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公开(公告)号：US09012675B2
公开(公告)日：2015-04-21
申请号：US13119407
申请日：2009-09-17
CPC分类号： C08G64/0208 , C08G64/34 , C08G64/406
摘要： The present disclosure is directed to, in part, an aliphatic polycarbonate polymerization reaction initiated by combining an epoxide with carbon dioxide in the presence of a catalytic transition metal-ligand complex to form a reaction mixture, and further quenching that polymerization reaction by contacting the reaction mixture with an acid containing a non-nucleophilic anion produces a crude polymer solution with improved stability and processability.
摘要翻译： 本公开部分地涉及通过在催化过渡金属 - 配体络合物的存在下将环氧化物与二氧化碳结合以形成反应混合物引发的脂族聚碳酸酯聚合反应，并通过使反应接触进一步淬灭该聚合反应 与含有非亲核阴离子的酸的混合物产生具有改进的稳定性和加工性的粗聚合物溶液。
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公开(公告)号：US08252891B2
公开(公告)日：2012-08-28
申请号：US13119408
申请日：2009-09-17
CPC分类号： C08G64/0208 , C08G64/34 , C08G64/406
摘要： The present disclosure provides, in part, a method for removing a catalyst from a product of catalyzed aliphatic polycarbonate polymerization reaction.
摘要翻译： 本公开部分地提供了从催化的脂肪族聚碳酸酯聚合反应的产物中除去催化剂的方法。
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公开(公告)号：US20110207899A1
公开(公告)日：2011-08-25
申请号：US13119407
申请日：2009-09-17
IPC分类号： C08G64/34
CPC分类号： C08G64/0208 , C08G64/34 , C08G64/406
摘要： The present disclosure is directed to, in part, an aliphatic polycarbonate polymerization reaction initiated by combining an epoxide with carbon dioxide in the presence of a catalytic transition metal-ligand complex to form a reaction mixture, and further quenching that polymerization reaction by contacting the reaction mixture with an acid containing a non-nucleophilic anion produces a crude polymer solution with improved stability and processability.
摘要翻译： 本公开部分地涉及通过在催化过渡金属 - 配体络合物的存在下将环氧化物与二氧化碳结合以形成反应混合物引发的脂族聚碳酸酯聚合反应，并通过使反应接触进一步淬灭该聚合反应 与含有非亲核阴离子的酸的混合物产生具有改进的稳定性和加工性的粗聚合物溶液。
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公开(公告)号：US20110201779A1
公开(公告)日：2011-08-18
申请号：US13119408
申请日：2009-09-17
CPC分类号： C08G64/0208 , C08G64/34 , C08G64/406
摘要： The present disclosure provides, in part, a method for removing a catalyst from a product of catalyzed aliphatic polycarbonate polymerization reaction.
摘要翻译： 本公开部分地提供了从催化的脂肪族聚碳酸酯聚合反应的产物中除去催化剂的方法。
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公开(公告)号：US08575245B2
公开(公告)日：2013-11-05
申请号：US13141532
申请日：2009-12-18
IPC分类号： C08L69/00 , C08K5/3415 , C08K5/59 , C08K5/19
CPC分类号： C08G64/183 , C08G64/0208 , C08G64/34 , C08K5/19 , C08L69/00
摘要： The present invention provides polycarbonate compositions having a tunable decomposition temperature. Suitable cationic additives (e.g., phosphonium, phosphazene, quaternary ammonium, guanidinium, pyridinium, arsonium, etc.) are disclosed for lowering the decomposition temperature of polymer compositions. The invention further provides methods of preparing such polymer compositions with tunable decomposition temperatures.
摘要翻译： 本发明提供具有可调分解温度的聚碳酸酯组合物。 公开了适合的阳离子添加剂（例如鏻，磷腈，季铵，胍，吡啶鎓，ium等）以降低聚合物组合物的分解温度。 本发明还提供了制备具有可调分解温度的聚合物组合物的方法。
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公开(公告)号：US20110257296A1
公开(公告)日：2011-10-20
申请号：US13141532
申请日：2009-12-18
IPC分类号： C08L69/00 , C08K5/3415 , C08K5/59 , C08K5/19 , C08K5/5399
CPC分类号： C08G64/183 , C08G64/0208 , C08G64/34 , C08K5/19 , C08L69/00
摘要： The present invention provides polymer compositions having a tunable decomposition temperature. Suitable additives are disclosed for lowering the decomposition temperature of polymer compositions. The invention further provides methods of preparing such polymer compositions with tunable decomposition temperatures.
摘要翻译： 本发明提供具有可调分解温度的聚合物组合物。 公开了用于降低聚合物组合物的分解温度的合适的添加剂。 本发明还提供了制备具有可调分解温度的聚合物组合物的方法。
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公开(公告)号：US20110152497A1
公开(公告)日：2011-06-23
申请号：US13059967
申请日：2009-08-24
申请人： Scott D. Allen , Anna E. Cherian , Chris A. Simoneau , Jay J. Farmer , Geoffrey W. Coates , Alexei Gridnev , Robert E. LaPointe
发明人： Scott D. Allen , Anna E. Cherian , Chris A. Simoneau , Jay J. Farmer , Geoffrey W. Coates , Alexei Gridnev , Robert E. LaPointe
CPC分类号： C07F15/065 , B01J31/0239 , B01J31/0259 , B01J31/0265 , B01J31/182 , B01J31/183 , B01J31/1835 , B01J31/2243 , B01J2531/0238 , B01J2531/025 , B01J2531/0252 , B01J2531/0294 , B01J2531/31 , B01J2531/62 , B01J2531/845 , C07C251/24 , C07C279/12 , C07C2601/14 , C07D213/53 , C07D487/04 , C07D487/22 , C07F9/5355 , C07F9/6561 , C07F19/005 , C08F4/80 , C08G64/34
摘要： The present invention provides unimolecular metal complexes having increased activity in the copolymerization of carbon dioxide and epoxides. Also provided are methods of using such metal complexes in the synthesis of polymers. According to one aspect, the present invention provides metal complexes comprising an activating species with co-catalytic activity tethered to a multidentate ligand that is coordinated to the active metal center of the complex.
摘要翻译： 本发明提供了在二氧化碳和环氧化物的共聚中具有增加的活性的单分子金属络合物。 还提供了在合成聚合物中使用这种金属络合物的方法。 根据一个方面，本发明提供金属络合物，其包含与辅助配位体配位的辅助催化活性的活化物质，其与配合物的活性金属中心配位。
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公开(公告)号：US08445703B2
公开(公告)日：2013-05-21
申请号：US13262985
申请日：2010-04-07
申请人： Scott D. Allen , Ronald R. Valente , Han Lee , Anna E. Cherian , Donald L. Bunning , Nye A. Clinton , Olan Stanley Fruchey , Bernard Duane Dombek
发明人： Scott D. Allen , Ronald R. Valente , Han Lee , Anna E. Cherian , Donald L. Bunning , Nye A. Clinton , Olan Stanley Fruchey , Bernard Duane Dombek
IPC分类号： C07D305/12
CPC分类号： C07C51/377 , C07C51/09 , C07C67/30 , C07C67/317 , C07C231/14 , C07D305/12 , C07D307/60 , C08G63/08 , Y02P20/584
摘要： The present application provides a method for producing an beta-lactone product. The method includes the steps of: reacting an epoxide, a solvent with a carbonylation catalyst and carbon monoxide to produce a reaction stream comprising a beta-lactone then separating a portion of the beta-lactone in the reaction stream from the solvent and carbonylation catalyst to produce: i) a beta-lactone stream with the beta-lactone, and ii) a catalyst recycling stream including the carbonylation catalyst and the high boiling solvent; and adding the catalyst recycling stream to the feed stream.
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公开(公告)号：US08247520B2
公开(公告)日：2012-08-21
申请号：US12994544
申请日：2009-09-08
申请人： Scott D. Allen , Geoffrey W. Coates , Anna E. Cherian , Chris A. Simoneau , Alexei A. Gridnev , Jay J. Farmer
发明人： Scott D. Allen , Geoffrey W. Coates , Anna E. Cherian , Chris A. Simoneau , Alexei A. Gridnev , Jay J. Farmer
CPC分类号： C08G64/34 , C08G18/44 , C08G64/0208
摘要： In one aspect, the present disclosure encompasses polymerization systems for the copolymerization of CO2 and epoxides comprising 1) a catalyst including a metal coordination compound having a permanent ligand set and at least one ligand that is a polymerization initiator, and 2) a chain transfer agent having two or more sites that can initiate polymerization. In a second aspect, the present disclosure encompasses methods for the synthesis of polycarbonate polyols using the inventive polymerization systems. In a third aspect, the present disclosure encompasses polycarbonate polyol compositions characterized in that the polymer chains have a high percentage of —OH end groups and a high percentage of carbonate linkages. The compositions are further characterized in that they contain polymer chains having an embedded polyfunctional moiety linked to a plurality of individual polycarbonate chains.
摘要翻译： 一方面，本公开内容涵盖用于CO 2和环氧化物共聚的聚合体系，其包括1）包含具有永久性配体组的金属配位化合物和至少一种作为聚合引发剂的配体的催化剂，和2）链转移剂 具有两个或更多个可引发聚合的位点。 在第二方面，本发明包括使用本发明聚合体系合成聚碳酸酯多元醇的方法。 在第三方面，本公开内容包括聚碳酸酯多元醇组合物，其特征在于聚合物链具有高百分比的-OH端基和高百分比的碳酸酯键。 组合物的特征还在于它们含有聚合物链，其具有与多个单独的聚碳酸酯链连接的嵌入的多官能部分。
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公开(公告)号：US20120123137A1
公开(公告)日：2012-05-17
申请号：US13262985
申请日：2010-04-07
申请人： Scott D. Allen , Ronald R. Valente , Han Lee , Anna E. Cherian , Donald L. Bunning , Nye A. Clinton , Olan Stanley Fruchey , Bernard Duane Dombek
发明人： Scott D. Allen , Ronald R. Valente , Han Lee , Anna E. Cherian , Donald L. Bunning , Nye A. Clinton , Olan Stanley Fruchey , Bernard Duane Dombek
IPC分类号： C07D305/12
CPC分类号： C07C51/377 , C07C51/09 , C07C67/30 , C07C67/317 , C07C231/14 , C07D305/12 , C07D307/60 , C08G63/08 , Y02P20/584
摘要： The present application provides a method for producing an beta-lactone product. The method includes the steps of: reacting an epoxide, a solvent with a carbonylation catalyst and carbon monoxide to produce a reaction stream comprising a beta-lactone then separating a portion of the beta-lactone in the reaction stream from the solvent and carbonylation catalyst to produce: i) a beta-lactone stream with the beta-lactone, and ii) a catalyst recycling stream including the carbonylation catalyst and the high boiling solvent; and adding the catalyst recycling stream to the feed stream.
摘要翻译： 本申请提供了生产β-内酯产物的方法。 该方法包括以下步骤：使环氧化物，溶剂与羰基化催化剂和一氧化碳反应，以产生包含β-内酯的反应物流，然后将反应物流中的一部分β-内酯与溶剂和羰基化催化剂分离成 产生：i）具有β-内酯的β-内酯流，和ii）包含羰基化催化剂和高沸点溶剂的催化剂再循环流; 并将催化剂再循环流加入进料流中。
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