公开(公告)号：US20230014154A1

公开(公告)日：2023-01-19

申请号：US17781613

申请日：2020-12-01

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Ken Egashira

IPC: C08G18/75 ,  C08G18/32 ,  C08G18/72

Abstract: Provided is a decorative film having excellent weather resistance, scratch resistance, and elongation properties, and a decorative article using the same, and a surface protective composition that can exhibit such properties. A decorative film according to one embodiment of the present disclosure includes a surface protective layer. The surface protective layer contains a polyurethane resin obtained by reacting a composition containing a polycarbonate diol, and a trimer or higher multimer of a diisocyanate including a cyclohexane structure, a diisocyanate including a cyclohexane structure or a prepolymer thereof, or a mixture thereof, and the decorative film satisfies Formulas 1 to 3 below: 0≤X1≤2.00 . . . Formula 1 X1≤−0.7×X2+4.67 . . . Formula 2 X1≥−0.7×X2+2.14 . . . Formula 3 where X1 is a numerical value obtained by multiplying the number of branches from a branch point relative to a converted molecular weight of the polyurethane resin by 1000, and X2 is a numerical value obtained by multiplying the number of cyclohexane structure portions included in the polyurethane resin relative to the converted molecular weight of the polyurethane resin by 1000.

公开(公告)号：US20150321452A1

公开(公告)日：2015-11-12

申请号：US14655367

申请日：2013-12-19

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Ken Egashira

IPC: B32B15/095 ,  B29C45/14 ,  B29C43/56 ,  B32B27/40 ,  B32B7/12 ,  B32B15/085 ,  B32B27/32 ,  B29C47/02 ,  B29C43/18

Abstract: A decorative laminated sheet with excellent scratch resistance that is capable of adhering to a polyolefin-based resin substrate, and that is a hardly adhesive material, through an extrusion method, a vacuum-pressure molding method, a mold integrated injection molding method, and the like. The decorative laminated sheet includes a surface layer, a design layer, and an adhesive layer containing a polymer having a propylene unit of 85 mass % or more, in that order.

Abstract translation: 通过挤出法，真空压力成型法，模具一体注射成型法以及能够粘附在聚烯烃系树脂基板上的难以粘附的耐刮擦性的装饰性层压片， 喜欢。 装饰性层压片依次包括表面层，设计层和含有丙烯单元的聚合物的粘合剂层的85质量％以上。

公开(公告)号：US20220203599A1

公开(公告)日：2022-06-30

申请号：US17698156

申请日：2022-03-18

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Ken Egashira

IPC: B29C53/84 ,  B29C51/14 ,  B29C53/00 ,  B29C53/04 ,  B32B37/12 ,  B32B38/00 ,  B29C53/02

Abstract: A method for manufacturing a sheet laminate to be affixed to an adherent surface of an object, the method comprising preparing a sheet member having a front surface to become a design surface and a rear surface on which an adhesive part has been formed, bending an edge part of the sheet member by sandwiching the sheet member from a front surface side and a rear surface side in a mold, and heating a part of a bent sheet member. The sheet laminate has a flat part spreading out in a flat plate shape, a side surface on which the edge part bent by the bending step is configured, and a connecting surface protruding and curving toward the front surface side between the flat part and the side surface, and in the heating step, the connecting surface is partially heated after the side surface is molded in the bending step.

公开(公告)号：US10590303B2

公开(公告)日：2020-03-17

申请号：US15328530

申请日：2015-07-24

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Charlie C. Ho ,  Robert D. Hamann ,  Jeremy P. Gundale ,  Vijay Rajamani ,  Ken Egashira ,  Chia Hui Lin ,  Hsi Shou Kuo

IPC: C09D175/06 ,  B29C48/08 ,  B29C48/00 ,  B32B7/12 ,  B32B27/40 ,  B29C51/14 ,  C08G18/75 ,  C08G18/42 ,  B32B27/08 ,  B32B27/30 ,  C08G18/66 ,  B32B27/36 ,  C09J7/25 ,  B29C51/10 ,  B29K75/00 ,  B29L9/00 ,  B29L31/30 ,  B29L31/00

Abstract: Disclosed herein are improved thermoplastic polyurethane compositions, articles, and related methods. These compositions include aliphatic thermoplastic polyurethanes having a hard segment content ranging from 57 percent to 80 percent by weight. The hard coat compositions have a Shore D hardness of at least 70 and can display an Elongation at Break test result at 25 degrees Celsius of at least 150 percent. These materials, when hardened, can serve decorative and/or protective functions while displaying both a high degree of elongation at moderate temperatures and high hardness.

公开(公告)号：US20170357039A1

公开(公告)日：2017-12-14

申请号：US15537302

申请日：2015-12-17

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Saori Ueda ,  Toshitaka Nakajima ,  Yorinobu Takamatsu ,  Ken Egashira ,  Koji Saito

IPC: G02B5/20 ,  B60R13/10

CPC classification number: G02B5/208 ,  B60R13/10 ,  G02B1/04 ,  G02B5/124 ,  C08L75/04

Abstract: The disclosed retroreflective sheet contains a retroreflective layer and a polyurethane surface protecting layer, wherein the surface protecting layer contains at least a reaction product of a polyol with either a polyester backbone or a polycarbonate backbone and a trifunctional or higher aliphatic isocyanate, and the glass transition temperature Tg of the surface protecting layer is 50° C. or higher, and the tan δ of the loss tangent at 120° C. is 0.1 or less.

公开(公告)号：US20240018371A1

公开(公告)日：2024-01-18

申请号：US18035964

申请日：2021-11-22

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Keisuke Kato ,  Shinsuke Kondo ,  Ken Egashira ,  Naota Sugiyama ,  Yorinobu Takamatsu ,  Yusaku Yoshiike ,  Masaaki Furusawa

IPC: C09D7/65 ,  C09D5/00 ,  C09D7/42 ,  C09D7/40 ,  C09D5/16 ,  C09D175/04 ,  B32B27/30 ,  B32B27/36 ,  B32B27/08 ,  B32B27/22

CPC classification number: C09D7/65 ,  C09D5/00 ,  C09D7/42 ,  C09D7/69 ,  C09D5/1637 ,  C09D175/04 ,  B32B27/304 ,  B32B27/36 ,  B32B27/08 ,  B32B27/22 ,  B32B2255/10 ,  B32B2255/26 ,  B32B2307/584 ,  B32B2307/408 ,  B32B2451/00

Abstract: Provided is a laminate including a surface layer that has excellent matte properties and can obtain good results in both the needle scratch test and the nail scratch test, and a surface coating composition that can prepare such a surface layer.

公开(公告)号：US10730268B2

公开(公告)日：2020-08-04

申请号：US14655367

申请日：2013-12-19

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Ken Egashira

IPC: B32B15/095 ,  B29C45/14 ,  B29C43/56 ,  B29C43/18 ,  B32B15/085 ,  B29C48/15 ,  B32B7/12 ,  B32B27/40 ,  B32B27/32 ,  B44C5/04 ,  B44C1/10 ,  B32B15/08 ,  B32B27/36 ,  B32B27/08 ,  B29K75/00 ,  B29K105/00 ,  B29L9/00 ,  B29L31/00

Abstract: A decorative laminated sheet with excellent scratch resistance that is capable of adhering to a polyolefin-based resin substrate, and that is a hardly adhesive material, through an extrusion method, a vacuum-pressure molding method, a mold integrated injection molding method, and the like. The decorative laminated sheet includes a surface layer, a design layer, and an adhesive layer containing a polymer having a propylene unit of 85 mass % or more, in that order.

公开(公告)号：US20200047398A1

公开(公告)日：2020-02-13

申请号：US16499628

申请日：2018-03-26

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Ken Egashira

IPC: B29C63/04 ,  B29C63/00 ,  B29C53/34 ,  B29C53/84 ,  B32B27/36 ,  B32B27/40 ,  B32B7/022

Abstract: A sheet laminate that can be easily affixed to a bonded surface and which can enhance handleability. The sheet laminate (1) includes a pair of sidewall parts (3), each extending toward the rear surface (2b) side from a pair of mutually opposing edges of the main body part (2). The pair of sidewall parts 3 have a curved shape projecting outward with respect to the main body part (2). Including such a sidewall part (3) makes it possible to affix the sheet laminate (1) to the B-pillar (50) by sandwiching the side surfaces (50b) of both sides of the B-pillar (50) having a bonded surface (50a) by using the curved shape of the pair of sidewall parts (3) while covering the bonded surface (50a) with the design surface of the main body part (2). As a result, the sheet laminate (1) can be affixed easily to the bonded surface (50a), which enhances handleability of the sheet laminate (1).

公开(公告)号：US10365418B2

公开(公告)日：2019-07-30

申请号：US15537302

申请日：2015-12-17

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Saori Ueda ,  Toshitaka Nakajima ,  Yorinobu Takamatsu ,  Ken Egashira ,  Koji Saito

IPC: G02B1/04 ,  G02B5/20 ,  B60R13/10 ,  C08L75/04 ,  G02B5/124

Abstract: The disclosed retroreflective sheet contains a retroreflective layer and a polyurethane surface protecting layer, wherein the surface protecting layer contains at least a reaction product of a polyol with either a polyester backbone or a polycarbonate backbone and a trifunctional or higher aliphatic isocyanate, and the glass transition temperature Tg of the surface protecting layer is 50° C. or higher, and the tan δ of the loss tangent at 120° C. is 0.1 or less.

公开(公告)号：US11292181B2

公开(公告)日：2022-04-05

申请号：US16470403

申请日：2017-12-19

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Ken Egashira

IPC: B29C53/84 ,  B29C51/14 ,  B29C53/00 ,  B29C53/04 ,  B32B37/12 ,  B32B38/00 ,  B29C53/02 ,  B29K105/00 ,  B32B27/08 ,  B32B27/36 ,  B32B37/26

Abstract: A method for manufacturing a sheet laminate to be affixed to an adherent surface of an object, the method comprising preparing a sheet member having a front surface to become a design surface and a rear surface on which an adhesive part has been formed, bending an edge part of the sheet member by sandwiching the sheet member from a front surface side and a rear surface side in a mold, and heating a part of a bent sheet member. The sheet laminate has a flat part spreading out in a flat plate shape, a side surface on which the edge part bent by the bending step is configured, and a connecting surface protruding and curving toward the front surface side between the flat part and the side surface, and in the heating step, the connecting surface is partially heated after the side surface is molded in the bending step.