摘要:
An alignment film, a method for preparing the same, a liquid crystal display device including the alignment film. The alignment film is an oriented polyimide film. The method for preparing the alignment film includes: adding a bridging diphenyl diamine to N-methylpyrrolidinone, followed by the addition of 1,4,5,8-naphthalenetetracarboxylic dianhydride to allow the reaction to occur, and filtering the reaction mixture to give a liquid polyamide acid; dissolving the liquid polyamide acid into N-methylpyrrolidinone to give a solution, which is coated onto the surface of a substrate and subjected to a heat treatment, to produce a polyimide film; and orienting the polyimide film via an orientation process to form an alignment film, wherein, polyimide has a structure represented by Formula-4: wherein, R is a strong electron withdrawing group, each of R1 and R2 is independently methyl, ethyl, propyl, isopropyl, methoxy, ethoxy, propoxy, or isopropoxy, The polyimide film has good optical transmittance.
摘要:
Lithium-ion electrochemical cells are provided that include a positive electrode that includes a lithium metal oxide or a lithium metal phosphate, a negative electrode capable of intercalating or alloying with lithium, and an electrolyte that includes an additive. The additive includes a multifunctional anion that has the formula, X—SO2—Rf—SO2—Y, wherein X and Y are, independently, either O— or RfSO2N—, Rf is a straight or branched fluoroalkyl moiety having from 1 to 6 carbon atoms, and can, optionally, contain one or more in-chain heteroatoms, wherein Rf is a straight or branched chain or cyclic fluoroalkylene having from 1 to 10 carbon atoms and can, optionally, contain one or more in-chain heteroatoms, and wherein both Rf and Rf have a maximum of 20% non-fluorine substituents. The provided additives can improve the performance, hydrolytic stability, and thermal stability of the provided electrochemical cells.
摘要:
The invention provides a liquid crystal alignment film, a method for preparing the same and a liquid crystal display device comprising the same. The alignment film comprises polyimide obtained by reacting the compound as shown in Formula 2 or Formula 3 with the aromatic diamine as shown in Formula 1, wherein the R1, R2, R3, R4, R5, R6, R7, R1′, R2′, R3′, R4′, R5′, R6′, R7′, or R8′ substituent is H, alkyl, aralkyl or haloalkyl, and the Ar is aryl. The liquid crystal alignment film has a tactic spatial configuration, decreases the π-π attractive interaction between the polyimide backbones, allows the directional and homogenous alignment of the liquid crystal molecules on the surface of the polyimide, and thereby increases the contrast of the liquid crystal display.
摘要:
A lithium ion battery electrolyte for use in lithium ion batteries. The electrolyte includes LiPF6, LiBF4, LiB(C2O4)2, or a related salt dissolved in a mixture of organic carbonate, ether or ester solvents with low concentrations of oxidatively unstable additives such that the additives react with a surface of cathode particles to generate a passivation film which prevents oxidation of the electrolyte by the cathode. The additive is a polymerizable organic molecule selected from 2,3-dihydrofuran (2,3-DHF), 2,5-dihydrofuran (2,5-DHF), vinylene carbonate (VC), vinyltrimethoxysilane (VTMS), dimethyl vinylene cabonate (DMVC), and gamma-buyrolactone, or related unsaturated ethers, esters, or carbonates.
摘要翻译:锂离子电池用锂离子电池。 电解质包括LiPF 6,LiBF 4,LiB(C 2 O 4)2或溶解在低浓度氧化不稳定的添加剂的有机碳酸酯,醚或酯溶剂的混合物中的相关盐,使得添加剂与阴极颗粒的表面反应产生 防止阴极氧化电解质的钝化膜。 添加剂是选自2,3-二氢呋喃(2,3-DHF),2,5-二氢呋喃(2,5-DHF),碳酸亚乙烯酯(VC),乙烯基三甲氧基硅烷(VTMS),二甲基亚乙烯基二 DMVC)和γ-丁内酯,或相关的不饱和醚,酯或碳酸酯。
摘要:
Lithium-ion electrochemical cells are provided that include a positive electrode that includes a lithium metal oxide or a lithium metal phosphate, a negative electrode capable of intercalating or alloying with lithium, and an electrolyte that includes an additive. The additive includes a multifunctional anion that has the formula, X—SO2—Rf′—SO2—Y, wherein X and Y are, independently, either O— or RfSO2N—, Rf is a straight or branched fluoroalkyl moiety having from 1 to 6 carbon atoms, and can, optionally, contain one or more in-chain heteroatoms, wherein Rf′ is a straight or branched chain or cyclic fluoroalkylene having from 1 to 10 carbon atoms and can, optionally, contain one or more in-chain heteroatoms, and wherein both Rf and Rf′ have a maximum of 20% non-fluorine substituents. The provided additives can improve the performance, hydrolytic stability, and thermal stability of the provided electrochemical cells.
摘要:
A non-aqueous electrolyte usable in rechargeable lithium-ion batteries including a solution of LiPF6/carbonate based electrolytes with low concentrations of LiFOP such that the thermal stability is increased compared to a standard lithium battery. A method of making lithium tetrafluorophospahte (LiF4C2O4, LiFOP) including, reacting PF5 with lithium oxalate, recrystallizing DMC/dichloromethane from a 1:1 mixture of to separate LiF4OP from LiPF6 to form a lithium salt. An electric current producing rechargeable Li-ion cell. The rechargeable lithium ion cell includes an anode, a cathode, and a non-aqueous electrolyte comprising a solution of a lithium salt in a non-aqueous organic solvent containing lithium tetrafluorooxalatophosphate (LiPF4(C2O4), LiF4OP).
摘要翻译:可用于可再充电锂离子电池的非水电解质,其包括LiPF 6的LiPF 6 /碳酸盐基电解质溶液,使得与标准锂电池相比热稳定性增加。 制备四氟磷酸锂(LiF 4 C 2 O 4,LiFOP)的方法,其包括使PF5与草酸锂反应,从1:1的混合物中重结晶DMC /二氯甲烷以从LiPF 6分离LiF 4 OP以形成锂盐。 一种产生可再充电锂离子电池的电流。 可充电锂离子电池包括阳极,阴极和包含锂盐在含有四氟草酸磷酸锂(LiPF 4(C 2 O 4),LiF 4 OP)的非水有机溶剂中的溶液的非水电解质。
摘要:
Electrochemical cells, and more specifically, release systems for the fabrication of electrochemical cells are described. In particular, release layer arrangements, assemblies, methods and compositions that facilitate the fabrication of electrochemical cell components, such as electrodes, are presented. In some embodiments, methods of fabricating an electrode involve the use of a release layer to separate portions of the electrode from a carrier substrate on which the electrode was fabricated. For example, an intermediate electrode assembly may include, in sequence, an electroactive material layer, a current collector layer, a release layer, and a carrier substrate. The carrier substrate can facilitate handling of the electrode during fabrication and/or assembly, but may be released from the electrode prior to commercial use.
摘要:
The invention provides a liquid crystal alignment film, a method for preparing the same and a liquid crystal display device comprising the same. The alignment film comprises a polyimide obtained by reacting a compound as shown in Formula 2 or Formula 3 with an aromatic diamine as shown in Formula 1, wherein the R1, R2, R3, R4, R5, R6, R7, R1′, R2′, R3′, R4′, R5′, R6′, R7′, or R8′ is H, an alkyl, an aralkyl or a haloalkyl, and the Ar is an aryl. The liquid crystal alignment film has a tactic spatial configuration, decreases the π-π attractive interaction between the polyimide backbones, allows the directional and homogenous alignment of the liquid crystal molecules on the surface of the polyimide, and thereby increases the contrast of the liquid crystal display.