摘要:
The use of compounds of the general formula I where A is ═N— or ═CH—; X when A is ═N— is methyl or a radical of the formula IIa or when A is ═CH— is an R radical; Y is an R radical or a radical of the formula IIb with either X being a radical of the formula IIa or Y being a radical of the formula IIb; R is hydrogen, halogen, C1-C4-alkyl, —SO3H, —SO3−Me+, —SO3−N+R1R2R3R4, —SO2NR1R2, —CH2NR1R2, —CH2R5, —COOH, —COO−N+R1R2R3R4, —COOR6 or —COR6; R1, R2, R3 and R4 are each independently hydrogen; C1-C22-alkyl or C2-C22-alkenyl whose carbon chain may in either case be interrupted by one or more —O—, —S—, —NR7—, —CO— or —SO2− moieties and/or which may be substituted by one or more of hydroxyl, halogen, aryl, C1-C4-alkoxy and acetyl; C3-C8-cycloalkyl whose carbon skeleton may be interrupted by one or more —O—, —S—, —NR7— or —CO— moieties and/or which may be substituted by one or more of hydroxyl, halogen, aryl, C1-C4-alkoxy and acetyl; hydroabietyl, abietyl or aryl; R1 and R2 or R1, R2 and R3 may combine to form a 5- to 7-membered cyclic radical which contains the nitrogen atom and may contain further hetero atoms; R5 is a radical of the formula IIb′ R6 is one of the R1 alkyl radicals; R7 is hydrogen or C1-C4-alkyl; Me is an alkali metal ion; Z and Z′ are each independently arylene which may be substituted by one or more of halogen, —SO3H, —SO3−Me+, —SO3−N+R1R2R3R4, and C1-C12-alkyl, and the rings B1 and B2 may each be independently additionally substituted by one or more identical or different R radicals other than hydrogen, as crystallization modifiers for organic pigments.
摘要:
The invention provides a process for preparing N,N′-di(3′,5′-dimethylphenyl) perylenebis(dicarboximide) by reaction of perylene-3,4,9,10-tetracarboxylic dianhydride with 3,5-dimethylaniline in the presence of a secondary or tertiary amine as catalyst, which comprises effecting the reaction in an aqueous reaction medium and in the presence of added seed crystals of N,N′-di(3′,5′-dimethylphenyl) perylenebis(dicarboximide).
摘要:
Black perylene pigments which comprise one of the isomers of the formula Ia or Ib in which R1, R2 are each independently phenylene, naphthylene or pyridylene, each of which may be mono- or polysubstituted by C1-C12-alkyl, C1-C6-alkoxy, hydroxyl, nitro, and/or halogen; X is halogen; n Is from 0 to 4, or comprises a mixture of both isomers and has a blackness value ≧210 in an alkyd/melamine baking varnish.
摘要:
Colorant composition consisting essentially of one or more cholesteric liquid-crystalline polymers having a pitch of the helical superstructure of between 760 nm and 500 &mgr;m, and of at least one colorant which absorbs light in the visible wavelength range. Suitable colorants are organic or inorganic pigments or dyes. Coatings featuring such colorant compositions are notable for heat insulation properties.
摘要:
Solid pigment preparations containing the following ingredients as substantial components: (A) 60–85 wt. % of at least one organic pigment, (B) 0.1–15 wt. % of at least one pigment derivative of general formula I wherein the variables have the following meanings: P is the radical of the parent substance of an organic pigment; T1, T2 independently represent a chemical bond, —CONR1— or —SO2NR1—; B1, B2 independently represent a chemical bond, C1–C8-alkylene or phenylene; X, Y independently represent similar or different groups —SO3— Ka+ or —COO— Ka+; m, n represent a rational number from 0 to 3, whereby 1=m+n=4; Ka+ H+, Li+, Na+, K+, N+R2R3 R4 R5 or a mixture of said cations; R1 represents hydrogen; C1–C4-alkyl; phenyl or naphthyl which can be respectively substituted by C1–C18-alkyl; R2, R3, R4, R5 independently represent hydrogen; C1–C30-alkyl; C3–C30-alkenyl; C5–C6-cycloalkyl which can be substituted by C1–C24-alkyl; phenyl or naphthyl which can be respectively substituted by C1–C24-alkyl or C2–C24-alkenyl; a radical of formula —[CHR6—CHR7—O]x—R8, wherein the repeating units —[CHR6—CHR7—O] for x >1 can vary; R6, R7, R8 independently represent hydrogen or C1–C6-alkyl; x is a whole number =1, and (C) 14.9 39.9 wt. % of at least one surface active additive from the group of non-ionic polyethers containing no primary amino groups, the acidic phosphoric acid esters, phosphonic acid esters, sulphuric acid esters and/or sulfonic acid esters thereof, the salts thereof and the condensation produces thereof with formaldehyde.
摘要:
The present invention relates to the use of wax-coated pigment granules as colorants in electrophotographic toners and developers, powder coating materials, inkjet inks, electret fibers, and color filters, wherein the coated pigment granules have a particle size of between 0.05 and 5 mm and a wax content of from 1 to 50% by weight, based on the overall weight of the coated pigment granules.
摘要:
The invention relates to compounds with the general formula Y1—A1—M1—A2—Y2 wherein Y1 and Y2 are different from each other and Y1 is an acrylate or methacrylate residue and Y2 is a vinyl ether, epoxy, or azide residue, A1 and A2 are identical or different residues with the general formula CnH2n in which n is a whole number from 0 to 20 and one or more methylene groups can be replaced by oxygen atoms, and M1 has the general formula —R1—X1—R2—X2—R3—X3—R4— wherein R1, R2, R3, and R4 are identical or different doubly bonded residues from the group —O—, —COO—, —CONH—, —CO—, —S—, —C≡C—, —CH═CH—, —CH═N—, —CH2—, —N═N—, and —N═N(O)—, and R2—X2—R3 can also be a C—C bond, and X1, X2, and X3 are identical or different residues from the group 1,4-phenylene, 1,4-cyclohexylene; arylalkane or heteroarylalkane with 1 to 10 carbon atoms which contains one to three heteroatoms from the group O, N, and S, substituted with B1, B2, and/or B3; and cycloalkylene with 1 to 10 carbon atoms and substituted with B1, B2, and/or B3, wherein B1, B2, and B3 can be identical or different substituents from the group —H, C1-C20-alkyl, C1-C20-alkoxy, C1-C20- alkylthio, C1-C20-alkylcarbonyl, C1-C20-alkoxycarbonyl, C1-C20-alkylthiocarbonyl, —OH, halogen (fluorine, chlorine, bromine, iodine), —CN, —NO2, cycloalkyl, formyl, acetyl, and alkyl, alkoxy, or alkylthio residues with 1-20 carbon atoms interrupted by ether oxygen, thioether sulfur, or ester groups.
摘要:
The invention relates to a process for generating a marking on an effect coating or molding compound comprising cholesteric liquid-crystalline main-chain or side-group polymers or comprising a combination of main-chain and side-group polymers, which comprises inducing a color change at the irradiated sites of the effect coating or molding compound by laser irradiation.
摘要:
The invention relates to a cholesteric liquid-crystalline polymer which in the molecule comprises at least one stabilizer comonomer from the group consisting of UV absorbers and antioxidants.
摘要:
The present invention discloses coated objects, such as car bodies, as well as coatings for coating such objects. In order to achieve new, hitherto unknown color effects with said coatings, at least some, and preferably only platelet-like interference pigments are mixed into the coating. When the coating is applied, the interference pigments automatically align themselves in a direction approximately parallel to the object surface. These interference pigments are made of liquid crystalline side chain polymers with a nematic and a chiral component, in which the side group mesogens are at least approximately nematic, smectic and/or cholesteric. Particularly intensive tones having a hitherto unknown brilliance may thus be obtained on a coated object, or a shimmering effect depending on the angle of incidence of light and viewing direction.