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    Separation and recovery of unsaturated hydrocarbons by copper (I) complexes
    2.
    发明授权
    Separation and recovery of unsaturated hydrocarbons by copper (I) complexes 失效
    铜（I）配合物分离和回收不饱和烃

    公开(公告)号：US4434317A

    公开(公告)日：1984-02-28

    申请号：US492225

    申请日：1983-05-06

    申请人： Gerald Doyle ,  Roy L. Pruett ,  David W. Savage

    发明人： Gerald Doyle ,  Roy L. Pruett ,  David W. Savage

    IPC分类号： C07C7/152 ,  C07C7/156

    CPC分类号： C07C7/152

    摘要： Alkenes, alkynes or mixtures thereof are removed from feedstreams by a process which comprises contacting the feedstream with a solution of a cuprous fluorinated acetylacetone in an organic solvent containing stabilizing agent to remove alkene, alkyne or mixture thereof by forming a first cuprous complex, decomposing the first cuprous complex whereby stabilizing agent replaces alkene or alkyne in the first cuprous complex to form a second cuprous complex, and separating the displaced component. The formation of the second cuprous complex avoids any deposition of copper metal upon heating.

    摘要翻译： 烯烃，炔烃或其混合物通过一种方法从进料流中除去，该方法包括使进料流与含氟的含氟乙酰丙酮的有机溶剂中的溶液接触，以除去烯烃，炔烃或其混合物，形成第一个亚铜络合物，分解 第一亚铜络合物，由此稳定剂代替第一亚铜络合物中的烯烃或炔烃以形成第二亚铜络合物，并分离置换的组分。 第二种亚铜络合物的形成避免了加热时铜金属的任何沉积。

    Process for separating unsaturated hydrocarbons using copper or silver complexes with fluorinated diketonates
    3.
    发明授权
    Process for separating unsaturated hydrocarbons using copper or silver complexes with fluorinated diketonates 失效
    使用铜或银络合物与氟化二酮分离不饱和烃的方法

    公开(公告)号：US4385005A

    公开(公告)日：1983-05-24

    申请号：US282653

    申请日：1981-07-13

    申请人： Gerald Doyle

    发明人： Gerald Doyle

    IPC分类号： C07C7/152 ,  C07C11/00 ,  C07D333/22 ,  C07F1/00 ,  C07F1/08 ,  C07C119/02 ,  C07C7/12 ,  C07C121/46

    CPC分类号： C07C251/00 ,  C07C7/152 ,  C07D333/22 ,  C07F1/005 ,  C07F1/08

    摘要： A process of removing unsaturated hydrocarbons containing at least one non-aromatic unsaturation from feedstreams which comprises contacting the feedstream with at least one of Cu.sub.2 O or Ag.sub.2 O and a fluorinated acetylacetonate of the formula ##STR1## where R.sup.1 is C.sub.1 -C.sub.6 fluoroalkyl, C.sub.1 -C.sub.8 alkyl, C.sub.4 -C.sub.6 heterocycle containing O, S or N or C.sub.6 -C.sub.10 aryl, R.sup.2 is H or C.sub.1 -C.sub.6 alkyl with the proviso that R.sup.1 and R.sup.2 together with the carbons to which they are attached may be joined together to form a C.sub.6 ring and n is from 1 to 8, in an inert organic solvent.

    摘要翻译： 从进料流中除去含有至少一种非芳族不饱和度的不饱和烃的方法，该方法包括使进料流与Cu 2 O或Ag 2 O中的至少一种和式（VI）的氟化乙酰丙酮化物反应，其中R 1是C 1 -C 6氟烷基，C 1 -C 8 烷基，含有O，S或N或C 6 -C 10芳基的C 4 -C 6杂环，R 2是H或C 1 -C 6烷基，条件是R 1和R 2与它们连接的碳一起可以连接在一起形成C6 环，n为1至8，在惰性有机溶剂中。

    Cu(1) Acetylacetonate complexes for CO separation
    4.
    发明授权
    Cu(1) Acetylacetonate complexes for CO separation 失效
    Cu（1）用于CO分离的乙酰丙酮络合物

    公开(公告)号：US4279874A

    公开(公告)日：1981-07-21

    申请号：US141055

    申请日：1980-04-17

    申请人： Gerald Doyle

    发明人： Gerald Doyle

    IPC分类号： B01D53/14 ,  B01D53/62 ,  B01J20/22 ,  B01D53/34

    CPC分类号： B01D53/1493 ,  B01D53/62

    摘要： Carbon monoxide is selectively removed from a gas stream by a process which comprises contacting the gas stream with an absorbent solution containing the reaction product of a Cu(I) compound and a halogenated acetylacetone of the formula: ##STR1## where X is a halogen, R.sub.1 is CX.sub.3, linear or branched C.sub.1 to C.sub.8 alkyl, C.sub.4 to C.sub.6 heterocycle containing O, S or N or C.sub.6 to C.sub.10 aryl, R.sub.2 is hydrogen or C.sub.1 to C.sub.6 alkyl, or R.sub.1 and R.sub.2 are joined together to form a C.sub.6 ring.

    摘要翻译： 通过一种方法选择性地从气流中除去一氧化碳，该方法包括使气体流与含有下列化学式的Cu（I）化合物和卤代乙酰丙酮的反应产物的吸收剂溶液接触：其中X是卤素， R1是CX3，直链或支链C1至C8烷基，含O，S或N或C6至C10芳基的C4至C6杂环，R2为氢或C1至C6烷基，或R1和R2连接在一起形成C6环。

    Bimetallic carbonyl hydroformylation catalysts
    5.
    发明授权
    Bimetallic carbonyl hydroformylation catalysts 失效
    双金属羰基羰基化催化剂

    公开(公告)号：US4551543A

    公开(公告)日：1985-11-05

    申请号：US563971

    申请日：1983-12-21

    申请人： Gerald Doyle ,  Kenneth A. Eriksen ,  Roy L. Pruett

    发明人： Gerald Doyle ,  Kenneth A. Eriksen ,  Roy L. Pruett

    IPC分类号： C07C45/50 ,  C07F15/06 ,  C07F1/08 ,  C07F15/00

    CPC分类号： C07F15/065 ,  C07C45/50

    摘要： A hydroformylation catalyst of the formulaL.sub.a CuCo(CO).sub.b L'cwherein L is a monodentate phosphine, a bidentate phosphine or a bidentate amine, a is 1-3, b is 3 or 4, c is 0 or 1; provided that, where b=4, c=0 and L' is CO, phosphine or phosphite. Where the catalysts have the formulaL.sub.a CuCo(CO).sub.4the compounds are novel.

    摘要翻译： 式LaCuCo（CO）bL'c的加氢甲酰化催化剂，其中L是单齿膦，二齿膦或二齿胺，a为1-3，b为3或4，c为0或1; 条件是其中b = 4，c = 0，L'为CO，膦或亚磷酸酯。 当催化剂具有式LaCuCo（CO）4时，化合物是新颖的。

    Removal of CO and unsaturated hydrocarbons from gas streams using copper oxalate complexes
    6.
    发明授权
    Removal of CO and unsaturated hydrocarbons from gas streams using copper oxalate complexes 失效
    使用草酸铜复合物从气流中除去CO和不饱和烃

    公开(公告)号：US4347066A

    公开(公告)日：1982-08-31

    申请号：US282654

    申请日：1981-07-13

    申请人： Gerald Doyle

    发明人： Gerald Doyle

    IPC分类号： B01D53/14 ,  B01D53/62

    CPC分类号： B01D53/1493 ,  B01D53/14 ,  B01D53/1425 ,  B01D53/62

    摘要： A process for removing CO from a gas stream which comprises contacting the gas stream with a mixture of Cu.sub.2 O and oxalic acid in an inert organic solvent. The process selectively removes CO from the gas stream and forms a novel cuprous oxalate complex of the formula Cu.sub.2 (CO).sub.2 C.sub.2 O.sub.4. Cu.sub.2 (CO)C.sub.2 O.sub.4 can be further contacted with a feedstream containing unsaturated hydrocarbon L thereby displacing CO from the oxalate complex, removing L from the feedstream and forming a new complex Cu.sub.2 (CO).sub.n L.sub.m C.sub.2 O.sub.4 where n and m are numbers from 0 to 2.

    摘要翻译： 一种从气流中除去CO的方法，其包括使气流与Cu 2 O和草酸的混合物在惰性有机溶剂中接触。 该方法选择性地从气流中除去CO，并形成新颖的式Cu2（CO）2C2O4的草酸亚铁盐络合物。 Cu2（CO）C2O4可以进一步与含有不饱和烃L的原料流接触，从而从草酸盐络合物中取代CO，从原料流中除去L并形成新的络合物Cu2（CO）nLmC2O4，其中n和m为0至2的数字。

    Method for assessing disease states by profile analysis of isolated circulating endothelial cells
    8.
    发明申请
    Method for assessing disease states by profile analysis of isolated circulating endothelial cells 有权
    通过分离的循环内皮细胞的轮廓分析来评估疾病状态的方法

    公开(公告)号：US20070154960A1

    公开(公告)日：2007-07-05

    申请号：US11701763

    申请日：2007-02-02

    申请人： Mark Connelly ,  Gerald Doyle ,  Galla Rao ,  Leon Terstappen

    发明人： Mark Connelly ,  Gerald Doyle ,  Galla Rao ,  Leon Terstappen

    IPC分类号： G01N33/567

    CPC分类号： G01N33/6893 ,  G01N33/5091 ,  G01N2800/32 ,  Y10T436/101666 ,  Y10T436/107497 ,  Y10T436/108331 ,  Y10T436/2525 ,  Y10T436/25375

    摘要： Elevated number of Circulating Endothelial Cells (CEC) have been implicated in disease conditions associated with the formation or destruction of blood vessels such as acute coronary syndrome, thrombocytopenic purpura, sickle cell disease, sepsis, lupus, nephrotic syndromes, rejection of organ transplants, surgical trauma and cancer. This invention provides a method for assessing the levels of CEC which vary between different studies using a sensitive enrichment, imaging, and enumberation analysis. CD146 is one of the most specific endothelium-associated cell-surface antigens which can be used in image cytometry. CEC analysis provides an essential tool in prognostic/diagnostic evaluation in the clinic.

    摘要翻译： 循环内皮细胞数量增加已涉及与血管形成或破坏相关的疾病状况，如急性冠状动脉综合征，血小板减少性紫癜，镰状细胞病，败血症，狼疮，肾病综合征，器官移植排斥，外科手术 创伤和癌症。 本发明提供了一种用于评估使用敏感浓缩，成像和启发分析的不同研究之间变化的CEC水平的方法。 CD146是可用于图像细胞计数的最特异的内皮相关细胞表面抗原之一。 CEC分析为诊所的预后/诊断评估提供了重要的工具。

    Copper or silver complexes with fluorinated diketones and unsaturated ligands
    9.
    发明授权
    Copper or silver complexes with fluorinated diketones and unsaturated ligands 失效
    铜或银配合物与氟化二酮和不饱和配体

    公开(公告)号：US4425281A

    公开(公告)日：1984-01-10

    申请号：US282652

    申请日：1981-07-13

    申请人： Gerald Doyle

    发明人： Gerald Doyle

    IPC分类号： C07C49/92 ,  C07C1/00 ,  C07C7/152 ,  C07C45/00 ,  C07C67/00 ,  C07D333/22 ,  C07F1/00 ,  C07F1/08 ,  C07F1/10

    CPC分类号： C07C251/00 ,  C07C7/152 ,  C07D333/22 ,  C07F1/005 ,  C07F1/08

    摘要： A composition of matter of the formula ##STR1## where M is Cu(I) or Ag(I); R.sup.1 is C.sub.1 -C.sub.6 fluoroalkyl, C.sub.1 -C.sub.8 alkyl, C.sub.4 -C.sub.6 heterocycle containing O, S or N or C.sub.6 -C.sub.10 aryl; R.sup.2 is H or C.sub.1 -C.sub.6 alkyl, with the proviso that R.sup.1 and R.sup.2 together with the carbons to which they are attached may be joined together to form a C.sub.6 ring; L is an unsaturated hydrocarbon containing at least one non-aromatic unsaturation; x and y are 1 or 2; and n is from 1 to 8.

    摘要翻译： 其中M是Cu（I）或Ag（I）的式（I）的物质组成; R1是C1-C6氟烷基，C1-C8烷基，含有O，S或N或C6-C10芳基的C4-C6杂环; R2是H或C1-C6烷基，条件是R1和R2与它们所连接的碳一起可以连接在一起形成C6环; L是含有至少一个非芳族不饱和键的不饱和烃; x和y为1或2; n为1〜8。