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公开(公告)号:US20200369820A1
公开(公告)日:2020-11-26
申请号:US15733412
申请日:2019-02-13
发明人: Kevin M. Lewandowski , Stephen B. Roscoe , Babu N. Gaddam , Bryan T. Whiting , John L. Battiste , George W. Griesgraber
IPC分类号: C08F293/00 , C08F265/06 , C09J4/06 , C09J153/00 , C09J133/08 , C07C329/16 , C07C333/20
摘要: Controlled radical initiators that are ketone-containing dithiocarbamate or ketone-containing dithiocarbonate compounds are used to form polymeric materials that have a single polymeric block or multiple polymeric blocks. Reaction mixtures containing controlled radical initiators and various ethylenically unsaturated monomers, polymeric materials formed from the reaction mixtures, crosslinkable compositions containing the polymeric materials, crosslinked compositions formed from the crosslinkable compositions, and articles containing the polymeric materials, the crosslinkable compositions, or the crosslinked compositions are provided.
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公开(公告)号:US20200017727A1
公开(公告)日:2020-01-16
申请号:US16495586
申请日:2018-03-23
IPC分类号: C09J7/38 , C08F293/00 , C09J4/06 , C09J11/08
摘要: Controlled radical initiators, reaction mixtures containing the controlled radical initiators and various ethylenically unsaturated monomers, polymeric materials formed from the reaction mixtures, crosslinkable compositions containing the polymeric materials, and crosslinked compositions formed from the crosslinkable compositions are provided. The controlled radical initiators are bis-dithiocarbamate or bis-dithiocarbonate compounds having a single carbon between the two dithiocarbamate or dithiocarbonate groups.
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公开(公告)号:US10400055B2
公开(公告)日:2019-09-03
申请号:US16314760
申请日:2017-06-27
发明人: George W. Griesgraber , Stephen B. Roscoe , Hae-Seung Harry Lee , Serkan Yurt , Joon Chatterjee , Duane D. Fansler , Stefan H. Gryska , Babu N. Gaddam , Kevin M. Lewandowski , John L. Battiste
IPC分类号: C08F2/50 , C08F2/48 , C08G61/04 , C08F297/02 , C08F220/10 , C08F293/00 , C08F220/14 , C08F220/18 , C08F220/28
摘要: Controlled radical initiators, reaction mixtures containing the controlled radical initiators and various ethylenically unsaturated monomers, and polymeric materials formed from the reaction mixtures are provided. The controlled radical initiators are bis-dithiocarbamate or bis-dithiocarbonate compounds with a single carbon atom between the two dithiocarbamate or dithiocarbonate groups. Polymeric materials such as homopolymers, random copolymers, and block copolymers can be prepared using the controlled radical initiators.
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公开(公告)号:US09006357B2
公开(公告)日:2015-04-14
申请号:US14368332
申请日:2012-12-21
发明人: Yu Yang , George G. I. Moore , James T. Wolter , Kanta Kumar , Michael A. Semonick , John L. Battiste
IPC分类号: C09D183/04 , B05D3/00 , C07F9/06 , C07C279/00 , C07C279/04 , C09J7/02 , C08L83/04 , C08L83/14 , C08K5/00 , C08K5/55
CPC分类号: C09D183/04 , B05D3/007 , C07C279/00 , C07C279/04 , C07F9/062 , C07F9/065 , C08K5/0091 , C08K5/55 , C08L83/04 , C08L83/14 , C09J7/201 , C09J7/22 , C09J2201/606 , C09J2483/005 , Y10T428/31663
摘要: A curable composition comprises (a) at least one polyorganosiloxane, fluorinated polyorganosiloxane, or combination thereof comprising reactive silane functionality comprising at least two hydroxysilyl moieties; (b) at least one polyorganosiloxane, fluorinated polyorganosiloxane, or combination thereof comprising reactive silane functionality comprising at least two hydrosilyl moieties; and (c) a catalyst composition comprising (1) at least one base selected from amidines, guanidines, phosphazenes, proazaphosphatranes, and combinations thereof, and (2) at least one Lewis acid; wherein at least one of the components (a) and (b) has an average reactive silane functionality of at least three.
摘要翻译: 可固化组合物包含(a)至少一种聚有机硅氧烷,氟化聚有机硅氧烷或其组合,其包含至少两个羟基甲硅烷基部分的反应性硅烷官能团; (b)至少一种聚有机硅氧烷,氟化聚有机硅氧烷或其组合,其包含至少两个氢化甲硅烷基部分的反应性硅烷官能团; 和(c)催化剂组合物,其包含(1)至少一种选自脒,胍,磷腈,前氮磷酸盐及其组合的碱,和(2)至少一种路易斯酸; 其中组分(a)和(b)中的至少一种具有至少三个的平均反应性硅烷官能度。
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公开(公告)号:US11319461B2
公开(公告)日:2022-05-03
申请号:US15733503
申请日:2019-02-13
发明人: Kevin M. Lewandowski , Stephen B. Roscoe , Babu N. Gaddam , Bryan T. Whiting , John L. Battiste
IPC分类号: C08F2/48 , C08F2/50 , C08G61/04 , C09J4/06 , C09J7/38 , C07C329/16 , C08F265/06 , C08F293/00 , C09J133/08 , C08F220/18
摘要: Controlled radical initiators, reaction mixtures containing the controlled radical initiators and various ethylenically unsaturated monomers, polymeric materials formed from the reaction mixtures, crosslinkable compositions containing the polymeric materials, crosslinked compositions formed from the crosslinkable compositions, and various articles are provided. The controlled radical initiators are bis-dithiocarbamate or bis-dithiocarbonate compounds having a carbonyl group between the two dithiocarbamate or dithiocarbonate groups.
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公开(公告)号:US10941234B2
公开(公告)日:2021-03-09
申请号:US15733412
申请日:2019-02-13
发明人: Kevin M. Lewandowski , Stephen B. Roscoe , Babu N. Gaddam , Bryan T. Whiting , John L. Battiste , George W. Griesgraber
IPC分类号: C08F293/00 , C08F265/06 , C07C329/16 , C07C333/20 , C09J4/06 , C09J153/00 , C09J133/08
摘要: Controlled radical initiators that are ketone-containing dithiocarbamate or ketone-containing dithiocarbonate compounds are used to form polymeric materials that have a single polymeric block or multiple polymeric blocks. Reaction mixtures containing controlled radical initiators and various ethylenically unsaturated monomers, polymeric materials formed from the reaction mixtures, crosslinkable compositions containing the polymeric materials, crosslinked compositions formed from the crosslinkable compositions, and articles containing the polymeric materials, the crosslinkable compositions, or the crosslinked compositions are provided.
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公开(公告)号:US20210101867A1
公开(公告)日:2021-04-08
申请号:US15733503
申请日:2019-02-13
发明人: Kevin M. Lewandowski , Stephen B. Roscoe , Babu N. Gaddam , Bryan T. Whiting , John L. Battiste
IPC分类号: C07C329/16 , C08F265/06 , C09J133/08 , C09J7/38 , C09J4/06 , C08F293/00
摘要: Controlled radical initiators, reaction mixtures containing the controlled radical initiators and various ethylenically unsaturated monomers, polymeric materials formed from the reaction mixtures, crosslinkable compositions containing the polymeric materials, crosslinked compositions formed from the crosslinkable compositions, and various articles are provided. The controlled radical initiators are bis-dithiocarbamate or bis-dithiocarbonate compounds having a carbonyl group between the two dithiocarbamate or dithiocarbonate groups.
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公开(公告)号:US20210095097A1
公开(公告)日:2021-04-01
申请号:US15733169
申请日:2018-12-12
发明人: Kevin M. Lewandowski , Stephen B. Roscoe , Babu N. Gaddam , Bryan T. Whiting , John L. Battiste , George W. Griesgraber
IPC分类号: C08K5/39 , C08F2/38 , C08F2/50 , C08F220/18 , C08F236/20
摘要: Controlled radical initiators, reaction mixtures containing the controlled radical initiators and various ethylenically unsaturated monomers, polymeric materials formed from the reaction mixtures, crosslinkable compositions containing the polymeric materials, crosslinked compositions formed from the crosslinkable compositions, and articles containing the polymeric materials, the crosslinkable compositions, or the crosslinked compositions are provided. The controlled radical initiators are bis-dithiocarbamate or bis-dithiocarbonate compounds having a single carbon between the two dithiocarbamate or dithiocarbonate groups. Also attached to that single carbon is a ketone group.
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公开(公告)号:US20190153142A1
公开(公告)日:2019-05-23
申请号:US16314760
申请日:2017-06-27
发明人: George W. Griesgraber , Stephen B. Roscoe , Hae-Seung Harry Lee , Serkan Yurt , Joon Chatterjee , Duane D. Fansler , Stefan H. Gryska , Babu N. Gaddam , Kevin M. Lewandowski , John L. Battiste
IPC分类号: C08F297/02
CPC分类号: C08F297/026 , C08F2/48 , C08F2/50 , C08F220/10 , C08F220/14 , C08F293/005 , C08F297/023 , C08F2220/1825 , C08F2220/1858 , C08F2220/281 , C08F2438/03 , C08F2/38
摘要: Controlled radical initiators, reaction mixtures containing the controlled radical initiators and various ethylenically unsaturated monomers, and polymeric materials formed from the reaction mixtures are provided. The controlled radical initiators are bis-dithiocarbamate or bis-dithiocarbonate compounds with a single carbon atom between the two dithiocarbamate or dithiocarbonate groups. Polymeric materials such as homopolymers, random copolymers, and block copolymers can be prepared using the controlled radical initiators.
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公开(公告)号:US10241237B2
公开(公告)日:2019-03-26
申请号:US14361107
申请日:2012-11-01
发明人: Naiyong Jing , Yongshang Lu , Dang Xie , Zhigang Yu , John L. Battiste , Alan L. Levin , Caroline M. Ylitalo , Mahfuza B. Ali
摘要: An anti-fog coating composition is described comprising an aqueous polymeric dispersion; a crosslinker, and a surfactant. The dried and cured coating composition does not exhibit fogging within 8 seconds after being soaked in 25° C. water for 1 hour. In favored embodiments, the dried and cured coating composition does not exhibit fogging within 60 seconds after being soaked in 50° C. water for 24 hours. Also described are articles comprising the dried and cured coating composition disposed on a substrate as well as a method a providing an anti-fog coating on a substrate.
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