摘要:
This invention provides PEG-modified semiconductor nanoparticles of which fluorescence intensity is effectively inhibited from lowering, which are capable of forming a stable dispersion in water, and which are capable of bonding easily with biomolecules having specific recognition, as well as methods for conveniently preparing such nanoparticles, and a material for biological diagnosis. The water-soluble PEG-modified semiconductor nanoparticles of the present invention includes a structure having PEG of a number average molecular weight of 300 to 20000 having a thiol group at one end, bonded via cadmium to II–VI semiconductor nanocrystals of a core-shell structure having a ZnX (wherein X stands for O, S, Se, or Te) shell.
摘要:
A crosslinked polymer or polymer fine particles which can be obtained through copolymerization of at least a macromonomer having a polyethylene glycol segment, a comonomer having tertiary amine groups in its side chains and a crosslinking agent are provided. Said crosslinked polymer can be provided in the form of polymer nano- or micro-spheres; and also as conjugate nano- or micro-spheres with their core parts fixing or encapsulating metal or semiconductor ultrafine particles.
摘要:
A crosslinked polymer or polymer fine particles which can be obtained through copolymerization of at least a macromonomer having a polyethylene glycol segment, a comonomer having tertiary amine groups in its side chains and a crosslinking agent are provided. Said crosslinked polymer can be provided in the form of polymer nano- or micro- spheres; and also as conjugate nano- or micro-spheres with their core parts fixing or encapsulating metal or semiconductor ultrafine particles.
摘要:
The invention provides a cosmetic product which has a good texture and allows full expression of the inherent functions of ceramide as an intercellular lipid, such as skin barrier function and hair protection effect, as well as nanoparticles for cosmetics and powder for cosmetics which may be used in the above cosmetic product, exhibit good skin barrier function and hair protection effect, and are easy to incorporate into the above cosmetic product. The cosmetic product, the nanoparticles, and the powder for cosmetics according to the present invention contain a polymer obtained by polymerization of a monomer material containing a glycerol (meth)acrylate monomer represented by the formula (1): (R1: —H, —CH3; R2: —(CH2)n-; n is an integer of 1 to 4).
摘要:
The present invention provides compounds having in their molecule a structure contributing to high hydrophilicity, and having high photopolymerizability, as well as polymers of such compounds, and a method for producing the compound. The compounds are diol (meth)acrylate having a urethane bond represented by the formula (1), and cyclic ketal (meth)acrylate having a urethane bond represented by the formula (2): (R1: H, —CH3; R2: —(CH2)n-; R3: —(CH2)m-; n: 1-4; m: 1-8; (AO) : C2-C4 oxyalkylene group; x: 0-1000; R4, R5: H, —CH3, —C2H5).
摘要翻译:本发明提供了在其分子中具有有助于高亲水性和高光聚合性的结构的化合物,以及这些化合物的聚合物,以及该化合物的制备方法。 化合物是具有由式(1)表示的氨基甲酸酯键的二醇(甲基)丙烯酸酯和具有由式(2)表示的氨基甲酸酯键的环状缩酮(甲基)丙烯酸酯:(R 1) H,-CH 3; R 2: - (CH 2)n - ; R 3: - ( CH 2)m-; n:1-4; m:1-8;(AO):C 2 -C 4亚氧烷基; x:0-1000; R 4 < H 5,-CH 3,-C 2 H 5)。
摘要:
The invention relates to a method for producing semiconductor nanocrystals with a core-shell structure and the semiconductor nanocrystals obtained by the method, which enables continuous production in a compact system. The method includes (1) passing a stock solution of a core component such as CdSe through a first hollow microchannel having an inner diameter of 1 to 1000 μm at a predetermined constant flowrate to form cores at 250 to 350° C., (2) passing a stock solution of a shell component such as ZnS through a second microchannel, and (3) passing the core stream merged with the shell component stream through a third microchannel at a predetermined constant flow rate to epitaxially grow the shell component on the cores at 100 to 250° C. to thereby form a core-shell structure. The microchannels communicate with each other, and step (3) is performed consecutively with steps (1) and (2).
摘要:
The present disclosure provides an inorganic-organic hybrid film which is excellent in transparency, adhesion, heat resistance, weatherability, and anti-rust property, whose refractive index may be controlled easily, and which is also excellent in hardness. Also provided are an inorganic-organic hybrid composition as a starting material for the film, and a hard coating material, an optical material, an anti-rust coating material, and a conductive coating material, all utilizing the composition. The composition is characterized by containing organic component (A) composed of monomer component (a1) containing a particular diol (meth)acrylate compound (U) having a urethane bond, or polymer component (a2) containing polymer (P) obtained by polymerization of monomer component (a1), and inorganic component (B), wherein the ratio of the organic component (A) to the inorganic component (B) is 1:99 to 99:1 by mass.
摘要:
The present invention provides compounds having in their molecule a structure contributing to high hydrophilicity, and having high photopolymerizability, as well as polymers of such compounds, and a method for producing the compound. The compounds are diol (meth)acrylate having a urethane bond represented by the formula (1), and cyclic ketal (meth)acrylate having a urethane bond represented by the formula (2): (R1: H, —CH3; R2: —(CH2)n-; R3: —(CH2)m-; n: 1-4; m: 1-8; (AO): C2-C4 oxyalkylene group; x: 0-1000; R4, R5: H, —CH3, —C2H5).
摘要:
The present invention provides compounds having in their molecule a structure contributing to high hydrophilicity, and having high photopolymerizability, as well as polymers of such compounds, and a method for producing the compound. The compounds are diol (meth)acrylate having a urethane bond represented by the formula (1), and cyclic ketal (meth)acrylate having a urethane bond represented by the formula (2): (R1: H, —CH3; R2: —(CH2)n-; R3: —(CH2)m-; n: 1-4; m: 1-8; (AO): C2-C4 oxyalkylene group; x: 0-1000; R4, R5: H, —CH3, —C2H5).
摘要:
The present invention provides compounds having in their molecule a structure contributing to high hydrophilicity, and having high photopolymerizability, as well as polymers of such compounds, and a method for producing the compound. The compounds are diol (meth)acrylate having a urethane bond represented by the formula (1), and cyclic ketal (meth)acrylate having a urethane bond represented by the formula (2): (R1: H, —CH3; R2: —(CH2)n-; R3: —(CH2)m-; n: 1-4; m: 1-8; (AO): C2-C4 oxyalkylene group; x: 0-1000; R4, R5: H, —CH3, —C2H5).