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公开(公告)号：US4524232A
公开(公告)日：1985-06-18
申请号：US568015
申请日：1984-01-04
IPC分类号： C10G57/02 , B01J29/00 , B01J29/40 , C10G50/02 , C10G69/12 , C10M105/04 , C10N20/02 , C07C2/02
CPC分类号： C10G69/126 , C10G50/02
摘要： A combination process for producing high viscosity index lubes from light olefins is provided wherein light olefins are first passed over a small pore zeolite and the liquid product therefrom is then processed over an intermediate pore zeolite to provide a lubricating oil with a higher viscosity, high Viscosity Index and low pour point in greater yield than obtained with either of the catalysts alone.
摘要翻译： 提供了用于从轻质烯烃生产高粘度指数的润滑剂的组合方法，其中轻质烯烃首先通过小孔沸石，然后将其中的液体产物在中间孔沸石上加工以提供具有较高粘度，高粘度的润滑油 指数和低倾点比单独使用任一种催化剂获得的产率更高。
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2.发明授权
公开(公告)号：US4618737A
公开(公告)日：1986-10-21
申请号：US808705
申请日：1985-12-13
CPC分类号： C07C2/26 , C07C11/02 , C07C2/12 , C10G50/02 , C07C2529/06 , C07C2529/40 , C07C2531/02
摘要： High viscosity lubricants are formed by oligomerizing olefins in two stages. The first stage converts a lower olefin feed to distillate range hydrocarbons in the presence of an aluminosilicate zeolite such as ZSM-5. The distillate effluent from the first stage is further polymerized to lubricant range hydrocarbons at elevated temperatures in the presence of a ditertiary alkylperoxide catalyst.
摘要翻译： 高粘度润滑剂通过两个阶段的烯烃低聚而形成。 第一阶段在铝硅酸盐沸石如ZSM-5存在下将低级烯烃进料转化为馏出物范围的烃。 在二级烷基过氧化物催化剂的存在下，来自第一阶段的馏出物流出物在高温下进一步聚合成润滑剂烃。
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3.发明授权Alumina removal from crystalline alumino-silicates with Cr(III) solutions 失效用CR（III）溶液从结晶铝 - 硅酸盐中除去氧化铝
公开(公告)号：US3937791A
公开(公告)日：1976-02-10
申请号：US389109
申请日：1973-08-17
CPC分类号： B01J20/186 , C07C5/333 , B01J2229/16 , Y02P20/52 , Y10S423/21 , Y10S423/25 , Y10S423/26
摘要： A method of removing alumina from a crystalline aluminosilicate composition having a silica/alumina mole ratio of from above 3 to about 12 which comprises heating said aluminosilicate composition to a temperature of greater than 50.degree.C. to about 100.degree.C. in the presence of a cationic form of chromium, preferably Cr.sup.+.sup.3, in aqueous solution of above 0.01 Normal of a chromium salt of a mineral acid whereby the pH is less than 3.5, and such that the atomic ratio of chromium to aluminum is greater than 0.5 for a time sufficient to remove the alumina. The method of this invention permits the aluminosilicate composition to retain substantial crystallinity. Organic compound conversion with the dealuminized material formed by the method of this invention may be advantageously utilized.
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4.发明授权Multistage system for conversion of lower olefins with reactor quenching means 失效用反应器淬火方法转化低级烯烃的多级体系
公开(公告)号：US4942021A
公开(公告)日：1990-07-17
申请号：US137224
申请日：1987-12-23
摘要： A continuous multistage catalytic conversion system for upgrading lower olefins comprisingfirst adaibatic catalytic bed reactor means containing an acidic zeolite solid catalyst;means for feeding light olefinic gas directly to the first reactor without addition of separate diluent or recycle streams;means for operating the first reactor under olefin partial conversion conditions at elevated temperature to control adiabatic temperature increase;interstage quench means for injecting a liquid coolant directly into first stage effluent for reducing the temperature thereof and protecting downstream catalyst;second catalytic bed reactor means for receiving cooled first stage effluent with injected liquid coolant and further converting the olefins over a metallic zeolite catalyst having a metal ethene oligomerization component;means for cooling and recovering heavier liquid hydrocarbon product from the second reactor effluent; andmeans for recovering liquid coolant from the second effluent for recycle to the interstage quench means.
摘要翻译： 一种用于升级低级烯烃的连续多级催化转化系统，包括含有酸性沸石固体催化剂的第一辅助催化床反应器装置; 用于将轻质烯属气体直接供给到第一反应器而不加入单独的稀释剂或再循环流的装置; 用于在高温下在烯烃部分转化条件下操作第一反应器的装置，以控制绝热温度升高; 级间骤冷装置，用于将液体冷却剂直接注入第一级流出物中以降低其温度并保护下游催化剂; 第二催化床反应器装置，用于接收具有注入的液体冷却剂的冷却的第一级流出物，并进一步转化具有金属乙烯低聚组分的金属沸石催化剂的烯烃; 用于从第二反应器流出物冷却和回收较重液体烃产物的装置; 以及用于从第二流出物回收液体冷却剂以再循环到级间骤冷装置的装置。
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公开(公告)号：US4740645A
公开(公告)日：1988-04-26
申请号：US903915
申请日：1986-09-05
CPC分类号： C10G50/00 , C07C11/02 , C07C2/12 , C07C2529/46 , Y02P20/52
摘要： A continuous multi-stage catalytic process for converting ethene-rich lower olefinic feedstock to heavier liquid hydrocarbon product, comprising the steps ofcontacting ethene-rich feedstock at elevated temperature and moderate pressure in a primary stage reaction zone with a first catalyst comprising shape selective medium pore zeolite to convert at least a portion of the lower olefinic components to intermediate olefinic hydrocarbons;cooling primary stage reaction effluent by introducing a stream of cold water sufficient to reduce the primary stage effluent to second stage reaction temperature; andcontacting unreacted ethene and at least a portion of the intermediate olefinic hydrocarbons from the primary stage with nickel-containing shape selective medium pore zeolite oligomerization component at elevated temperature to provide a heavier hydrocarbon effluent stream comprising gasoline and/or distillate range hydrocarbons.
摘要翻译： 一种用于将含富烯烃的较低级烯烃原料转化为较重液体烃产物的连续多级催化方法，包括以下步骤：在初级阶段反应区中将升温和中等压力的富含烯烃的原料与包含形状选择介质 孔沸石将至少一部分低级烯烃组分转化成中间体烯烃; 通过引入足以将初级阶段流出物降至第二阶段反应温度的冷水流来冷却初级反应流出物; 并在升高的温度下使未反应的乙烯和至少一部分来自初级阶段的中间体烯烃与含镍形状选择性中孔沸石低聚组分接触，以提供包含汽油和/或馏出物范围烃的较重烃流出物流。
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公开(公告)号：US4684756A
公开(公告)日：1987-08-04
申请号：US858620
申请日：1986-05-01
申请人： W. Rodman Derr, Jr. , William E. Garwood , James C. Kuo , Tiberiu M. Leib , Donald M. Nace , Samuel A. Tabak
发明人： W. Rodman Derr, Jr. , William E. Garwood , James C. Kuo , Tiberiu M. Leib , Donald M. Nace , Samuel A. Tabak
CPC分类号： C10L1/06 , C07C1/0485 , C10G2/32 , C10L1/04 , C10G2300/1022
摘要： The waxy liquid phase of an oil suspension of Fischer-Tropsch catalyst containing dissolved wax is separated out and the wax is converted by hydrocracking, dewaxing or by catalytic cracking with a low activity catalyst to provide a highly olefinic product which may be further converted to premium quality gasoline and/or distillate fuel.
摘要翻译： 分离含有溶解蜡的费 - 托催化剂的油悬浮液的蜡状液相，通过加氢裂化，脱蜡或用低活性催化剂进行催化裂化来转化蜡，以提供可进一步转化为优质的高烯烃产物 优质汽油和/或馏出燃料。
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公开(公告)号：US4717782A
公开(公告)日：1988-01-05
申请号：US893522
申请日：1986-08-05
CPC分类号： C07C2/12 , C07C2529/46 , Y02P20/52
摘要： A continuous catalytic process for converting ethene-rich olefinic feedstock containing reducing gas to heavier liquid hydrocarbon product, comprising the steps ofcontacting the ethene-rich feedstock at elevated temperature in a catalytic reaction zone with a zeolite catalyst comprising a nickel-ethene oligomerization component and a shape-selective medium pore acid zeolite oligomerization component to convert at least a portion of the lower olefinic components to heavier olefinic hydrocarbons; andfeeding water with the feedstock in sufficient amount to prevent substantial reduction of the nickel component.
摘要翻译： 一种用于将含有还原气体的富含烯烃的烯烃原料转化为较重液体烃产物的连续催化方法，包括以下步骤：使催化反应区中升温的富含乙烯的原料与包含镍 - 乙烯低聚组分的沸石催化剂和 形状选择性中孔酸性沸石低聚组分，将至少一部分较低级烯烃组分转化成较重的烯烃; 并用足够量的原料给予原料以防止镍组分的显着减少。
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公开(公告)号：US5243112A
公开(公告)日：1993-09-07
申请号：US776247
申请日：1985-09-16
IPC分类号： C07C2/12
CPC分类号： C07C2/12 , C07C2529/70
摘要： Lower olefins are upgraded to high viscosity index lubricants by converting olefinic feed over a medium pore zeolite catalyst consisting essentially of aluminosilicate HzSM-22 under oligomerization conditions.
摘要翻译： 通过在低聚条件下通过基本上由铝硅酸盐HzSM-22组成的中孔沸石催化剂转化烯烃进料，将低级烯烃升级为高粘度指数润滑剂。
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公开(公告)号：US4414097A
公开(公告)日：1983-11-08
申请号：US369852
申请日：1982-04-19
IPC分类号： B01J29/00 , B01J29/65 , B01J29/70 , B01J29/74 , C10G45/64 , C10G65/12 , C10G67/04 , C10G49/08 , C10G47/16
CPC分类号： B01J29/74 , B01J29/70 , B01J2229/26 , B01J2229/42 , C10G2400/10
摘要： This invention relates to an energy-efficient process for dewaxing hydrocrackate and manufacturing a stabilized and dewaxed hydrocracked lubricating oil stock from hydrocarbon feedstock boiling above about 343.degree. C.
摘要翻译： 本发明涉及一种用于脱氢加氢裂化剂的能量有效的方法，并从沸点高于约343℃的烃原料制备稳定和脱蜡的加氢裂化润滑油原料。
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公开(公告)号：US4810357A
公开(公告)日：1989-03-07
申请号：US171209
申请日：1988-03-16
IPC分类号： C10G65/10 , B01J29/00 , B01J29/40 , B01J29/65 , C10G45/64 , C10G65/00 , C10G65/16 , C10G73/02 , C10G65/14
摘要： Relatively heavy or relatively light lube chargestocks are dewaxed in two parallel, separate reactors. The reactor used for dewaxing the relatively light chargestocks contains a crystalline aluminosilicate zeolite exemplified natural or synthetic ferrierite, ZSM-22, ZSM-23 and ZSM-35 zeolites and/or mixtures thereof. The reactor used for dewaxing the relatively heavy chargestocks contains a crystalline aluminosilicate zeolite exemplified by ZSM-5, ZSM-11 zeolites, ZSM-5/ZSM-11 intermediates and/or mixtures thereof.
摘要翻译： 相对较重或较轻的润滑油装置在两个平行的单独反应器中脱蜡。 用于脱蜡相对轻的原料的反应器含有结晶的硅铝酸盐沸石，例如天然或合成镁碱沸石，ZSM-22，ZSM-23和ZSM-35沸石和/或其混合物。 用于脱蜡相对重的原料的反应器含有由ZSM-5，ZSM-11沸石，ZSM-5 / ZSM-11中间体和/或其混合物示例的结晶硅铝酸盐沸石。
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