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1.发明申请INHIBITION OF ELECTROLYTE OXIDATION IN LITHIUM ION BATTERIES WITH ELECTROLYTE ADDITIVES 审中-公开用电解质添加剂在锂离子电池中抑制电解氧化公开(公告)号：US20110117446A1
公开(公告)日：2011-05-19
申请号：US12975477
申请日：2010-12-22
申请人： Brett Lucht , Li Yang , Mengqing Xu , Ang Xiao
发明人： Brett Lucht , Li Yang , Mengqing Xu , Ang Xiao
IPC分类号： H01M10/056
CPC分类号： H01M10/052 , H01M2/16 , H01M10/0525 , H01M10/056 , H01M10/0567 , H01M2300/0025 , H01M2300/0091 , Y02T10/7011
摘要： A lithium ion battery electrolyte for use in lithium ion batteries. The electrolyte includes LiPF6, LiBF4, LiB(C2O4)2, or a related salt dissolved in a mixture of organic carbonate, ether or ester solvents with low concentrations of oxidatively unstable additives such that the additives react with a surface of cathode particles to generate a passivation film which prevents oxidation of the electrolyte by the cathode. The additive is a polymerizable organic molecule selected from 2,3-dihydrofuran (2,3-DHF), 2,5-dihydrofuran (2,5-DHF), vinylene carbonate (VC), vinyltrimethoxysilane (VTMS), dimethyl vinylene cabonate (DMVC), and gamma-buyrolactone, or related unsaturated ethers, esters, or carbonates.
摘要翻译： 锂离子电池用锂离子电池。 电解质包括LiPF 6，LiBF 4，LiB（C 2 O 4）2或溶解在低浓度氧化不稳定的添加剂的有机碳酸酯，醚或酯溶剂的混合物中的相关盐，使得添加剂与阴极颗粒的表面反应产生 防止阴极氧化电解质的钝化膜。 添加剂是选自2,3-二氢呋喃（2,3-DHF），2,5-二氢呋喃（2,5-DHF），碳酸亚乙烯酯（VC），乙烯基三甲氧基硅烷（VTMS），二甲基亚乙烯基二 DMVC）和γ-丁内酯，或相关的不饱和醚，酯或碳酸酯。
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公开(公告)号：US08334404B2
公开(公告)日：2012-12-18
申请号：US12553366
申请日：2009-09-03
申请人： Brett Lucht , Ang Xiao , Li Yang , Mengqing Xu
发明人： Brett Lucht , Ang Xiao , Li Yang , Mengqing Xu
IPC分类号： C07F9/02
CPC分类号： H01M10/0525 , H01M4/131 , H01M4/133 , H01M10/0566 , H01M10/0568 , H01M10/0569
摘要： A non-aqueous electrolyte usable in rechargeable lithium-ion batteries including a solution of LiPF6/carbonate based electrolytes with low concentrations of LiFOP such that the thermal stability is increased compared to a standard lithium battery. A method of making lithium tetrafluorophospahte (LiF4C2O4, LiFOP) including, reacting PF5 with lithium oxalate, recrystallizing DMC/dichloromethane from a 1:1 mixture of to separate LiF4OP from LiPF6 to form a lithium salt. An electric current producing rechargeable Li-ion cell. The rechargeable lithium ion cell includes an anode, a cathode, and a non-aqueous electrolyte comprising a solution of a lithium salt in a non-aqueous organic solvent containing lithium tetrafluorooxalatophosphate (LiPF4(C2O4), LiF4OP).
摘要翻译： 可用于可再充电锂离子电池的非水电解质，其包括LiPF 6的LiPF 6 /碳酸盐基电解质溶液，使得与标准锂电池相比热稳定性增加。 制备四氟磷酸锂（LiF 4 C 2 O 4，LiFOP）的方法，其包括使PF5与草酸锂反应，从1:1的混合物中重结晶DMC /二氯甲烷以从LiPF 6分离LiF 4 OP以形成锂盐。 一种产生可再充电锂离子电池的电流。 可充电锂离子电池包括阳极，阴极和包含锂盐在含有四氟草酸磷酸锂（LiPF 4（C 2 O 4），LiF 4 OP）的非水有机溶剂中的溶液的非水电解质。
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公开(公告)号：US20100062346A1
公开(公告)日：2010-03-11
申请号：US12553366
申请日：2009-09-03
申请人： Brett Lucht , Ang Xiao , Li Yang , Mengqing Xu
发明人： Brett Lucht , Ang Xiao , Li Yang , Mengqing Xu
CPC分类号： H01M10/0525 , H01M4/131 , H01M4/133 , H01M10/0566 , H01M10/0568 , H01M10/0569
摘要： A non-aqueous electrolyte usable in rechargeable lithium-ion batteries including a solution of LiPF6/carbonate based electrolytes with low concentrations of LiFOP such that the thermal stability is increased compared to a standard lithium battery. A method of making lithium tetrafluorophospahte (LiF4C2O4, LiFOP) including, reacting PF5 with lithium oxalate, recrystallizing DMC/dichloromethane from a 1:1 mixture of to separate LiF4OP from LiPF6 to form a lithium salt. An electric current producing rechargeable Li-ion cell. The rechargeable lithium ion cell includes an anode, a cathode, and a non-aqueous electrolyte comprising a solution of a lithium salt in a non-aqueous organic solvent containing lithium tetrafluorooxalatophosphate (LiPF4(C2O4), LiF4OP).
摘要翻译： 可用于可再充电锂离子电池的非水电解质，其包括LiPF 6的LiPF 6 /碳酸盐基电解质溶液，使得与标准锂电池相比热稳定性增加。 制备四氟磷酸锂（LiF 4 C 2 O 4，LiFOP）的方法，其包括使PF5与草酸锂反应，从1:1的混合物中重结晶DMC /二氯甲烷以从LiPF 6分离LiF 4 OP以形成锂盐。 一种产生可充电锂离子电池的电流。 可充电锂离子电池包括阳极，阴极和包含锂盐在含有四氟草酸磷酸锂（LiPF 4（C 2 O 4），LiF 4 OP）的非水有机溶剂中的溶液的非水电解质。
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4.发明授权公开(公告)号：US09701793B2
公开(公告)日：2017-07-11
申请号：US14387029
申请日：2013-11-12
申请人： Ang Xiao , Shanshan Wang
发明人： Ang Xiao , Shanshan Wang
IPC分类号： C09K19/00 , C08G73/10 , C09K19/56 , G02F1/1337 , C09D179/08
CPC分类号： C08G73/1067 , C08G73/1039 , C08G73/105 , C08G73/1064 , C08G73/1071 , C09D179/08 , C09K19/56 , G02F1/133723 , Y10T428/1005 , Y10T428/1023
摘要： An alignment film, a method for preparing the same, a liquid crystal display device including the alignment film. The alignment film is an oriented polyimide film. The method for preparing the alignment film includes: adding a bridging diphenyl diamine to N-methylpyrrolidinone, followed by the addition of 1,4,5,8-naphthalenetetracarboxylic dianhydride to allow the reaction to occur, and filtering the reaction mixture to give a liquid polyamide acid; dissolving the liquid polyamide acid into N-methylpyrrolidinone to give a solution, which is coated onto the surface of a substrate and subjected to a heat treatment, to produce a polyimide film; and orienting the polyimide film via an orientation process to form an alignment film, wherein, polyimide has a structure represented by Formula-4: wherein, R is a strong electron withdrawing group, each of R1 and R2 is independently methyl, ethyl, propyl, isopropyl, methoxy, ethoxy, propoxy, or isopropoxy, The polyimide film has good optical transmittance.
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5.发明授权Lithium-ion electrochemical cells including fluorocarbon electrolyte additives 有权锂离子电化学电池包括氟碳电解质添加剂公开(公告)号：US09455472B2
公开(公告)日：2016-09-27
申请号：US14122596
申请日：2012-05-30
IPC分类号： H01M6/04 , H01M6/14 , H01M10/0564 , H01M10/0525 , H01M10/0567 , H01M10/0565 , H01M4/505 , H01M4/525 , H01M4/58
CPC分类号： H01M10/0564 , H01M4/505 , H01M4/525 , H01M4/5825 , H01M10/0525 , H01M10/0565 , H01M10/0567 , H01M2300/0025 , H01M2300/0065 , H01M2300/0082 , H01M2300/0085 , Y02E60/122 , Y02T10/7011
摘要： Lithium-ion electrochemical cells are provided that include a positive electrode that includes a lithium metal oxide or a lithium metal phosphate, a negative electrode capable of intercalating or alloying with lithium, and an electrolyte that includes an additive. The additive includes a multifunctional anion that has the formula, X—SO2—Rf—SO2—Y, wherein X and Y are, independently, either O— or RfSO2N—, Rf is a straight or branched fluoroalkyl moiety having from 1 to 6 carbon atoms, and can, optionally, contain one or more in-chain heteroatoms, wherein Rf is a straight or branched chain or cyclic fluoroalkylene having from 1 to 10 carbon atoms and can, optionally, contain one or more in-chain heteroatoms, and wherein both Rf and Rf have a maximum of 20% non-fluorine substituents. The provided additives can improve the performance, hydrolytic stability, and thermal stability of the provided electrochemical cells.
摘要翻译： 提供了包括包含锂金属氧化物或锂金属磷酸盐的正极，能够与锂嵌入或合金化的负极以及包含添加剂的电解质的锂离子电化学电池。 添加剂包括具有下式的多官能阴离子：X-SO 2 -R f -SO 2 -Y，其中X和Y独立地是O-或RfSO 2 N-，Rf是具有1-6个碳原子的直链或支链氟烷基部分 原子，并且可以任选地含有一个或多个在链的杂原子，其中R f是具有1至10个碳原子的直链或支链或环状氟代亚烷基，并且可以任选地含有一个或多个链内杂原子，并且其中 Rf和Rf均具有最多20％的非氟取代基。 所提供的添加剂可以提高所提供的电化学电池的性能，水解稳定性和热稳定性。
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6.发明申请LIQUID CRYSTAL ALIGNMENT FILM, METHOD FOR PREPARING SAME AND LIQUID CRYSTAL DISPLAY DEVICE COMPRISING SAME 有权液晶体对准膜，其制备方法和包含其的液晶显示装置公开(公告)号：US20130150523A1
公开(公告)日：2013-06-13
申请号：US13703668
申请日：2012-09-07
申请人： Ang Xiao , Haibo Zhu , Sunghun Song , Wei Li , Zhiyong Liu
发明人： Ang Xiao , Haibo Zhu , Sunghun Song , Wei Li , Zhiyong Liu
IPC分类号： C09D179/08
CPC分类号： C09D179/08 , G02F1/133723 , G02F1/133784 , Y10T428/10 , Y10T428/1005 , Y10T428/1023
摘要： The invention provides a liquid crystal alignment film, a method for preparing the same and a liquid crystal display device comprising the same. The alignment film comprises polyimide obtained by reacting the compound as shown in Formula 2 or Formula 3 with the aromatic diamine as shown in Formula 1, wherein the R1, R2, R3, R4, R5, R6, R7, R1′, R2′, R3′, R4′, R5′, R6′, R7′, or R8′ substituent is H, alkyl, aralkyl or haloalkyl, and the Ar is aryl. The liquid crystal alignment film has a tactic spatial configuration, decreases the π-π attractive interaction between the polyimide backbones, allows the directional and homogenous alignment of the liquid crystal molecules on the surface of the polyimide, and thereby increases the contrast of the liquid crystal display.
摘要翻译： 本发明提供一种液晶取向膜，其制备方法和包含该液晶取向膜的液晶显示装置。 取向膜包括通过如式2或式3所示的化合物与式1所示的芳族二胺反应得到的聚酰亚胺，其中R1，R2，R3，R4，R5，R6，R7，R1'，R2'， R 3'，R 4'，R 5'，R 6'，R 7'或R 8'取代基是H，烷基，芳烷基或卤代烷基，Ar是芳基。 液晶取向膜具有策略空间结构，降低了聚酰亚胺主链之间的吸引力相互作用，允许液晶分子在聚酰亚胺表面上的定向和均匀取向，从而增加液晶的对比度 显示。
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7.发明申请LITHIUM-ION ELECTROCHEMICAL CELLS INCLUDING FLUOROCARBON ELECTROLYTE ADDITIVES 有权锂离子电化学电池，包括荧光电解质添加剂公开(公告)号：US20140093783A1
公开(公告)日：2014-04-03
申请号：US14122596
申请日：2012-05-30
IPC分类号： H01M10/0564 , H01M10/0565 , H01M10/0525 , H01M10/0567
CPC分类号： H01M10/0564 , H01M4/505 , H01M4/525 , H01M4/5825 , H01M10/0525 , H01M10/0565 , H01M10/0567 , H01M2300/0025 , H01M2300/0065 , H01M2300/0082 , H01M2300/0085 , Y02E60/122 , Y02T10/7011
摘要： Lithium-ion electrochemical cells are provided that include a positive electrode that includes a lithium metal oxide or a lithium metal phosphate, a negative electrode capable of intercalating or alloying with lithium, and an electrolyte that includes an additive. The additive includes a multifunctional anion that has the formula, X—SO2—Rf′—SO2—Y, wherein X and Y are, independently, either O— or RfSO2N—, Rf is a straight or branched fluoroalkyl moiety having from 1 to 6 carbon atoms, and can, optionally, contain one or more in-chain heteroatoms, wherein Rf′ is a straight or branched chain or cyclic fluoroalkylene having from 1 to 10 carbon atoms and can, optionally, contain one or more in-chain heteroatoms, and wherein both Rf and Rf′ have a maximum of 20% non-fluorine substituents. The provided additives can improve the performance, hydrolytic stability, and thermal stability of the provided electrochemical cells.
摘要翻译： 提供了包括包含锂金属氧化物或锂金属磷酸盐的正极，能够与锂嵌入或合金化的负极以及包含添加剂的电解质的锂离子电化学电池。 添加剂包括具有下式的多官能阴离子：X-SO 2 -R f'-SO 2 -Y，其中X和Y独立地为O-或RfSO 2 N-，R f为具有1-6个碳原子的直链或支链氟烷基部分 碳原子，并且可以任选地含有一个或多个在线的杂原子，其中R f'是具有1至10个碳原子的直链或支链或环状氟代亚烷基，并且可任选地含有一个或多个链内杂原子， 并且其中Rf和Rf'都具有最多20％的非氟取代基。 所提供的添加剂可以提高所提供的电化学电池的性能，水解稳定性和热稳定性。
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公开(公告)号：US20110068001A1
公开(公告)日：2011-03-24
申请号：US12862513
申请日：2010-08-24
申请人： John D. Affinito , John A. Martens , Ang Xiao , Christopher T.S. Campbell , Yuriy V. Mikhaylik , Igor Kovalev , Ashley H. Bulldis , Zhesheng Xu
发明人： John D. Affinito , John A. Martens , Ang Xiao , Christopher T.S. Campbell , Yuriy V. Mikhaylik , Igor Kovalev , Ashley H. Bulldis , Zhesheng Xu
CPC分类号： H01M4/667 , B32B37/12 , B32B2037/246 , B32B2038/168 , B32B2307/748 , B32B2310/0806 , B32B2457/10 , H01M4/0404 , H01M4/13 , H01M4/134 , H01M4/139 , H01M4/1395 , H01M4/382 , H01M4/662 , H01M10/052
摘要： Electrochemical cells, and more specifically, release systems for the fabrication of electrochemical cells are described. In particular, release layer arrangements, assemblies, methods and compositions that facilitate the fabrication of electrochemical cell components, such as electrodes, are presented. In some embodiments, methods of fabricating an electrode involve the use of a release layer to separate portions of the electrode from a carrier substrate on which the electrode was fabricated. For example, an intermediate electrode assembly may include, in sequence, an electroactive material layer, a current collector layer, a release layer, and a carrier substrate. The carrier substrate can facilitate handling of the electrode during fabrication and/or assembly, but may be released from the electrode prior to commercial use.
摘要翻译： 描述了电化学电池，更具体地说，用于制造电化学电池的释放系统。 特别地，提出了有助于制造电化学电池元件（例如电极）的释放层布置，组件，方法和组合物。 在一些实施例中，制造电极的方法包括使用剥离层来将电极的部分与其上制造电极的载体基板分离。 例如，中间电极组件可以依次包括电活性材料层，集电器层，释放层和载体衬底。 载体衬底可以在制造和/或组装期间促进电极的处理，但可以在商业使用之前从电极释放。
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