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    Process for the preparation of dimethylether from hydrocarbons
    2.
    发明授权
    Process for the preparation of dimethylether from hydrocarbons 有权
    从碳氢化合物制备二甲醚的方法

    公开(公告)号：US07211606B2

    公开(公告)日：2007-05-01

    申请号：US11450580

    申请日：2006-06-10

    申请人： Young Soon Baek ,  Won Ihl Cho ,  Byoung Hak Cho ,  Jung Chul Suh ,  Dong Hyuk Kim ,  Hyung Gyu Kim ,  Seung Ho Lee ,  Woo Sung Ju

    发明人： Young Soon Baek ,  Won Ihl Cho ,  Byoung Hak Cho ,  Jung Chul Suh ,  Dong Hyuk Kim ,  Hyung Gyu Kim ,  Seung Ho Lee ,  Woo Sung Ju

    IPC分类号： C07C27/00

    CPC分类号： C07C41/09 ,  C07C41/01 ,  C07C43/043

    摘要： Disclosed herein is a process for the preparation of dimethylether from hydrocarbons, including tri-reforming a feedstock mixture comprised of hydrocarbons, carbon dioxide and water vapor in the presence of a tri-reforming catalyst, to prepare a syngas, which then undergoes gas-phase direct synthesis into dimethylether in one step in the presence of a hybrid catalyst. According to the process of this invention, three main processes among typical syngas preparation processes are simultaneously performed, and then, the syngas thus obtained is prepared into dimethylether through a direct reaction in one step, thereby decreasing the apparatus cost and operation cost. In addition, all of the carbon dioxide separated and recovered from the unreacted material and by-products may be reused as reaction material, thus decreasing the generation of carbon dioxide and reducing the material cost.

    摘要翻译： 本文公开了一种从烃制备二甲醚的方法，包括在三重转化催化剂的存在下，由烃，二氧化碳和水蒸气组成的原料混合物进行三重重整，以制备合成气，然后将其合成气相 在混合催化剂存在下，在一个步骤中直接合成二甲醚。 根据本发明的方法，同时进行典型的合成气制备过程中的三个主要过程，然后通过一步直接反应将由此获得的合成气制备成二甲醚，从而降低设备成本和操作成本。 此外，从未反应的物质和副产物中分离回收的二氧化碳全部可以作为反应物质再利用，从而减少二氧化碳的产生并降低材料成本。

    Method of producing a catalyst used for synthesizing dimethylether from a synthesis gas containing carbon dioxide
    3.
    发明授权
    Method of producing a catalyst used for synthesizing dimethylether from a synthesis gas containing carbon dioxide 有权
    制备用于从含二氧化碳的合成气中合成二甲醚的催化剂的方法

    公开(公告)号：US08450234B2

    公开(公告)日：2013-05-28

    申请号：US11678092

    申请日：2007-02-23

    申请人： Young Soon Baek ,  Won Jun Cho ,  Yun Bin Yan ,  Yong Gi Mo ,  Kyung Hae Lee ,  Eun Mee Jang

    发明人： Young Soon Baek ,  Won Jun Cho ,  Yun Bin Yan ,  Yong Gi Mo ,  Kyung Hae Lee ,  Eun Mee Jang

    IPC分类号： B01J27/25 ,  C07C1/04

    CPC分类号： B01J27/25 ,  B01J23/80 ,  B01J23/825 ,  B01J27/16 ,  B01J35/0006 ,  B01J37/03 ,  B01J37/04 ,  C07C1/048 ,  C07C41/09 ,  C07C2523/54 ,  C07C43/043

    摘要： The present invention relates to a catalyst used for producing dimethylether, a method of producing the same, and a method of producing dimethylether using the same. More particularly, the present invention relates to a catalyst used for producing dimethylether comprising a methanol synthesis catalyst produced by adding one or more promoters to a main catalyst comprised of a Cu—Zn—Al metal component and a dehydration catalyst formed by mixing Aluminum Phosphate (AlPO4) with gamma alumina, a method of producing the same, and a method of producing dimethylether using the same, wherein a ratio of the main catalyst to the promoter in the methanol synthesis catalyst is in a range of 99/1 to 95/5, and a mixing ratio of the methanol synthesis catalyst to the dehydration catalyst is in a range of 60/40 to 70/30.

    摘要翻译： 本发明涉及用于制备二甲醚的催化剂，其制备方法和使用其制备二甲醚的方法。 更具体地说，本发明涉及用于生产二甲醚的催化剂，其包括通过将一种或多种促进剂加入到由Cu-Zn-Al金属组分构成的主催化剂和通过混合磷酸铝形成的脱水催化剂 AlPO 4），其制造方法以及使用其制造二甲醚的方法，其中甲醇合成催化剂中的主催化剂与助催化剂的比例在99/1〜95/5的范围内 ，甲醇合成催化剂与脱水催化剂的混合比在60/40〜70/30的范围内。

    METHOD OF PRODUCING A CATALYST USED FOR SYNTHESIZING DIMETHYLETHER FROM A SYNTHESIS GAS CONTAINING CARBON DIOXIDE
    4.
    发明申请
    METHOD OF PRODUCING A CATALYST USED FOR SYNTHESIZING DIMETHYLETHER FROM A SYNTHESIS GAS CONTAINING CARBON DIOXIDE 有权
    生产用于合成含二氧化碳合成气的二甲醚的催化剂的制备方法

    公开(公告)号：US20080125311A1

    公开(公告)日：2008-05-29

    申请号：US11678092

    申请日：2007-02-23

    申请人： Young Soon BAEK ,  Won Jun CHO ,  Yun Bin YAN ,  Yong Gi MO ,  Kyung Hae LEE ,  Eun Mee JANG

    发明人： Young Soon BAEK ,  Won Jun CHO ,  Yun Bin YAN ,  Yong Gi MO ,  Kyung Hae LEE ,  Eun Mee JANG

    IPC分类号： B01J27/25 ,  C07C27/00

    CPC分类号： B01J27/25 ,  B01J23/80 ,  B01J23/825 ,  B01J27/16 ,  B01J35/0006 ,  B01J37/03 ,  B01J37/04 ,  C07C1/048 ,  C07C41/09 ,  C07C2523/54 ,  C07C43/043

    摘要： The present invention relates to a catalyst used for producing dimethylether, a method of producing the same, and a method of producing dimethylether using the same. More particularly, the present invention relates to a catalyst used for producing dimethylether comprising a methanol synthesis catalyst produced by adding one or more promoters to a main catalyst comprised of a Cu—Zn—Al metal component and a dehydration catalyst formed by mixing Aluminum Phosphate (AlPO4) with gamma alumina, a method of producing the same, and a method of producing dimethylether using the same, wherein a ratio of the main catalyst to the promoter in the methanol synthesis catalyst is in a range of 99/1 to 95/5, and a mixing ratio of the methanol synthesis catalyst to the dehydration catalyst is in a range of 60/40 to 70/30.

    摘要翻译： 本发明涉及用于制备二甲醚的催化剂，其制备方法和使用其制备二甲醚的方法。 更具体地说，本发明涉及用于生产二甲醚的催化剂，其包括通过将一种或多种促进剂加入到由Cu-Zn-Al金属组分构成的主催化剂和通过混合磷酸铝形成的脱水催化剂 AlPO 4）与其制备方法，以及使用其制备二甲醚的方法，其中甲醇合成催化剂中主催化剂与助催化剂的比例在一个范围内 为99/1〜95/5，甲醇合成催化剂与脱水催化剂的混合比为60/40〜70/30。