公开(公告)号：US20080019898A1

公开(公告)日：2008-01-24

申请号：US10583417

申请日：2004-12-20

申请人： Adrien Dromard ,  Yvonick Chevallier ,  Remi Valero ,  Dominique Petit

发明人： Adrien Dromard ,  Yvonick Chevallier ,  Remi Valero ,  Dominique Petit

IPC分类号： C01B33/113 ,  C01B33/143

CPC分类号： C01B33/193 ,  A61K8/25 ,  A61Q11/00 ,  C08K3/36 ,  C08L83/04 ,  H01M2/16 ,  C08L21/00

摘要： The invention relates to a highly-structured precipitated silica having a low water uptake and high dispersibility in different pasty or solid matrices or media, elastomers or silicon, and to the preparation method thereof. The invention also relates to the use of said silica, for example, as a reinforcing filler in matrices based on elastomers (clear or semi-clear for shoe soles), in silicon matrices (in particular, for the coating of electric cables), as a filler and/or support and/or vehicle in different compositions (food compositions, cosmetic compositions, pharmaceutical compositions, compositions for the production of paints or paper, compositions for the production of porous membrane separators for batteries) or as a thickening agent in toothpastes.

摘要翻译： 本发明涉及在不同的糊状或固体基质或介质，弹性体或硅中具有低吸水率和高分散性的高度结构的沉淀二氧化硅及其制备方法。 本发明还涉及所述二氧化硅在硅基质（特别是用于电缆涂层）中基于弹性体（鞋底的透明或半透明）的基质中作为增强填料的用途，如 不同组成的填充剂和/或载体和/或载体（食品组合物，化妆品组合物，药物组合物，用于生产油漆或纸的组合物，用于生产电池的多孔隔膜的组合物）或牙膏中的增稠剂 。

公开(公告)号：US20050074386A1

公开(公告)日：2005-04-07

申请号：US10500107

申请日：2002-12-24

申请人： Remi Valero ,  Yvonick Chevallier

发明人： Remi Valero ,  Yvonick Chevallier

IPC分类号： A61K47/04 ,  A23L29/294 ,  C01B33/193 ,  C08K3/36 ,  C01B33/12

CPC分类号： C01B33/193 ,  C01P2006/12 ,  C01P2006/80 ,  C01P2006/82 ,  C08K3/36 ,  C08L83/04

摘要： The invention concerns a method for preparing low water uptake precipitated silicas, comprising successive steps which consist in: (a) producing an initial starter including a silicate, the silicate concentration in said starter, expressed in SiO2 equivalent, being less than 15 g/L; (b) bringing the medium pH to a value ranging between 7 and 8 by adding an acidifying agent, (c) in the resulting medium, simultaneously adding a silicate and an acidifying agent the respective amounts of silicate and acidifying agent added in time being specifically such that, during the entire addition (1) the reaction medium pH stays between 7 and 8, and (ii) the silicon concentration in the medium, expressed in SiO2 equivalent, stays below 35 g/L; (d) adding an acidifying agent in the medium resulting from step (c), so as to bring the medium to a pH ranging between 3 and 6.5; and (e) filtering the resulting aqueous silica dispersion, then drying the filter cake obtained at the end of the filtering step. The invention also concerns low water uptake silicas obtained by said method and their use, in particular for reinforcing silicones or polymer or elastomer matrices.

摘要翻译： 本发明涉及一种制备低吸水沉淀二氧化硅的方法，包括连续步骤，其包括：（a）产生包含硅酸盐的初始起始物，所述起始物中的硅酸盐浓度以SiO 2当量表示，小于15g / L ; （b）通过添加酸化剂使介质pH值达到7〜8，（c）在得到的培养基中，同时加入硅酸盐和酸化剂，分别加入相应量的硅酸盐和酸化剂 使得在整个添加（1）期间，反应介质pH保持在7和8之间，和（ii）以SiO 2当量表示的介质中的硅浓度保持在35g / L以下; （d）在由步骤（c）得到的培养基中加入酸化剂，以使培养基达到3至6.5的pH; 和（e）过滤所得的二氧化硅水溶液，然后干燥在过滤步骤结束时获得的滤饼。 本发明还涉及通过所述方法获得的低吸水二氧化硅及其用途，特别是用于增强硅氧烷或聚合物或弹性体基质。

公开(公告)号：US07524478B2

公开(公告)日：2009-04-28

申请号：US10500107

申请日：2002-12-24

申请人： Remi Valero ,  Yvonick Chevallier

发明人： Remi Valero ,  Yvonick Chevallier

IPC分类号： C01B33/12 ,  C01B33/18 ,  C01B33/187 ,  C01B33/193

CPC分类号： C01B33/193 ,  C01P2006/12 ,  C01P2006/80 ,  C01P2006/82 ,  C08K3/36 ,  C08L83/04

摘要： The invention concerns a method for preparing low water uptake precipitated silicas, comprising successive steps which consist in: (a) producing an initial starter including a silicate, the silicate concentration in said starter, expressed in SiO2 equivalent, being less than 15 g/L; (b) bringing the medium pH to a value ranging between 7 and 8 by adding an acidifying agent, (c) in the resulting medium, simultaneously adding a silicate and an acidifying agent the respective amounts of silicate and acidifying agent added in time being specifically such that, during the entire addition (1) the reaction medium pH stays between 7 and 8, and (ii) the silicon concentration in the medium, expressed in SiO2 equivalent, stays below 35 g/L; (d) adding an acidifying agent in the medium resulting from step (c), so as to bring the medium to a pH ranging between 3 and 6.5; and (e) filtering the resulting aqueous silica dispersion, then drying the filter cake obtained at the end of the filtering step. The invention also concerns low water uptake silicas obtained by said method and their use, in particular for reinforcing silicones or polymer or elastomer matrices.

摘要翻译： 本发明涉及一种制备低吸水沉淀二氧化硅的方法，包括连续步骤，其包括：（a）产生包含硅酸盐的初始起始物，所述起始物中的硅酸盐浓度以SiO 2当量表示，小于15g / L ; （b）通过添加酸化剂使介质pH值达到7〜8，（c）在得到的培养基中，同时加入硅酸盐和酸化剂，分别加入相应量的硅酸盐和酸化剂 使得在整个添加（1）期间，反应介质pH保持在7和8之间，和（ii）以SiO 2当量表示的介质中的硅浓度保持在35g / L以下; （d）在由步骤（c）得到的培养基中加入酸化剂，以使培养基达到3至6.5的pH; 和（e）过滤所得的二氧化硅水溶液，然后干燥在过滤步骤结束时获得的滤饼。 本发明还涉及通过所述方法获得的低吸水二氧化硅及其用途，特别是用于增强硅氧烷或聚合物或弹性体基质。

公开(公告)号：US20100221541A1

公开(公告)日：2010-09-02

申请号：US12461689

申请日：2009-08-20

申请人： Remi Valero ,  Julien Hernandez

发明人： Remi Valero ,  Julien Hernandez

IPC分类号： C01B33/12 ,  C01B33/193

CPC分类号： A61K8/25 ,  A61K2800/412 ,  A61Q11/00 ,  C01B33/193 ,  C01P2004/32 ,  C01P2004/51 ,  C01P2004/61 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C01P2006/17 ,  C01P2006/80 ,  C01P2006/90 ,  C08K3/36 ,  H01M2/1646 ,  Y10T428/2982 ,  C08L21/00

摘要： The invention relates to a novel method of preparing silicas and to highly-structured silicas having the following characteristics: a specific surface area CTAB (SCTAB) of between 40 and 525 m2/g; a specific surface area BET (SBET) of between 45 and 550 m2/g; an object size distribution width Ld ((d84−d16)/d50), which is measured by XDC particle size analysis after deagglomeration with ultrasound, of at least 0.91; and a pore-size distribution such that ratio V(d5−d50)/V(d5−d100) is at least 0.66. The invention also relates to the use of said silicas as polymer reinforcing fillers.

摘要翻译： 本发明涉及一种制备二氧化硅的新方法和具有以下特征的高度结构的二氧化硅：比表面积CTAB（SCTAB）为40-525m2 / g; 比表面积BET（SBET）在45和550m 2 / g之间; 通过用超声波解聚缩后的XDC粒度分析测量的物体尺寸分布宽度Ld（（d84-d16）/ d50）至少为0.91; 和比率V（d5-d50）/ V（d5-d100））至少为0.66的孔径分布。 本发明还涉及所述二氧化硅作为聚合物增强填料的用途。

公开(公告)号：US20100192636A1

公开(公告)日：2010-08-05

申请号：US12667458

申请日：2008-07-02

申请人： Remi Valero ,  Bernard Lericque ,  Alexis Ponnouradjou

发明人： Remi Valero ,  Bernard Lericque ,  Alexis Ponnouradjou

IPC分类号： C02F1/66 ,  C03B37/00 ,  C03B37/07

CPC分类号： D04H3/004 ,  C02F1/66 ,  C02F2103/12 ,  C02F2303/08 ,  C03C25/146 ,  C03C25/285 ,  D04H1/4218 ,  D04H1/587 ,  D04H1/645 ,  D04H1/655

摘要： The invention relates to a method of controlling the level of corrosivity of an aqueous solution recovered during a process for producing a blanket of mineral fibers, comprising in particular the fiberizing and the coating of said fibers with a binder comprising a polyacid typically of the acrylic type, said aqueous solution being at least partly recycled into a zone in which said resin is prepared and/or a scrubbing zone of the production plant, said method being characterized in that the pH of the solution in the recycling circuit is maintained between minimum and maximum values by injecting into said circuit an agent for modifying said pH, such as a base, the quantity injected or the flow rate of the pH-modifying agent being adjusted directly according to the quantity or the flow rate of acid binder injected during the fiberizing process.The invention also relates to the device for implementing the method.

摘要翻译： 本发明涉及一种控制在用于生产无机纤维毯的方法中回收的水溶液的腐蚀性水平的方法，特别地包括所述纤维的纤维化和涂层，所述粘合剂包含通常为丙烯酸类型的多元酸 所述水溶液至少部分地再循环到制备所述树脂的区域和/或所述生产设备的洗涤区域中，所述方法的特征在于，回收回路中的溶液的pH保持在最小和最大值之间 通过在所述回路中注入用于改变所述pH（例如碱）的试剂，注入的量或pH调节剂的流速根据在成纤过程中注入的酸粘合剂的量或流速直接调节 。 本发明还涉及实现该方法的装置。

公开(公告)号：US20060147546A1

公开(公告)日：2006-07-06

申请号：US10525107

申请日：2003-08-21

申请人： Patrick Ferlin ,  Lorraine Leite ,  Pierre-Yves Lahary ,  Remi Valero

发明人： Patrick Ferlin ,  Lorraine Leite ,  Pierre-Yves Lahary ,  Remi Valero

IPC分类号： A61K33/42

CPC分类号： B01J20/048 ,  B01J2/04 ,  B01J20/103 ,  B01J20/28004 ,  B01J20/28011 ,  B01J20/28019 ,  B01J20/28057 ,  B01J20/28076 ,  B01J20/3085 ,  B01J2220/42 ,  Y10T428/2996

摘要： The invention concerns compounds, for use as liquid support and as anticaking agent, and, simultaneously, as nutrient additive in particular for animals, consisting of precipitated silica and phosphate selected among phosphates of elements of groups Ia or IIa of the periodic table of the elements and rare-earth phosphates, said compounds being in the form of substantially spherical pellets.

摘要翻译： 本发明涉及用作液体支持物和抗起泡剂的化合物，并且同时作为特别用于动物的营养添加剂，由沉淀二氧化硅和磷酸盐组成，所述沉淀二氧化硅和磷酸盐选自元素周期表的Ia或IIa族元素的磷酸盐 和稀土磷酸盐，所述化合物为基本上球形的颗粒形式。

公开(公告)号：US20050032965A1

公开(公告)日：2005-02-10

申请号：US10486573

申请日：2002-08-13

申请人： Remi Valero

发明人： Remi Valero

IPC分类号： A43B13/04 ,  A61K8/25 ,  A61K8/29 ,  A61Q11/00 ,  B01J32/00 ,  C01B33/193 ,  C08K3/36 ,  C08L21/00 ,  H01M2/16 ,  C08K3/34 ,  C01B33/12

CPC分类号： A61K8/25 ,  A61K2800/412 ,  A61Q11/00 ,  C01B33/193 ,  C01P2004/32 ,  C01P2004/51 ,  C01P2004/61 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C01P2006/17 ,  C01P2006/80 ,  C01P2006/90 ,  C08K3/36 ,  H01M2/1646 ,  Y10T428/2982 ,  C08L21/00

摘要： The invention relates to a novel method of preparing silicas and to highly-structured silicas having the following characteristics: a specific surface area CTAB (SCTAB) of between 40 and 525 m2/g; a specific surface area BET (SBET) of between 45 and 550 m2/g; an object size distribution width Ld ((d84−d16)/d50), which is measured by XDC particle size analysis after deagglomeration with ultrasound, of at least 0.91; and a pore-size distribution such that ratio V(d5−d50)/V(d5−d100) is at least 0.66. The invention also relates to the use of said silicas as polymer reinforcing fillers.

摘要翻译： 本发明涉及一种制备二氧化硅的新方法和具有以下特征的高度结构的二氧化硅：比表面积CTAB（SCTAB）为40-525m2 / g; 比表面积BET（SBET）在45和550m 2 / g之间; 通过用超声波解聚缩后的XDC粒度分析测量的物体尺寸分布宽度Ld（（d84-d16）/ d50）至少为0.91; 和比率V（d5-d50）/ V（d5-d100））至少为0.66的孔径分布。 本发明还涉及所述二氧化硅作为聚合物增强填料的用途。

公开(公告)号：US20090214449A1

公开(公告)日：2009-08-27

申请号：US11921073

申请日：2006-05-29

申请人： Remi Valero ,  Jean-Noel Jas ,  Joel Racinoux ,  Kyu-Min Hwang ,  Youn-Kwon Yoo ,  Soline Daudey

发明人： Remi Valero ,  Jean-Noel Jas ,  Joel Racinoux ,  Kyu-Min Hwang ,  Youn-Kwon Yoo ,  Soline Daudey

IPC分类号： C04B14/04 ,  C08J5/14 ,  C08K5/09 ,  A61K8/365 ,  A61Q11/00

CPC分类号： C01B33/193

摘要： Carboxylic acids are employed during the preparation of precipitated silica or a suspension of precipitated silica to provide precipitated silicas with low water uptake, which are useful, for example, as reinforcing fillers for silicon matrices.

摘要翻译： 在制备沉淀二氧化硅或沉淀二氧化硅的悬浮液中使用羧酸以提供具有低吸水率的沉淀二氧化硅，其可用作例如硅基质的增强填料。

公开(公告)号：US20050004297A1

公开(公告)日：2005-01-06

申请号：US10777075

申请日：2004-02-13

申请人： Olivier Durel ,  Arnaud Lapra ,  Julien Hernandez ,  Remi Valero

发明人： Olivier Durel ,  Arnaud Lapra ,  Julien Hernandez ,  Remi Valero

IPC分类号： B60C1/00 ,  C01B33/143 ,  C01B33/193 ,  C08K3/36 ,  C08K5/548 ,  C08L9/00 ,  C08K3/34

CPC分类号： B82Y30/00 ,  B60C1/0016 ,  C01B33/193 ,  C01P2004/50 ,  C01P2004/51 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C01P2006/17 ,  C08K3/36 ,  C08K5/548 ,  Y10T152/10495 ,  C08L21/00

摘要： Diene rubber compositions are described containing a diene elastomer, a reinforcing inorganic filler, and a coupling agent wherein the inorganic filler includes a silica having the following characteristics: (a) a BET specific surface area between 45 and 400 m2/g; (b) a CTAB specific surface area between 40 and 380 m2/g; (c) an average particle size (by mass), dw, of 20 to 300 nm; and at least one of the following characteristics, preferably two and more preferably all three: (d) a particle size distribution such that dw≧/CTAB)−30; (e) a porosity which meets the criterion L/FI≧−0.0025 CTAB+0.85; (f) an amount of silanols per unit of surface area, NSiOH/nm2; NSiOH/nm2≦−0.027 CTAB+10.5. These diene rubber compositions can be used for the manufacture of tires or of semi-finished products intended for tires.

摘要翻译： 描述了含有二烯弹性体，增强无机填料和偶联剂的二烯橡胶组合物，其中无机填料包括具有以下特性的二氧化硅：（a）BET比表面积为45-400m 2 / g; （b）CTAB比表面积在40和380m 2 / g之间; （c）平均粒径（质量百分比）dw为20〜300nm; 和以下特征中的至少一个，优选两个，更优选全部三个：（d）使得dw> = / CTAB）-30的粒度分布; （e）满足标准L / FI> = - 0.0025 CTAB + 0.85的孔隙率; （f）每单位表面积的硅烷醇量，NSiOH / nm 2; NSiOH / nm 2 = 0.027 CTAB + 10.5。 这些二烯橡胶组合物可用于制造轮胎或用于轮胎的半成品。