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    Cerium based phosphor materials for solid-state lighting applications
    1.
    发明授权
    Cerium based phosphor materials for solid-state lighting applications 有权
    用于固态照明应用的铈基磷光体材料

    公开(公告)号：US08920676B2

    公开(公告)日：2014-12-30

    申请号：US11541708

    申请日：2006-10-02

    申请人： Anthony K. Cheetham ,  Ronan P. Le Toquin

    发明人： Anthony K. Cheetham ,  Ronan P. Le Toquin

    IPC分类号： C09K11/08 ,  C09K11/66 ,  H01J1/52 ,  H01J19/40 ,  C09K11/77 ,  H01L33/50 ,  H05B33/14

    CPC分类号： C09K11/7721 ,  C09K11/0883 ,  H01L33/502 ,  H05B33/14 ,  Y02B20/181

    摘要： A luminescent cerium (Ce) doped compound emitting bright red light, comprising a calcium silicate nitride ternary system, such as CaSiN2-δOδ:Ce3+, that crystallizes in a face-centered cubic unit cell with a lattice parameter of ˜a=14.88 Å. The Ce doped compound can be used for white light applications either: (i) to enhance the light quality of the system based on a blue LED with a yellow or green phosphor, (ii) as an orange phosphor in combination with a blue LED and a green phosphor, or (iii) as a red phosphor in a setup comprising a ultraviolet (UV) LED and red, green and blue (RGB) phosphors. Substitution of smaller elements on the Ca site or larger elements on the Si site leads to a decrease of the emission wavelength towards the yellow or orange region.

    摘要翻译： 包含硅酸钙氮化物三元体系如CaSiN 2-δOδ：Ce 3+的发光的明亮的红光的发光铈（Ce）掺杂化合物，其结晶在具有〜a = 14.88的晶格参数的面心立方晶胞中。 Ce掺杂的化合物可以用于白光应用：（i）基于具有黄色或绿色磷光体的蓝色LED来提高系统的光质，（ii）作为橙色荧光粉与蓝色LED组合，以及 绿色荧光体，或（iii）在包括紫外线（UV）LED和红色，绿色和蓝色（RGB））荧光体的设置中的红色荧光体。 在Ca位置上取代更小的元素或Si位点上的较大元素导致朝向黄色或橙色区域的发射波长的减小。

    Red phosphors for solid state lighting
    2.
    发明授权
    Red phosphors for solid state lighting 有权
    红色荧光粉用于固态照明

    公开(公告)号：US07220369B2

    公开(公告)日：2007-05-22

    申请号：US11350698

    申请日：2006-02-08

    申请人： Anthony K. Cheetham ,  Neeraj Sharma

    发明人： Anthony K. Cheetham ,  Neeraj Sharma

    IPC分类号： C09K11/69

    CPC分类号： C09K11/7736 ,  C09K11/7794 ,  H01L33/502

    摘要： A red phosphor composition in combination with a semiconductor light emitting device (e.g., VCSEL, LED, or LD), preferably a GaN based device, that emits light at a bright violet-blue light range, i.e., having a wavelength in the range of 400 nm to 600 nm, which can be further combined with green and blue phosphors. The red phosphor composition in the combination is a vanadate combined with yttrium, gadolinium and/or lanthanum and activated with trivalent Eu3+, Sm3+ and Pr330 , or any combination thereof, with or without Tb3+ as a co-dopant, has the general formula: BixLn1-xVO4:A where x=0 to 1, Ln is an element selected from the group consisting of Y, La and Gd, and A is an activator selected from Eu3+, Sm3+ and Pr3+, or any combination thereof, with or without Tb3+ as a co-dopant. Novel red phosphor compositions are provided when x is greater than 0 and less than 1, preferably 0.05 to 0.5.

    摘要翻译： 一种红色磷光体组合物，与发光在明亮的紫 - 蓝光范围的半导体发光器件（例如，VCSEL，LED或LD）（优选GaN基器件）结合，即具有波长在 400nm至600nm，其可以进一步与绿色和蓝色荧光体组合。 组合中的红色荧光体组合物是与钇，钆和/或镧结合的钒酸盐，并用三价Eu 3+，Sm 3+和Pr 3 或其任何组合，具有或不具有作为共掺杂剂的Tb 3+，具有以下通式：Bi×x 其中x = 0至1，Ln是选自Y，La和Gd的元素，A是一个 选自Eu 3+，Sm 3+和Pr 3+的活化剂或其任何组合，具有或不具有Tb 3+ 作为共掺杂剂。 当x大于0且小于1，优选为0.05至0.5时，提供新的红色荧光粉组合物。

    Metal-incorporated nanoporous nickel phosphate molecular sieve and its preparation method
    3.
    发明授权
    Metal-incorporated nanoporous nickel phosphate molecular sieve and its preparation method 有权
    金属纳米多孔磷酸镍分子筛及其制备方法

    公开(公告)号：US07235508B2

    公开(公告)日：2007-06-26

    申请号：US10916512

    申请日：2004-08-12

    申请人： Sung Hwa Jhung ,  Jong-San Chang ,  Sang-Eon Park ,  Anthony K. Cheetham

    发明人： Sung Hwa Jhung ,  Jong-San Chang ,  Sang-Eon Park ,  Anthony K. Cheetham

    IPC分类号： B01J29/04 ,  B01J29/82

    CPC分类号： C01B37/002 ,  B01J20/186 ,  B01J20/3078 ,  B01J29/82 ,  C01B3/001 ,  Y02E60/327 ,  Y02E60/328

    摘要： The present invention relates to a composition of metal-incorporated VSB-5 molecular sieve with nanopores and its preparation method, in particular, to a composition of a metal-incorporated VSB-5 molecular sieve with a framework of VSB-5 molecular sieve comprising nickel, phosphorous, oxygen and metal, which is useful in various fields such as a hydrogen storage material, an optical and electric/electronic material, a sensor, a catalyst, a catalyst supporter and an adsorbent, and its preparation method performed in such a manner that a specific metal component is added in a predetermined mole ratio to a reaction mixture comprised of nickel and phosphorous compounds and the resultant mixture is crystallized in the presence of inorganic or organic base as a pH modifier to yield a metal-incorporated VSB-5 molecular sieves in an economical and efficient manner.

    摘要翻译： 本发明涉及具有纳米孔的掺入金属的VSB-5分子筛的组合物及其制备方法，特别涉及具有包含镍的VSB-5分子筛骨架的金属掺入的VSB-5分子筛的组合物 ，磷，氧和金属，其可用于各种领域，例如储氢材料，光学和电气/电子材料，传感器，催化剂，催化剂载体和吸附剂，及其制备方法 将特定的金属组分以与镍和磷化合物组成的反应混合物以预定的摩尔比加入，所得混合物在无机或有机碱的存在下作为pH调节剂结晶，得到金属掺入的VSB-5分子 以经济高效的方式筛选。

    Red phosphors for solid state lighting
    4.
    发明授权
    Red phosphors for solid state lighting 有权
    红色荧光粉用于固态照明

    公开(公告)号：US07077979B2

    公开(公告)日：2006-07-18

    申请号：US10683899

    申请日：2003-10-10

    申请人： Anthony K. Cheetham ,  Neeraj Sharma

    发明人： Anthony K. Cheetham ,  Neeraj Sharma

    IPC分类号： C09K11/69

    CPC分类号： C09K11/7736 ,  C09K11/7794 ,  H01L33/502

    摘要： A red phosphor composition in combination with a semiconductor light emitting device (e.g., VCSEL, LED, or LD), preferably a GaN based device, that emits light at a bright violet-blue light range, i.e., having a wavelength in the range of 400 nm to 600 nm, which can be further combined with green and blue phosphors. The red phosphor composition in the combination is a vanadate combined with yttrium, gadolinium and/or lanthanum and activated with trivalent Eu3+, Sm3+ and Pr3+, or any combination thereof, with or without Tb3+ as a co-dopant, has the general formula: BixLn1−xVO4:A where x=0 to 1, Ln is an element selected from the group consisting of Y, La and Gd, and A is an activator selected from Eu3+, Sm3+ and Pr3+, or any combination thereof, with or without Tb3+ as a co-dopant. Novel red phosphor compositions are provided when x is greater than 0 and less than 1, preferably 0.05 to 0.5.

    摘要翻译： 一种红色磷光体组合物，与发光在明亮的紫 - 蓝光范围的半导体发光器件（例如，VCSEL，LED或LD）（优选GaN基器件）结合，即具有波长在 400nm至600nm，其可以进一步与绿色和蓝色荧光体组合。 组合中的红色荧光体组合物是与钇，钆和/或镧结合的钒酸盐，并用三价Eu 3+，Sm 3+和Pr 3 + /或其任何组合，具有或不具有作为共掺杂剂的Tb 3+，具有以下通式：Bi x L 1 N 1 - 其中x = 0至1，Ln是选自Y，La和Gd的元素，A是选自Eu， 3 +，+ 3 +和/或+ 3+，或其任何组合，具有或不具有Tb 3+ 多糖 当x大于0且小于1，优选为0.05至0.5时，提供新的红色荧光粉组合物。