合物， 干燥以形成导电底漆，并将导电涂层转移层压到薄的可热成形的塑料面板上。 无光泽的脱模涂层具有细微的颗粒填料，其将微钢化的无光泽表面转移到导电底漆涂层。 导电底漆包括含有细颗粒导电材料如碳黑的聚酯树脂，以及优选的防粘连剂如热解法二氧化硅。 底漆涂布的面板可以热成型并结合到下面的塑料基板。 导电底漆具有足够的伸长率，并且在整个转移层压，热成型和衬底面板包层过程中均具有均匀的电表面导电性和膜厚度。 导电底漆膜的均匀表面电阻足以允许成品轮廓面板的静电喷涂，并且在一个实施例中，在所得面板上产生“A”级外部汽车漆面。