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公开(公告)号:US11597856B2
公开(公告)日:2023-03-07
申请号:US16066360
申请日:2016-12-13
发明人: Carsten Franke , Kenneth L. Smith , Jesse R. Behnke , Robert L. W. Smithson , Lucas D. Crestik , Olester Benson, Jr. , Alexander J. Huffman , Michael A. Kropp , John P. Baetzold , Serkan Yurt
IPC分类号: B29C64/00 , C09J7/38 , C09J7/20 , B05D3/06 , B33Y70/00 , B23K26/082 , B29C64/245 , B29C64/129 , B05D5/10 , B05D1/28 , B33Y10/00 , B33Y30/00 , B33Y80/00
摘要: A continuous method of manufacturing adhesives is provided. The method includes obtaining an actinic radiation-polymerizable adhesive precursor composition disposed on a major surface of an actinic radiation-transparent substrate and irradiating a first portion of the actinic radiation-polymerizable adhesive precursor composition through the actinic radiation-transparent substrate for a first irradiation dosage. The method further includes moving the actinic radiation-transparent substrate and irradiating a second portion of the actinic radiation-polymerizable adhesive precursor composition through the actinic radiation-transparent substrate for a second irradiation dosage. Optionally, the method also includes irradiating a third portion of the actinic radiation-polymerizable adhesive precursor composition through the actinic radiation-transparent substrate prior to moving the substrate. The first irradiation dosage and the third irradiation dosage are often not the same, thereby forming an integral adhesive having a variable thickness in an axis normal to the actinic radiation-transparent substrate.
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公开(公告)号:US20200087547A1
公开(公告)日:2020-03-19
申请号:US16471630
申请日:2017-12-19
发明人: Stephen B. Roscoe , Deepti Gopalakrishnan , Stefan H. Gryska , George W. Griesgraber , Serkan Yurt , Duane D. Fansler , Kevin M. Lewandowski , Joon Chatterjee , Hae-Seung Harry Lee , Babu N. Gaddam
IPC分类号: C09J7/38 , C08F265/06 , C09J11/08
摘要: Crosslinkable compositions are provided that contain a) a polymeric material having at least two terminal dithiocarbamate groups or two terminal dithiocarbonate groups and b) a monomer composition that includes at least a crosslinking monomer having two or more ethylenically unsaturated groups. The polymeric materials in the crosslinkable compositions undergo chain extension and crosslinking reactions when exposed to actinic radiation in the ultraviolet region of the electromagnetic spectrum. Additionally, crosslinked compositions, articles that contain the crosslinkable compositions or the crosslinked compositions, and methods of making the articles are provided.
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公开(公告)号:US10035328B2
公开(公告)日:2018-07-31
申请号:US15034293
申请日:2014-11-13
IPC分类号: B32B7/12 , C09J4/06 , C09J133/06 , G02F1/1335 , B32B23/04 , B32B23/08 , B32B27/08 , B32B27/30 , B32B27/36 , C08K3/22
CPC分类号: B32B7/12 , B32B23/04 , B32B23/08 , B32B27/08 , B32B27/308 , B32B27/36 , B32B27/365 , B32B2255/26 , B32B2307/412 , B32B2307/416 , B32B2307/42 , B32B2307/732 , B32B2419/00 , B32B2457/20 , B32B2551/00 , C08F8/30 , C08F220/18 , C08K3/22 , C08K2201/011 , C08L33/08 , C09J4/00 , C09J4/06 , C09J133/066 , C09J133/08 , G02F1/133528 , G02F2202/28 , C08F2220/1891 , C08F220/20 , C08F2220/1875 , C08F222/20 , C08F265/06
摘要: The disclosure describes a curable composition comprising a) a solute (meth) acryloyl oligomer having a plurality of pendent, ethylenically unsaturated, free-radically polymerizable functional groups and nucleophilic, hydrophilic groups, a Mw of 5 k to 30 k. a Tg
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公开(公告)号:US20170291360A1
公开(公告)日:2017-10-12
申请号:US15635237
申请日:2017-06-28
发明人: Carsten Franke , Joseph C. Dingeldein , Jay A. Esch , Robert L.W. Smithson , Jayshree Seth , Olester Benson, JR. , Karen J. Calverley , Alexander J. Huffman , Serkan Yurt , Setareh Niknezhad , Michael A. Kropp , John P. Baetzold
IPC分类号: B29C67/00 , C09J9/00 , B33Y70/00 , B29C35/08 , B33Y80/00 , B33Y30/00 , B33Y50/02 , C09J5/00 , C09J4/00 , B33Y10/00
CPC分类号: C09J7/385 , B05D3/06 , B05D5/10 , B29C35/0805 , B29C64/112 , B29C2035/0827 , B29K2033/04 , B29K2105/0097 , B33Y10/00 , B33Y30/00 , B33Y50/02 , B33Y70/00 , B33Y80/00 , C08F2220/1875 , C09J4/00 , C09J5/00 , C09J7/20 , C09J9/00 , C09J11/04 , C09J133/00 , C09J2201/606 , C09J2205/31 , C09J2433/00 , C09J2467/005 , C08F220/18 , C08F2220/1858
摘要: A method of making an adhesive is provided, including obtaining an actinic radiation-polymerizable adhesive precursor composition disposed against a surface of an actinic radiation-transparent substrate and irradiating a first portion of the actinic radiation-polymerizable adhesive precursor composition through the actinic radiation-transparent substrate for a first irradiation dosage. The method further includes irradiating a second portion of the actinic radiation-polymerizable adhesive precursor composition through the actinic radiation-transparent substrate for a second irradiation dosage. The first portion and the second portion are adjacent to or overlapping with each other and the first irradiation dosage and the second irradiation dosage are not the same. The method forms an integral adhesive having a variable thickness in an axis normal to the surface of the actinic radiation-transparent substrate. Also, an adhesive article is provided, including a substrate having a major surface and an integral adhesive disposed on the major surface of the substrate. Further, methods are provided, including receiving, by a manufacturing device having one or more processors, a digital object comprising data specifying an article; and generating, with the manufacturing device by an additive manufacturing process, the article based on the digital object. A system is provided, including a display that displays a 3D model of an article; and one or more processors that, in response to the 3D model selected by a user, cause a 3D printer to create a physical object of an article.
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公开(公告)号:US20160289515A1
公开(公告)日:2016-10-06
申请号:US15034293
申请日:2014-11-13
IPC分类号: C09J133/08 , B32B7/12 , G02F1/1335
CPC分类号: B32B7/12 , B32B23/04 , B32B23/08 , B32B27/08 , B32B27/308 , B32B27/36 , B32B27/365 , B32B2255/26 , B32B2307/412 , B32B2307/416 , B32B2307/42 , B32B2307/732 , B32B2419/00 , B32B2457/20 , B32B2551/00 , C08F8/30 , C08F220/18 , C08K3/22 , C08K2201/011 , C08L33/08 , C09J4/00 , C09J4/06 , C09J133/066 , C09J133/08 , G02F1/133528 , G02F2202/28 , C08F2220/1891 , C08F220/20 , C08F2220/1875 , C08F222/20 , C08F265/06
摘要: The disclosure describes a curable composition comprising a) a solute (meth) acryloyl oligomer having a plurality of pendent, ethylenically unsaturated, free-radically polymerizable functional groups and nucleophilic, hydrophilic groups, a Mw of 5 k to 30 k. a Tg
摘要翻译: 本公开内容描述了一种可固化组合物,其包含a)具有多个侧链的,烯属不饱和的,可自由基聚合的官能团和亲核亲水基团的溶质(甲基)丙烯酰基低聚物,Mw为5k至30k。 Tg <20℃。 b)溶剂单体组分; 和非反应性低聚物和光引发剂。 可固化组合物可用作光学应用中的粘合剂。
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公开(公告)号:US09414996B2
公开(公告)日:2016-08-16
申请号:US14437200
申请日:2013-10-31
发明人: Guy D. Joly , Ahmed S. Abuelyaman , Ann R. Fornof , Bradley D. Craig , Larry R. Krepski , William H. Moser , Serkan Yurt , Joel D. Oxman , Afshin Falsafi
IPC分类号: A61K6/083 , A61K6/00 , C09J133/14
CPC分类号: A61K6/083 , A61K6/0023 , A61K6/0088 , A61K6/0835 , C09J133/14 , C08L33/10
摘要: A curable dental composition comprising an addition-fragmentation agent and a curable dental resin is disclosed.
摘要翻译: 公开了一种包含加成碎裂剂和可固化牙科用树脂的可固化牙科用组合物。
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公开(公告)号:US09403966B2
公开(公告)日:2016-08-02
申请号:US14674666
申请日:2015-03-31
发明人: Guy D. Joly , Larry R. Krepski , Ann R. Fornof , Serkan Yurt , Babu N. Gaddam , Ahmed S. Abuelyaman
IPC分类号: C07C67/00 , C08K5/205 , C07C69/593 , C07C271/16 , C07C67/14 , C07C67/26 , A61K6/083 , C08K3/22 , C08K3/36 , C08K5/11 , C08K5/12 , C09D133/08
CPC分类号: C08K5/205 , A61K6/083 , C07C67/14 , C07C67/26 , C07C69/593 , C07C271/16 , C08K3/22 , C08K3/36 , C08K5/11 , C08K5/12 , C09D133/08 , C08L33/10 , C08L33/08
摘要: Addition-fragmentation agents of the formula are disclosed: wherein R1, R2 and R3 are each independently Z-Q-, a (hetero)alkyl group or a (hetero)aryl group with the proviso that at least one of R1, R2 and R3 is Zm-Q-, Q is a linking group have a valence of m+1; Z is an ethylenically unsaturated polymerizable group, m is 1 to 6; each X1 is independently —O— or —NR4—, where R4 is H or C1-C4 alkyl, and n is 0 or 1.
摘要翻译: 公开了下式的加成碎裂剂:其中R1,R2和R3各自独立地为ZQ-,(杂)烷基或(杂)芳基,条件是R1,R2和R3中的至少一个为Zm -Q-,Q为连接基团,其价数为m + 1; Z为烯键式不饱和可聚合基团,m为1至6; 每个X1独立地是-O-或-NR4-,其中R4是H或C1-C4烷基,n是0或1。
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公开(公告)号:US11279853B2
公开(公告)日:2022-03-22
申请号:US15635237
申请日:2017-06-28
发明人: Carsten Franke , Joseph C. Dingeldein , Jay A. Esch , Robert L. W. Smithson , Jayshree Seth , Olester Benson, Jr. , Karen J. Calverley , Alexander J. Huffman , Serkan Yurt , Setareh Niknezhad , Michael A. Kropp , John P. Baetzold
IPC分类号: B33Y10/00 , B33Y30/00 , B33Y50/02 , B33Y70/00 , B29C35/08 , C09J5/00 , C09J9/00 , B05D3/06 , B05D5/10 , B29K105/00 , C09J4/00 , C09J133/00 , C09J7/20 , B29C64/112 , B33Y80/00 , C09J7/38 , C09J11/04 , C08F220/18 , B29K33/04
摘要: A method of making an adhesive is provided, including obtaining an actinic radiation-polymerizable adhesive precursor composition disposed against a surface of an actinic radiation-transparent substrate and irradiating a first portion of the actinic radiation-polymerizable adhesive precursor composition through the actinic radiation-transparent substrate for a first irradiation dosage. The method further includes irradiating a second portion of the actinic radiation-polymerizable adhesive precursor composition through the actinic radiation-transparent substrate for a second irradiation dosage. The first portion and the second portion are adjacent to or overlapping with each other and the first irradiation dosage and the second irradiation dosage are not the same. The method forms an integral adhesive having a variable thickness in an axis normal to the surface of the actinic radiation-transparent substrate. Also, an adhesive article is provided, including a substrate having a major surface and an integral adhesive disposed on the major surface of the substrate. Further, methods are provided, including receiving, by a manufacturing device having one or more processors, a digital object comprising data specifying an article; and generating, with the manufacturing device by an additive manufacturing process, the article based on the digital object. A system is provided, including a display that displays a 3D model of an article; and one or more processors that, in response to the 3D model selected by a user, cause a 3D printer to create a physical object of an article.
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公开(公告)号:US20200308321A1
公开(公告)日:2020-10-01
申请号:US15733259
申请日:2018-12-14
发明人: Serkan Yurt , Stephen B. Roscoe , George W. Griesgraber , Babu N. Gaddam , Kevin M. Lewandowski , Bryan T. Whiting , Haeen Sykora , Aaron T. Hedegaard , Jayshree Seth , Janet A. Venne
IPC分类号: C08F20/38 , C08F2/50 , C08K3/36 , C08K5/3492 , C08K5/5419 , C08F293/00 , C09J7/38
摘要: Crosslinkable polymeric materials, crosslinked polymeric materials, articles containing the crosslinkable polymeric materials or crosslinked polymeric materials, and methods of making the articles and various compositions are provided. More particularly, the crosslinkable composition contains a) a first polymeric material, which has terminal dithiocarbamate or dithiocarbonate groups, b) a crosslinking composition containing a chlorinated triazine crosslinking agent and/or a crosslinking monomer having two or more ethylenically unsaturated groups, and c) a thixotropic agent containing metal oxide particles. The crosslinkable composition may be printable or dispensed. In some embodiments, the crosslinked composition is a pressure-sensitive adhesive.
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公开(公告)号:US20180355221A1
公开(公告)日:2018-12-13
申请号:US16066360
申请日:2016-12-13
发明人: Carsten Franke , Kenneth L. Smith , Jesse R. Behnke , Robert L.W. Smithson , Lucas D. Crestik , Olester Benson, Jr. , Alexander J. Huffman , Michael A. Kropp , John P. Baetzold , Serkan Yurt
IPC分类号: C09J7/38 , C09J7/20 , B05D3/06 , B05D5/10 , B29C64/129 , B29C64/245 , B23K26/082
CPC分类号: C09J7/385 , B05D1/286 , B05D3/067 , B05D5/10 , B05D2252/02 , B23K26/082 , B29C64/129 , B29C64/245 , B33Y10/00 , B33Y30/00 , B33Y70/00 , B33Y80/00 , C09J7/20 , C09J2201/40 , C09J2205/31 , C09J2433/00 , C09J2463/00 , C09J2475/00
摘要: A continuous method of manufacturing adhesives is provided. The method includes obtaining an actinic radiation-polymerizable adhesive precursor composition disposed on a major surface of an actinic radiation-transparent substrate and irradiating a first portion of the actinic radiation-polymerizable adhesive precursor composition through the actinic radiation-transparent substrate for a first irradiation dosage. The method further includes moving the actinic radiation-transparent substrate and irradiating a second portion of the actinic radiation-polymerizable adhesive precursor composition through the actinic radiation-transparent substrate for a second irradiation dosage. Optionally, the method also includes irradiating a third portion of the actinic radiation-polymerizable adhesive precursor composition through the actinic radiation-transparent substrate prior to moving the substrate. The first irradiation dosage and the third irradiation dosage are often not the same, thereby forming an integral adhesive having a variable thickness in an axis normal to the actinic radiation-transparent substrate.
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