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    Dithienophthalimide semiconductor polymers
    8.
    发明授权
    Dithienophthalimide semiconductor polymers 有权

    公开(公告)号：US09006725B2

    公开(公告)日：2015-04-14

    申请号：US14129772

    申请日：2012-07-04

    申请人： Hiroyoshi Noguchi ,  Florian Doetz ,  Ashok Kumar Mishra ,  Subramanian Vaidyanathan ,  Mai Minh-Tien

    发明人： Hiroyoshi Noguchi ,  Florian Doetz ,  Ashok Kumar Mishra ,  Subramanian Vaidyanathan ,  Mai Minh-Tien

    IPC分类号： H01L29/08 ,  H01L51/00 ,  C08G61/12 ,  H01L51/05

    CPC分类号： H01L51/0036 ,  C08G61/126 ,  C08G2261/124 ,  C08G2261/1412 ,  C08G2261/3223 ,  C08G2261/3327 ,  C08G2261/344 ,  C08G2261/364 ,  C08G2261/92 ,  H01L51/0043 ,  H01L51/0558 ,  Y02E10/549

    摘要： The invention concerns apolymer of the formula (I): wherein: M1 is an optionally substituted dithienophthalimide formula (II): wherein: X is N or C—R, wherein R is H or a C1-C40 alkyl group, R2, at each occurrence, is independently selected from H, a C1-40 alkyl group, a C2-40 alkenyl group, a C1-40 haloalkyl group, and a monocyclicor polycyclic moiety, wherein: each of the C1-40 alkyl group, the C2-40 alkenyl group, and the C1-40 haloalkyl group can be optionally substituted with 1-10 substituents independently selected from a halogen, CN, —NO2, OH, NH2, —NH(C1-20 alkyl), N(C1-20 alkyl)2, —S(O)2OH, —CHO, —C(O)—C1-20 alkyl, —C(O)OH, —C(O)—OC1-20 alkyl, —C(O)NH2, —C(O)NH—C1-20 alkyl, —C(O)N(C1-20 alkyl)2, —OC1-20 alkyl, —SiH3, —SiH(C1-20 alkyl)2, —SiH2(C1-20 alkyl), and —Si(C1-20 alkyl)3; and the monocyclic or polycyclic moiety can be covalently bonded to the imide nitrogen via an optional linker, and can be optionally substituted with 1-5 substituentsindependently selected from a halogen, oxo, —CN, —NO2, OH, ═C(CN)2, —NH2, —NH(C1-20 alkyl), N(C1-20 alkyl)2, —S(O)2OH, —CHO, —C(O)OH, —C(O)—C1-20 alkyl, —C(O)—OC1-20 alkyl, —C(O)NH2, —C(O)NH—C1-20 alkyl, —C(O)N(C1-20 alkyl)2, —SiH3, —SiH(C1-20 alkyl)2, —SiH2(C1-20 alkyl), —Si(C1-20 alkyl)3, —O—C1-20 alkyl, —O—C1-20 alkenyl, —O—C1-20 haloalkyl, C1-20 alkyl, C1-20 alkenyl, C1-20 haloalkyl, C7-20 arylalkyl, C6-20 aryloxy and C7-20 arylcarbonyl. M2 is a repeating unit comprising one or more cyclic moieties; and n is an integer between 2 and 5,000.

    DITHIENOPHTHALIMIDE SEMICONDUCTOR POLYMERS
    9.
    发明申请
    DITHIENOPHTHALIMIDE SEMICONDUCTOR POLYMERS 有权

    公开(公告)号：US20140142265A1

    公开(公告)日：2014-05-22

    申请号：US14129772

    申请日：2012-07-04

    申请人： Hiroyoshi Noguchi ,  Florian Doetz ,  Ashok Kumar Mishra ,  Subramanian Vaidyanathan ,  Mai Minh-Tien

    发明人： Hiroyoshi Noguchi ,  Florian Doetz ,  Ashok Kumar Mishra ,  Subramanian Vaidyanathan ,  Mai Minh-Tien

    IPC分类号： H01L51/00

    CPC分类号： H01L51/0036 ,  C08G61/126 ,  C08G2261/124 ,  C08G2261/1412 ,  C08G2261/3223 ,  C08G2261/3327 ,  C08G2261/344 ,  C08G2261/364 ,  C08G2261/92 ,  H01L51/0043 ,  H01L51/0558 ,  Y02E10/549

    摘要： The invention concerns apolymer of the formula (I): wherein: M1 is an optionally substituted dithienophthalimide formula (II): wherein: X is N or C—R, wherein R is H or a C1-C40 alkyl group, R2, at each occurrence, is independently selected from H, a C1-40 alkyl group, a C2-40 alkenyl group, a C1-40 haloalkyl group, and a monocyclicor polycyclic moiety, wherein: each of the C1-40 alkyl group, the C2-40 alkenyl group, and the C1-40 haloalkyl group can be optionally substituted with 1-10 substituents independently selected from a halogen, CN, —NO2, OH, NH2, —NH(C1-20 alkyl), N(C1-20 alkyl)2, —S(O)2OH, —CHO, —C(O)—C1-20 alkyl, —C(O)OH, —C(O)—OC1-20 alkyl, —C(O)NH2, —C(O)NH—C1-20 alkyl, —C(O)N(C1-20 alkyl)2, —OC1-20 alkyl, —SiH3, —SiH(C1-20 alkyl)2, —SiH2(C1-20 alkyl), and —Si(C1-20 alkyl)3; and the monocyclic or polycyclic moiety can be covalently bonded to the imide nitrogen via an optional linker, and can be optionally substituted with 1-5 substituentsindependently selected from a halogen, oxo, —CN, —NO2, OH, ═C(CN)2, —NH2, —NH(C1-20 alkyl), N(C1-20 alkyl)2, —S(O)2OH, —CHO, —C(O)OH, —C(O)—C1-20 alkyl, —C(O)—OC1-20 alkyl, —C(O)NH2, —C(O)NH—C1-20 alkyl, —C(O)N(C1-20 alkyl)2, —SiH3, —SiH(C1-20 alkyl)2, —SiH2(C1-20 alkyl), —Si(C1-20 alkyl)3, —O—C1-20 alkyl, —O—C1-20 alkenyl, —O—C1-20 haloalkyl, C1-20 alkyl, C1-20 alkenyl, C1-20 haloalkyl, C7-20 arylalkyl, C6-20 aryloxy and C7-20 arylcarbonyl. M2 is a repeating unit comprising one or more cyclic moieties; and n is an integer between 2 and 5,000.