公开(公告)号：US09320685B2

公开(公告)日：2016-04-26

申请号：US14707096

申请日：2015-05-08

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： William H. Moser ,  Guy D. Joly ,  Larry R. Krepski ,  Babu N. Gaddam ,  Ahmed S. Abuelyaman ,  Bradley D. Craig ,  Timothy D. Dunbar ,  Chuntao Cao ,  Joel D. Oxman ,  Afshin Falsafi ,  Hoa T. Bui

IPC: A61K6/083 ,  A61K6/00

CPC classification number: A61K6/083 ,  A61K6/0023 ,  A61K6/0029 ,  A61K6/005 ,  C08L33/10

Abstract: Dental compositions are described comprising an addition-fragmentation agent of the formula: wherein R1, R2 and R3 are each independently Zm-Q-, a (hetero)alkyl group or a (hetero)aryl group with the proviso that at least one of R1, R2 and R3 is Zm-Q-; Q is a linking group have a valence of m+1; Z is an ethylenically unsaturated polymerizable group; m is 1 to 6; each X1 is independently —O— or —NR4—, where R4 is H or C1-C4 alkyl; and n is 0 or 1. Also described are dental articles prepared from a dental composition comprising an addition-fragmentation agent and methods of treating a tooth surface.

Abstract translation: 描述了牙科组合物，其包含下式的加成断裂剂：其中R 1，R 2和R 3各自独立地为Zm-Q-，（杂）烷基或（杂）芳基，条件是R 1 ，R2和R3是Zm-Q-; Q是连接基团，其价态为m + 1; Z是烯属不饱和可聚合基团; m为1〜6; 每个X 1独立地是-O-或-NR 4 - ，其中R 4是H或C 1 -C 4烷基; 并且n为0或1.还描述了由包含加成碎裂剂的牙科组合物制备的牙科用品和治疗牙齿表面的方法。

公开(公告)号：US20150368524A1

公开(公告)日：2015-12-24

申请号：US14758987

申请日：2014-03-03

Applicant: 3M Innovative Properties Company

Inventor： Arlin L. Weikel ,  Babu N. Gaddam ,  Larry R. Krepski ,  Wayne S. Mahoney ,  Jason D. Clapper

IPC: C09J133/08

CPC classification number: C09J133/08 ,  C08L63/00 ,  C08L2312/00 ,  C09J7/385 ,  C09J133/068 ,  Y10T428/2809

Abstract: Adhesive compositions and methods of preparing an adhesive composition are described. The method comprises providing a syrup composition comprising a free-radically polymerizable solvent monomer and a solute (meth)acrylic copolymer, and radiation curing the syrup composition in the absence of an ionic photoacid generator. The solute (meth)acrylic copolymer comprises epoxy-functional groups, acid-functional groups, or a combination thereof. In some embodiments, an epoxy resin having on average greater than one polymerizable epoxy group per molecule or an acid comprising at least two carboxylic acid groups is utilized. The epoxy-functional groups and acid-functional groups of the (meth)acrylic copolymer or the adhesive composition can readily crosslink in the absence of an ionic photoacid generator (PAG).

Abstract translation: 描述了粘合剂组合物和制备粘合剂组合物的方法。 该方法包括提供包含可自由基聚合的溶剂单体和溶质（甲基）丙烯酸共聚物的糖浆组合物，并且在不存在离子型光酸产生剂的情况下辐射固化糖浆组合物。 溶质（甲基）丙烯酸共聚物包含环氧官能团，酸官能团或其组合。 在一些实施方案中，使用每分子平均具有大于1个可聚合环氧基团的环氧树脂或包含至少两个羧酸基团的酸。 （甲基）丙烯酸共聚物或粘合剂组合物的环氧官能团和酸官能团可以在不存在离子光酸产生剂（PAG）的情况下容易地交联。

公开(公告)号：US20150284538A1

公开(公告)日：2015-10-08

申请号：US14437204

申请日：2013-11-04

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Guy D. Joly ,  Ahmed S. Abuelyaman ,  Ann R. Fornof ,  Bradley D. Craig ,  Larry R. Krepski ,  William H. Moser ,  Serkan Yurt ,  Joel D. Oxman

IPC: C08K5/5455 ,  C07F7/18

CPC classification number: C08K5/5455 ,  C07F7/1804 ,  C07F7/1892 ,  C08F2/38 ,  C08F230/08 ,  C08F2438/01 ,  C08F2438/03 ,  C09J4/06

Abstract: Addition-fragmentation agents of the formula are disclosed having the following functional groups: 1) a labile addition-fragmentation group that can cleave and reform to relieve strain, 2) at least two surface-binding functional groups that associate with the surface of a substrate.

Abstract translation: 公开了具有以下官能团的式的加成 - 裂解剂：1）可以切割和改性以减轻应变的不稳定的加成断裂基团，2）与底物表面缔合的至少两个表面结合官能团 。

公开(公告)号：US20130196152A1

公开(公告)日：2013-08-01

申请号：US13798807

申请日：2013-03-13

Applicant: 3M Innovative Properties Company

Inventor： Wayne S. Mahoney ,  Arlin L. Weikel ,  Larry R. Krepski ,  Babu N. Gaddam

IPC: C09J133/14 ,  C09J7/02

CPC classification number: C09J133/14 ,  C08G59/3209 ,  C08G59/68 ,  C08L33/062 ,  C08L63/00 ,  C09J7/38 ,  C09J7/385 ,  C09J133/062 ,  C09J163/00 ,  Y10T428/287

Abstract: A pre-adhesive composition is described comprising an acid-functional (meth)acryloyl copolymer and epoxy resin, which when crosslinked with or without using an ionic photoacid generator (PAG) provides a (e.g. pressure-sensitive) adhesive.

Abstract translation: 描述了一种预粘合剂组合物，其包含酸官能（甲基）丙烯酰基共聚物和环氧树脂，当与或不使用离子光酸产生剂（PAG）交联时，提供（例如压敏）粘合剂。

公开(公告)号：US09410030B2

公开(公告)日：2016-08-09

申请号：US14437204

申请日：2013-11-04

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Guy D. Joly ,  Ahmed S. Abuelyaman ,  Ann R. Fornof ,  Bradley D. Craig ,  Larry R. Krepski ,  William H. Moser ,  Serkan Yurt ,  Joel D. Oxman

IPC: C08K5/5455 ,  C08F230/08 ,  C09J4/06 ,  C07F7/18

CPC classification number: C08K5/5455 ,  C07F7/1804 ,  C07F7/1892 ,  C08F2/38 ,  C08F230/08 ,  C08F2438/01 ,  C08F2438/03 ,  C09J4/06

Abstract: Addition-fragmentation agents of the formula are disclosed having the following functional groups: 1) a labile addition-fragmentation group that can cleave and reform to relieve strain, 2) at least two surface-binding functional groups that associate with the surface of a substrate.

Abstract translation: 公开了具有以下官能团的式的加成 - 裂解剂：1）可以切割和改性以减轻应变的不稳定的加成断裂基团，2）与底物表面缔合的至少两个表面结合官能团 。

公开(公告)号：US20160206520A1

公开(公告)日：2016-07-21

申请号：US14915429

申请日：2014-09-05

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Ann R. Fornof ,  William H. Moser ,  Ahmed S. Abuelyaman ,  Guy D. Joly ,  Larry R. Krepski

IPC: A61K6/083 ,  A61K6/00 ,  C07C381/00

CPC classification number: A61K6/083 ,  A61K6/0023 ,  A61K6/0047 ,  A61K6/005 ,  A61K6/0052 ,  A61K6/0088 ,  C07C381/00 ,  C08F2/38 ,  C08F220/20 ,  C08F2438/03 ,  C08K5/38 ,  C08L33/10 ,  C08F2222/1013 ,  C08F2220/382

Abstract: The present disclosure provides addition-fragmentation oligomers of the general formula: The crosslinking oligomers of this disclosure provide stress relief by including labile crosslinks that can cleave and reform during the polymerization process.

Abstract translation: 本公开提供了通式的加成 - 断裂低聚物：本公开的交联低聚物通过包括可在聚合过程中切割和改性的不稳定交联而提供应力消除。

公开(公告)号：US09328110B2

公开(公告)日：2016-05-03

申请号：US14205114

申请日：2014-03-11

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Larry R. Krepski ,  Joseph F. Dellaria, Jr. ,  Daniel E. Duffy ,  Matthew R. Radmer ,  David T. Amos

IPC: C07D235/02 ,  C07D471/04 ,  C07D255/02 ,  C07D213/74 ,  C07D471/14

CPC classification number: C07D471/04 ,  C07D213/74 ,  C07D255/02 ,  C07D471/14

Abstract: Imidazo ring systems substituted at the 1-position, pharmaceutical compositions containing the compounds, intermediates, methods of making the compounds, and methods of use of these compounds as immunomodulators, for inducing cytokine biosynthesis in animals and in the treatment of diseases including viral and neoplastic diseases are disclosed.

Abstract translation: 在1位置取代的咪唑环体系，含有化合物的药物组合物，中间体，制备化合物的方法，以及这些化合物作为免疫调节剂的使用方法，用于诱导动物中的细胞因子生物合成和治疗包括病毒和肿瘤的疾病 疾病被披露。

公开(公告)号：US20160081887A1

公开(公告)日：2016-03-24

申请号：US14770103

申请日：2014-04-08

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Ahmed S. Abuelyaman ,  Ann R. Fornof ,  Larry R. Krepski ,  William H. Moser

IPC: A61K6/083 ,  A61C5/00 ,  A61C13/15 ,  A61K6/00

CPC classification number: A61K6/083 ,  A61C5/00 ,  A61C19/003 ,  A61K6/0005 ,  A61K6/0023 ,  A61K6/0047 ,  A61K6/0073 ,  A61K6/0835 ,  C08L33/10 ,  C08L33/08 ,  C08L33/00

Abstract: Provided are novel high refractive index monomers, and dental resins containing the same.

Abstract translation: 提供新颖的高折射率单体和含有它们的牙科树脂。

公开(公告)号：US09238702B1

公开(公告)日：2016-01-19

申请号：US14379767

申请日：2013-02-08

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Ann R. Fornof ,  Babu N. Gaddam ,  Hae-Seung Lee ,  Jason D. Clapper ,  Larry R. Krepski ,  Mary M. Caruso ,  Serkan Yurt

IPC: C09J7/02 ,  C09J133/14 ,  C08F220/68 ,  C08F222/10

CPC classification number: C08F222/10 ,  C09J7/385 ,  C09J133/14 ,  C08F2220/1858 ,  C08F220/06 ,  C08F2220/343

Abstract: The present disclosure provides an ionically crosslinkable composition comprising a (meth)acrylate copolymer component having pendant acid functional groups and pendant photobase functional groups. On exposure to light, the pendant photobase group photolyzes to provide a pendant amine group, that ionically crosslinks the copolymer.

Abstract translation: 本公开提供了包含具有侧链酸官能团和侧基光基官能团的（甲基）丙烯酸酯共聚物组分的可离子交联组合物。 在曝光时，侧基基团光聚合以提供使该共聚物离子交联的侧基胺基。

公开(公告)号：US20150328086A1

公开(公告)日：2015-11-19

申请号：US14652134

申请日：2013-11-27

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Ann R. Fornof ,  William H. Moser ,  Larry R. Krepski ,  Guy D. Joly ,  Ahmed S. Abuelyaman ,  Afshin Falsafi ,  Babu N. Gaddam

IPC: A61K6/083 ,  C09J133/14 ,  C08K3/36 ,  A61C19/06 ,  C07C67/26 ,  C07C271/16 ,  C07C269/02 ,  C09D133/14 ,  C07C69/604

CPC classification number: A61K6/0835 ,  A61C19/063 ,  A61K6/083 ,  C07C67/26 ,  C07C69/604 ,  C07C269/02 ,  C07C271/16 ,  C08F2/38 ,  C08F220/18 ,  C08F220/56 ,  C08F2438/03 ,  C08K3/36 ,  C09D133/14 ,  C09J133/14

Abstract: Addition-fragmentation oligomers of the general formula Z—By-A-(B-A)x-B-A-By—Z, where the A monomers units are derived from a diester or diacid, the B monomer units are derived from a difunctional monomer having functional groups co-reactive and at least one of the A or B monomers comprise a 1-methylene-3,3-dimethylpropyl group.

Abstract translation: 通式为Z-By-A-（BA）xBA-By-Z的加成裂解低聚物，其中A单体单元衍生自二酯或二酸，B单体单元衍生自具有官能团共轭的双官能单体 - 反应性的并且A或B单体中的至少一种包含1-亚甲基-3,3-二甲基丙基。