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公开(公告)号：US6121361A
公开(公告)日：2000-09-19
申请号：US225998
申请日：1999-01-07
申请人： Arimitsu Usuki , Makoto Kato , Akane Okada
发明人： Arimitsu Usuki , Makoto Kato , Akane Okada
摘要： A composite clay material with the interlayer distance sufficiently expanded by dispersing clay mineral in a low polar polymer on a molecular level and the method for producing the same, blend material and composite clay rubber material using the same and the production method thereof.The composite clay material is formed of a clay mineral rendered compatible with an organic material through ionic bonding to an organic onium ion having 6 or more carbon number and a main guest molecule having a polar group in its main chain and side chain and molecular length equal to or larger than that of said organic onium ion. The main guest molecule is incorporated at least partially into an interlayer section of the clay mineral which has a hydrogen bonding with the polar group of the main guest molecule. The main guest molecule preferably has a molecular weight ranging from about 100 to 100000. Alternatively a first guest molecule having a polar group and molecular length equal to or smaller than that of the organic onium ion and a second guest molecule having no polar group therein and molecular length larger than that of the organic onium ion are incorporated into the interlayer section of the clay mineral instead of the main guest molecule. The above obtained clay composite material may be mixed with the rubber material.
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公开(公告)号：US5936023A
公开(公告)日：1999-08-10
申请号：US921575
申请日：1997-09-02
申请人： Makoto Kato , Azusa Tsukigase , Arimitsu Usuki , Akane Okada , Masayoshi Ichikawa , Katsumasa Takeuchi , Kazuya Watanabe , Yasushi Miyamoto
发明人： Makoto Kato , Azusa Tsukigase , Arimitsu Usuki , Akane Okada , Masayoshi Ichikawa , Katsumasa Takeuchi , Kazuya Watanabe , Yasushi Miyamoto
CPC分类号： C08K3/346
摘要： The present invention provides a method of manufacturing a composite material made of a rubber and a clay mineral dispersed uniformly therein. The method proceeds exchanging inorganic ions of the clay mineral with organic onium ions to organize the clay mineral; mixing the organized clay mineral and a process oil and/or a plasticizer; and mixing the rubber material with the mixture of the organized clay mineral and the process oil and/or the plasticizer. Process oil and/or plasticizer are intercalated into the organized clay mineral. As a result, the interlayer distance of the clay mineral is enlarged. The most favorable mode of the present invention is for a barrier material against water, gas and the like and for a rubber material required for an improved mechanical property.
摘要翻译： 本发明提供一种制造由其中均匀分散的橡胶和粘土矿物制成的复合材料的方法。 该方法用有机鎓离子交换粘土矿物的无机离子，组织粘土矿物; 混合有机粘土矿物和加工油和/或增塑剂; 并将橡胶材料与有机粘土矿物和加工油和/或增塑剂的混合物混合。 加工油和/或增塑剂插入有机粘土矿物中。 结果，粘土矿物的层间距离扩大。 本发明最有利的方式是针对水，气体等的阻隔材料和用于改善机械性能所需的橡胶材料。
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3.发明授权Composite clay material and method for producing the same, blend material and composite clay rubber using the same and production method thereof 失效复合粘土材料及其制造方法，混合材料和使用该复合粘土橡胶的复合粘土橡胶及其制造方法
公开(公告)号：US6103817A
公开(公告)日：2000-08-15
申请号：US225999
申请日：1999-01-07
申请人： Arimitsu Usuki , Makoto Kato , Akane Okada
发明人： Arimitsu Usuki , Makoto Kato , Akane Okada
摘要： A composite clay material with the interlayer distance sufficiently expanded by dispersing clay mineral in a low polar polymer on a molecular level and the method for producing the same, blend material and composite clay rubber material using the same and the production method thereof. The composite clay material is formed of a clay mineral rendered compatible with an organic material through ionic bonding to an organic onium ion having 6 or more carbon number and a main guest molecule having a polar group in its main chain and side chain and molecular length equal to or larger than that of said organic onium ion. The main guest molecule is incorporated at least partially into an interlayer section of the clay mineral which has a hydrogen bonding with the polar group of the main guest molecule. The main guest molecule preferably has a molecular weight ranging from about 100 to 100000. Alternatively a first guest molecule having a polar group and molecular length equal to or smaller than that of the organic onium ion and a second guest molecule having no polar group therein and molecular length larger than that of the organic onium ion are incorporated into the interlayer section of the clay mineral instead of the main guest molecule. The above obtained clay composite material may be mixed with the rubber material.
摘要翻译： 通过在分子水平上将粘土矿物分散在低极性聚合物中的层间距离充分膨胀的复合粘土材料及其制造方法，使用其的混合材料和复合粘土橡胶材料及其制造方法。 复合粘土材料由与有机材料相容的粘土矿物形成，通过离子键合至具有6个或更多个碳数的有机鎓离子，并且主链和侧链具有极性基团的主客体分子和分子长度相等 达到或大于所述有机鎓离子的浓度。 主客体分子至少部分地并入与主客体分子的极性基团具有氢键的粘土矿物的中间层部分中。 主客体分子优选具有约100〜100000的分子量。或者，具有极性基团和分子长度等于或小于有机鎓离子的分子量的第一客体分子和不具有极性基团的第二客体分子， 大于有机鎓离子的分子长度被掺入粘土矿物的中间部分而不是主客体分子。 将上述得到的粘土复合材料与橡胶材料混合。
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公开(公告)号：US5973053A
公开(公告)日：1999-10-26
申请号：US656864
申请日：1996-05-30
申请人： Arimitsu Usuki , Makoto Kato , Akane Okada
发明人： Arimitsu Usuki , Makoto Kato , Akane Okada
摘要： A composite clay material with the interlayer distance sufficiently expanded by dispersing clay mineral in a low polar polymer on a molecular level and the method for producing the same, blend material and composite clay rubber material using the same and the production method thereof.The composite clay material is formed of a clay mineral rendered compatible with an organic material through ionic bonding to an organic onium ion having 6 or more carbon number and a main guest molecule having a polar group in its main chain and side chain and molecular length equal to or larger than that of said organic onium ion. The main guest molecule is incorporated at least partially into an interlayer section of the clay mineral which has a hydrogen bonding with the polar group of the main guest molecule. The main guest molecule preferably has a molecular weight ranging from about 100 to 100000. Alternatively a first guest molecule having a polar group and molecular length equal to or smaller than that of the organic onium ion and a second guest molecule having no polar group therein and molecular length larger than that of the organic onium ion are incorporated into the interlayer section of the clay mineral instead of the main guest molecule. The above obtained clay composite material may be mixed with the rubber material.
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5.发明授权Liquid crystal composition, liquid crystal device using the same, light controlling element, recording medium, and light shutter 失效液晶组合物，使用其的液晶装置，光控元件，记录介质和光快门
公开(公告)号：US5645758A
公开(公告)日：1997-07-08
申请号：US421407
申请日：1995-04-13
申请人： Masaya Kawasumi , Hisato Takeuchi , Arimitsu Usuki , Akane Okada
发明人： Masaya Kawasumi , Hisato Takeuchi , Arimitsu Usuki , Akane Okada
CPC分类号： G02F1/132 , C09K19/52 , G02F1/137 , G02F1/13725 , Y10T428/1041
摘要： A liquid crystal composition comprising a liquid crystal and a second substance dispersed therein, the second substance having affinity for the liquid crystal and being composed of particles having a particle size and an aspect ratio of a predetermined value or greater, and a liquid crystal composition comprising a liquid crystal containing electric field sensitive liquid crystal molecules having a positive dielectric anisotropy as the principal component and flat plate-shaped particles having affinity for the liquid crystal being dispersed therein at such a degree of density suitable for effectively forming liquid crystal domains. Also described are a liquid crystal device using the same, a light-controlling element, a recording medium, and a light shutter.
摘要翻译： 一种液晶组合物，其包含分散在其中的液晶和第二物质，所述第二物质对液晶具有亲和性，并且由具有预定值或更大的粒径和纵横比的颗粒组成，并且包含 以具有正介电各向异性为主要成分的电场敏感液晶分子的液晶和对液晶具有亲和性的平板状颗粒以适合于有效形成液晶畴的密度的方式分散在其中。 还描述了使用它的液晶装置，光控制元件，记录介质和光闸。
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公开(公告)号：US5164460A
公开(公告)日：1992-11-17
申请号：US707905
申请日：1991-05-30
申请人： Kazuhisa Yano , Arimitsu Usuki , Akane Okada , Toshio Kurauchi
发明人： Kazuhisa Yano , Arimitsu Usuki , Akane Okada , Toshio Kurauchi
CPC分类号： C08K9/04 , H05K1/0346 , H05K1/0373
摘要： Disclosed herein is a polyimide composite material which comprises a polyimide-containing resin and a layered clay mineral which is intercalated with organic onium ions and dispersed in the polyimide. Owing to the intercalated clay mineral, the composite material has improved gas and water vapor barrier properties and a small thermal expansion coefficient. Disclosed also herein is a process for producing a polyimide composite material which comprises the steps of intercalating a layered clay mineral with organic onium ions, adding by mixing the intercalated clay mineral to a solution of a monomer or prepolymer for polyimide, removing the solvent, and forming a polyimide. This process makes the layered clay mineral miscible with and dispersible in polyimide.
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公开(公告)号：US6117932A
公开(公告)日：2000-09-12
申请号：US154723
申请日：1998-09-17
CPC分类号： C08J5/005 , B82Y30/00 , C08K3/346 , C08K9/04 , C08L23/02 , C08J2323/12 , C08L23/06 , C08L23/0869 , C08L23/10 , C08L23/16 , C08L51/06
摘要： The resin composite of this invention comprises an organophilic clay and a polymer. The polymer is formed of two or more polymers at least one of which has a functional group, or the polymer is formed of a copolymer having a functional group. This structure provides the resin composite which can be easily made composite with a wide range of applications, and imparts the optimum physical properties to the composite.
摘要翻译： 本发明的树脂复合材料包括亲有机粘土和聚合物。 聚合物由两种或更多种聚合物形成，其中至少一种具有官能团，或者聚合物由具有官能团的共聚物形成。 这种结构提供了可以容易地制备具有广泛应用的复合材料的树脂复合材料，并赋予复合材料最佳的物理性能。
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8.发明授权
公开(公告)号：US5346984A
公开(公告)日：1994-09-13
申请号：US46837
申请日：1993-04-14
申请人： Naoki Hasegawa , Arimitsu Usuki , Akane Okada , Toshio Kurauchi
发明人： Naoki Hasegawa , Arimitsu Usuki , Akane Okada , Toshio Kurauchi
IPC分类号： C08G69/14 , C07C63/331 , C08G69/02 , C08G69/04 , C08G69/20 , C08G69/26 , C08G69/48 , C08G69/08
CPC分类号： C08G69/02 , C07C63/331 , C08G69/26 , C08G69/48
摘要： Star-shaped nylons with low melt viscosities and excellent mechanical properties, methods for their preparation, a novel tetrasubstituted carboxylic acid for use as a polymerization core therefor and methods for its preparation are provided.A star-shaped nylon has polymer chains emanating from 3 or more polymerization initiation groups which are substituents bonded to every other or more separated carbon atoms on an aromatic ring of an aromatic compound. The star-shaped nylon is produced by homogeneously mixing the aromatic compound with molten nylon monomer and polymerizing the nylon monomer with the respective polymerization initiation groups as the starting points. A novel tetrasubstituted carboxylic acid having a structure of 3,5,3',5'-biphenyltetracarboxylic acid is useful as a polymerization core for star-shaped nylons.
摘要翻译： 提供具有低熔体粘度和优异机械性能的星形尼龙，其制备方法，用作其聚合核心的新型四取代羧酸及其制备方法。 星形尼龙具有从3个或更多个聚合引发基团发出的聚合物链，其是与芳族化合物的芳香环上的每隔一个或更多分离的碳原子键合的取代基。 星形尼龙通过将芳族化合物与熔融尼龙单体均匀混合并将尼龙单体与各自的聚合引发基团聚合起始点而制备。 具有3,5,3'，5'-联苯四羧酸结构的新型四取代羧酸可用作星形尼龙的聚合核。
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公开(公告)号：US4739007A
公开(公告)日：1988-04-19
申请号：US909472
申请日：1986-09-19
申请人： Akane Okada , Yoshiaki Fukushima , Masaya Kawasumi , Shinji Inagaki , Arimitsu Usuki , Shigetoshi Sugiyama , Toshio Kurauchi , Osami Kamigaito
发明人： Akane Okada , Yoshiaki Fukushima , Masaya Kawasumi , Shinji Inagaki , Arimitsu Usuki , Shigetoshi Sugiyama , Toshio Kurauchi , Osami Kamigaito
CPC分类号： B82Y30/00 , C08J5/005 , C08K3/346 , C08L77/02 , C08J2377/00
摘要： Composite material with high mechanical strength and excellent high-temperature characteristics comprising a polymer matrix containing polyamide and layers of a silicate uniformly dispersed in the order of molecules in the polymer matrix, each of said silicate layers being 7 to 12 .ANG. thick and the interlayer distance being at least 20 .ANG.; and a process for manufacturing such composite material.
摘要翻译： 具有高机械强度和优异的高温特性的复合材料包括含有聚酰胺的聚合物基体和分层的均匀分散的硅酸盐层，每个硅酸盐层的厚度为7至12，层间距离 至少有20个ANGSTROM; 以及这种复合材料的制造方法。
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公开(公告)号：US5766508A
公开(公告)日：1998-06-16
申请号：US593888
申请日：1996-01-30
申请人： Masaya Kawasumi , Naoki Hasegawa , Arimitsu Usuki , Akane Okada , Masaaki Tani , Yoshiaki Fukushima
发明人： Masaya Kawasumi , Naoki Hasegawa , Arimitsu Usuki , Akane Okada , Masaaki Tani , Yoshiaki Fukushima
IPC分类号： G02F1/13 , C09K19/02 , C09K19/20 , C09K19/30 , C09K19/52 , C09K19/54 , C09K19/60 , G02F1/137
CPC分类号： G02F1/1375 , C09K19/52 , Y10T428/1059
摘要： This invention provides liquid crystal compositions for light controlling materials of light scattering type having both memory and high speed response characteristics. The composition neither needs a temperature controlling device nor a device for imparting a shear stress as a memory erasing device, because the composition comprises a two-frequency addressing liquid crystal or such liquid crystal with an ionic component. The two-frequency addressing liquid crystal responds to an electric field and exhibits a positive dielectric anisotropy or a negative dielectric anisotropy depending on the frequency region of the electric field. Because the flat shaped particles of the present invention exhibit an affinity with the liquid crystal, the particles are dispersed in the liquid crystal and form liquid crystal domains effectively.
摘要翻译： 本发明提供了具有记忆和高速响应特性的光散射型光控材料的液晶组合物。 该组合物既不需要温度控制装置也不需要赋予剪切应力的装置作为存储器擦除装置，因为该组合物包括双频寻址液晶或这种具有离子成分的液晶。 双频寻址液晶响应于电场，并且根据电场的频率区域呈现正的介电各向异性或负的介电各向异性。 由于本发明的扁平状颗粒与液晶呈亲和性，所以将颗粒分散在液晶中并有效地形成液晶畴。
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