Polyethylene glycol-modified semiconductor nanoparticles, method for producing the same, and material for biological diagnosis
    1.
    发明授权
    Polyethylene glycol-modified semiconductor nanoparticles, method for producing the same, and material for biological diagnosis 有权
    聚乙二醇改性半导体纳米粒子,其制造方法以及生物诊断用材料

    公开(公告)号:US07041371B2

    公开(公告)日:2006-05-09

    申请号:US10810305

    申请日:2004-03-26

    IPC分类号: B32B5/16

    摘要: This invention provides PEG-modified semiconductor nanoparticles of which fluorescence intensity is effectively inhibited from lowering, which are capable of forming a stable dispersion in water, and which are capable of bonding easily with biomolecules having specific recognition, as well as methods for conveniently preparing such nanoparticles, and a material for biological diagnosis. The water-soluble PEG-modified semiconductor nanoparticles of the present invention includes a structure having PEG of a number average molecular weight of 300 to 20000 having a thiol group at one end, bonded via cadmium to II–VI semiconductor nanocrystals of a core-shell structure having a ZnX (wherein X stands for O, S, Se, or Te) shell.

    摘要翻译: 本发明提供了PEG修饰的半导体纳米粒子,其荧光强度被有效地抑制,能够在水中形成稳定的分散体,并且能够容易地与具有特定识别性的生物分子结合,以及方便地制备 纳米颗粒和用于生物诊断的材料。 本发明的水溶性PEG改性的半导体纳米粒子包括数均分子量为300〜20000的具有一端具有硫醇基的PEG的结构,其通过镉键合到芯壳的II-VI半导体纳米晶体 具有ZnX(其中X代表O,S,Se或Te)壳的结构。

    COSMETIC PRODUCT, NANOPARTICLES FOR COSMETICS, AND POWDER FOR COSMETICS
    4.
    发明申请
    COSMETIC PRODUCT, NANOPARTICLES FOR COSMETICS, AND POWDER FOR COSMETICS 审中-公开
    化妆品,化妆品用纳米脂和化妆品粉末

    公开(公告)号:US20100040697A1

    公开(公告)日:2010-02-18

    申请号:US12581474

    申请日:2009-10-19

    IPC分类号: A61K9/50 A61K31/74

    摘要: The invention provides a cosmetic product which has a good texture and allows full expression of the inherent functions of ceramide as an intercellular lipid, such as skin barrier function and hair protection effect, as well as nanoparticles for cosmetics and powder for cosmetics which may be used in the above cosmetic product, exhibit good skin barrier function and hair protection effect, and are easy to incorporate into the above cosmetic product. The cosmetic product, the nanoparticles, and the powder for cosmetics according to the present invention contain a polymer obtained by polymerization of a monomer material containing a glycerol (meth)acrylate monomer represented by the formula (1): (R1: —H, —CH3; R2: —(CH2)n-; n is an integer of 1 to 4).

    摘要翻译: 本发明提供了一种具有良好质地的化妆品,并且能够充分表达神经酰胺作为细胞间脂质的固有功能,例如皮肤屏障功能和毛发保护效果,以及可用于化妆品的化妆品和粉末的纳米颗粒 在上述化妆品中,具有良好的皮肤屏障功能和护发效果,并且容易并入上述化妆品中。 根据本发明的化妆品,纳米颗粒和化妆品粉末含有通过聚合由式(1)表示的甘油(甲基)丙烯酸酯单体的单体材料得到的聚合物:(R1:-H, - CH3; R2: - (CH2)n-; n为1〜4的整数)。

    Diol (meth) acrylate compound having urethane bond, method for producing the same, and polymer thereof
    5.
    发明申请
    Diol (meth) acrylate compound having urethane bond, method for producing the same, and polymer thereof 有权
    具有氨基甲酸酯键的二醇(甲基)丙烯酸酯化合物,其制备方法及其聚合物

    公开(公告)号:US20060089473A1

    公开(公告)日:2006-04-27

    申请号:US11259543

    申请日:2005-10-25

    IPC分类号: C08F226/02 C07C271/18

    摘要: The present invention provides compounds having in their molecule a structure contributing to high hydrophilicity, and having high photopolymerizability, as well as polymers of such compounds, and a method for producing the compound. The compounds are diol (meth)acrylate having a urethane bond represented by the formula (1), and cyclic ketal (meth)acrylate having a urethane bond represented by the formula (2): (R1: H, —CH3; R2: —(CH2)n-; R3: —(CH2)m-; n: 1-4; m: 1-8; (AO) : C2-C4 oxyalkylene group; x: 0-1000; R4, R5: H, —CH3, —C2H5).

    摘要翻译: 本发明提供了在其分子中具有有助于高亲水性和高光聚合性的结构的化合物,以及这些化合物的聚合物,以及该化合物的制备方法。 化合物是具有由式(1)表示的氨基甲酸酯键的二醇(甲基)丙烯酸酯和具有由式(2)表示的氨基甲酸酯键的环状缩酮(甲基)丙烯酸酯:(R 1) H,-CH 3; R 2: - (CH 2)n - ; R 3: - ( CH 2)m-; n:1-4; m:1-8;(AO):C 2 -C 4亚氧烷基; x:0-1000; R 4 < H 5,-CH 3,-C 2 H 5)。

    Method for preparing semiconductor nanocrystals having core-shell structure
    6.
    发明申请
    Method for preparing semiconductor nanocrystals having core-shell structure 审中-公开
    制备具有核 - 壳结构的半导体纳米晶体的方法

    公开(公告)号:US20050164227A1

    公开(公告)日:2005-07-28

    申请号:US10913305

    申请日:2004-08-05

    摘要: The invention relates to a method for producing semiconductor nanocrystals with a core-shell structure and the semiconductor nanocrystals obtained by the method, which enables continuous production in a compact system. The method includes (1) passing a stock solution of a core component such as CdSe through a first hollow microchannel having an inner diameter of 1 to 1000 μm at a predetermined constant flowrate to form cores at 250 to 350° C., (2) passing a stock solution of a shell component such as ZnS through a second microchannel, and (3) passing the core stream merged with the shell component stream through a third microchannel at a predetermined constant flow rate to epitaxially grow the shell component on the cores at 100 to 250° C. to thereby form a core-shell structure. The microchannels communicate with each other, and step (3) is performed consecutively with steps (1) and (2).

    摘要翻译: 本发明涉及一种制备具有核 - 壳结构的半导体纳米晶体和通过该方法获得的半导体纳米晶体的方法,其能够在紧凑的系统中连续生产。 该方法包括:(1)将核心部件如CdSe的原液以预定的恒定流量通过内径为1〜1000μm的第一中空微通道,在250〜350℃下形成芯,(2) 将诸如ZnS的壳组分的储备溶液通过第二微通道,并且(3)使以与壳组分流合并的芯流以预定的恒定流速通过第三微通道以在芯上外延生长壳组分 100〜250℃,从而形成核 - 壳结构。 微通道彼此通信,并且步骤(3)与步骤(1)和(2)连续执行。

    Inorganic-organic hybrid composition and use thereof
    7.
    发明授权
    Inorganic-organic hybrid composition and use thereof 有权
    无机 - 有机杂化组合物及其用途

    公开(公告)号:US08399558B2

    公开(公告)日:2013-03-19

    申请号:US12305543

    申请日:2007-06-19

    IPC分类号: C08F136/00 C08F8/42 C08F8/40

    摘要: The present disclosure provides an inorganic-organic hybrid film which is excellent in transparency, adhesion, heat resistance, weatherability, and anti-rust property, whose refractive index may be controlled easily, and which is also excellent in hardness. Also provided are an inorganic-organic hybrid composition as a starting material for the film, and a hard coating material, an optical material, an anti-rust coating material, and a conductive coating material, all utilizing the composition. The composition is characterized by containing organic component (A) composed of monomer component (a1) containing a particular diol (meth)acrylate compound (U) having a urethane bond, or polymer component (a2) containing polymer (P) obtained by polymerization of monomer component (a1), and inorganic component (B), wherein the ratio of the organic component (A) to the inorganic component (B) is 1:99 to 99:1 by mass.

    摘要翻译: 本公开内容提供了透明性,粘合性,耐热性,耐候性和防锈性优异的无机 - 有机杂化膜,其折射率可以容易地控制,并且硬度也是优异的。 还提供了作为膜的起始材料的无机 - 有机杂化组合物,以及全部利用组合物的硬涂层材料,光学材料,防锈涂层材料和导电涂层材料。 该组合物的特征在于含有由含有具有氨基甲酸酯键的特定二醇(甲基)丙烯酸酯化合物(U)的单体成分(a1)构成的有机成分(A),或含有聚合物(P)的聚合物成分(a2) 单体成分(a1)和无机成分(B),其中有机成分(A)与无机成分(B)的比例为1:99〜99:1质量%。

    Diol (meth) acrylate compound having urethane bond, method for producing the same, and polymer thereof
    9.
    发明授权
    Diol (meth) acrylate compound having urethane bond, method for producing the same, and polymer thereof 有权
    具有氨基甲酸酯键的二醇(甲基)丙烯酸酯化合物,其制备方法及其聚合物

    公开(公告)号:US07763694B2

    公开(公告)日:2010-07-27

    申请号:US12631049

    申请日:2009-12-04

    IPC分类号: C08F20/26 C08F34/02 C08F20/58

    摘要: The present invention provides compounds having in their molecule a structure contributing to high hydrophilicity, and having high photopolymerizability, as well as polymers of such compounds, and a method for producing the compound. The compounds are diol (meth)acrylate having a urethane bond represented by the formula (1), and cyclic ketal (meth)acrylate having a urethane bond represented by the formula (2): (R1: H, —CH3; R2: —(CH2)n-; R3: —(CH2)m-; n: 1-4; m: 1-8; (AO): C2-C4 oxyalkylene group; x: 0-1000; R4, R5: H, —CH3, —C2H5).

    摘要翻译: 本发明提供了在其分子中具有有助于高亲水性和高光聚合性的结构的化合物,以及这些化合物的聚合物,以及该化合物的制备方法。 化合物是具有由式(1)表示的氨基甲酸酯键的二醇(甲基)丙烯酸酯和具有由式(2)表示的氨基甲酸酯键的环状缩酮(甲基)丙烯酸酯:(R1:H,-CH3; R2: - (CH2)n-; R3: - (CH2)m-; n:1-4; m:1-8;(AO):C2-C4氧化烯基; x:0-1000; R4,R5:H, CH3,-C2H5)。

    DIOL (METH) ACRYLATE COMPOUND HAVING URETHANE BOND, METHOD FOR PRODUCING THE SAME, AND POLYMER THEREOF
    10.
    发明申请
    DIOL (METH) ACRYLATE COMPOUND HAVING URETHANE BOND, METHOD FOR PRODUCING THE SAME, AND POLYMER THEREOF 有权
    具有URETHANE BOND的二(甲基)丙烯酸酯化合物,其制备方法及其聚合物

    公开(公告)号:US20100081780A1

    公开(公告)日:2010-04-01

    申请号:US12631097

    申请日:2009-12-04

    摘要: The present invention provides compounds having in their molecule a structure contributing to high hydrophilicity, and having high photopolymerizability, as well as polymers of such compounds, and a method for producing the compound. The compounds are diol (meth)acrylate having a urethane bond represented by the formula (1), and cyclic ketal (meth)acrylate having a urethane bond represented by the formula (2): (R1: H, —CH3; R2: —(CH2)n-; R3: —(CH2)m-; n: 1-4; m: 1-8; (AO): C2-C4 oxyalkylene group; x: 0-1000; R4, R5: H, —CH3, —C2H5).

    摘要翻译: 本发明提供了在其分子中具有有助于高亲水性和高光聚合性的结构的化合物,以及这些化合物的聚合物,以及该化合物的制备方法。 化合物是具有由式(1)表示的氨基甲酸酯键的二醇(甲基)丙烯酸酯和具有由式(2)表示的氨基甲酸酯键的环状缩酮(甲基)丙烯酸酯:(R1:H,-CH3; R2: - (CH2)n-; R3: - (CH2)m-; n:1-4; m:1-8;(AO):C2-C4氧化烯基; x:0-1000; R4,R5:H, CH3,-C2H5)。