公开(公告)号：US20210399291A1

公开(公告)日：2021-12-23

申请号：US17309205

申请日：2019-11-11

Applicant: BASF SE

Inventor： Maraike AHLF ,  Torsten MAEURER ,  Christoph ERK ,  Jacob HAAG ,  Heino SOMMER

IPC: H01M4/36 ,  H01M4/525 ,  H01M10/0525 ,  H01M4/505

Abstract: Process for making a coated oxide material wherein said process comprises the following steps: (a) providing a particulate material selected from lithiated nickel-cobalt aluminum oxides, lithium cobalt oxide, lithiated cobalt-manganese oxides and lithiated layered nickel-cobalt-manganese oxides, (b) treating said particulate material with an aqueous medium, (c) removing said aqueous medium, (d) drying said treated particulate material, (e) treating said particulate material from step (d) with a metal amide or alkyl metal compound, (f) treating the material obtained in step (e) with moisture or an oxidizing agent, and, optionally, repeating the sequence of steps (e) and (f).

公开(公告)号：US20190309417A1

公开(公告)日：2019-10-10

申请号：US16338915

申请日：2017-10-18

Applicant: BASF SE

Inventor： Maraike AHLF ,  David Dominique SCHWEINFURTH ,  Lukas MAYR ,  Kinga Izabela LESZCZYNSKA ,  David SCHESCHKEWITZ

IPC: C23C16/455 ,  C23C16/32 ,  C23C16/34 ,  C23C16/38 ,  C23C16/40

Abstract: The present invention is in the field of processes for the generation of thin inorganic films on substrates. In particular, the present invention relates to a process comprising depositing the compound of general formula (I) onto a solid substrate, wherein R1, R2, R3, R4, and R5 is hydrogen, an alkyl group, an alkenyl group, an aryl group or a silyl group, wherein not more than three of R1, R2, R3, R4, and R5 are hydrogen, X is a group which binds to silicon, m is 1 or 2, n is 0, 1, or 2, and Si is in the oxidation state +2.

公开(公告)号：US20210218008A1

公开(公告)日：2021-07-15

申请号：US17250792

申请日：2019-08-30

Applicant: BASF SE

Inventor： Maraike AHLF ,  Heino SOMMER ,  Carsten SUELING ,  Markus Daniel GRONER ,  Christopher GUMP ,  Robert HALL ,  Joseph SPENCER, II

IPC: H01M4/04 ,  H01M4/505 ,  H01M4/525

Abstract: The present disclosure relates to a process for coating an oxide material comprising: (a) providing a particulate material chosen from lithiated nickel-cobalt aluminum oxides, lithiated cobalt-manganese oxides, and lithiated layered nickel-cobalt-manganese oxides, (b) treating the cathode active material with a metal alkoxide, metal amide, alkyl metal compound, metal halide, or metal hydride at a pressure ranging from 5 mbar to 1 bar above ambient pressure, (c) deactivating the material obtained in step (b) with a HF containing gas at ambient pressure,  wherein step (b) is carried out in a mechanical mixer chosen from compulsory mixers and free-fall mixers, or step (b) is carried out using a moving bed or a fixed bed.

公开(公告)号：US20190393494A1

公开(公告)日：2019-12-26

申请号：US16489895

申请日：2018-02-21

Applicant: BASF SE

Inventor： Frank KLEINE JAEGER ,  Tillmann LIEBSCH ,  Michael SCHOENHERR ,  Dominik GARELLA ,  Fatih CETINEL ,  Heino SOMMER ,  Maraike AHLF ,  Daniel LOEFFLER ,  Regina VOGELSANG ,  Jacob HAAG

IPC: H01M4/36 ,  C23C16/44 ,  C23C16/442 ,  C23C16/455 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0525

Abstract: The present invention is related to a process for coating anoxide material, said process comprising the following steps: (a) providing a particulate material selected from lithiated nickel-cobalt aluminum oxides, lithiated cobalt-manganese oxides and lithiated layered nickel-cobalt-manganese oxides, (b) treating said cathode active material with a metal alkoxide or metal amide or alkyl metal compound, (c) treating the material obtained in step (b) with moisture, and, optionally, repeating the sequence of steps (b) and (c), wherein steps (b) and (c) are carried out in a mixer that mechanically introduces mixing energy into the particulate material, or by way of a moving bed or fixed bed, and wherein steps (b) and (c) are carried out at a pressure that is in the range of from 5 mbar to 1 bar above normal pressure.

公开(公告)号：US20190144998A1

公开(公告)日：2019-05-16

申请号：US15779570

申请日：2016-11-29

Applicant: BASF SE

Inventor： Falko ABELS ,  David Dominique SCHWEINFURTH ,  Karl MATOS ,  Daniel LOEFFLER ,  Maraike AHLF ,  Florian BLASBERG ,  Thomas SCHAUB ,  Jan SPIELMANN ,  Axel KIRSTE ,  Boris GASPAR

IPC: C23C16/455 ,  C07F9/50 ,  C07F9/6584 ,  C23C16/06

Abstract: The present invention is in the field of processes for the generation of thin inorganic films on substrates, in particular atomic layer deposition processes. It relates to a process for preparing metal films comprising (a) depositing a metal-containing compound from the gaseous state onto a solid substrate and (b) bringing the solid substrate with the deposited metal-containing compound in contact with a reducing agent in the gaseous state, wherein the reducing agent is or at least partially forms at the surface of the solid substrate a carbene, a silylene or a phosphor radical.

公开(公告)号：US20210214844A1

公开(公告)日：2021-07-15

申请号：US17250793

申请日：2019-08-30

Applicant: BASF SE

Inventor： Maraike AHLF ,  Heino SOMMER ,  Regina VOGELSANG ,  Jacob HAAG ,  Markus GRONER ,  Christopher GUMP ,  Robert HALL ,  Joseph SPENCER, II

IPC: C23C16/44 ,  C23C16/30 ,  C23C16/442 ,  H01M4/36 ,  C23C16/56 ,  H01M4/04 ,  H01M4/505 ,  H01M4/525 ,  H01M4/02

Abstract: The present disclosure relates to a process for coating an oxide material, process comprising: (a) providing a particulate material chosen from lithiated nickel-cobalt aluminum oxides, lithiated cobalt-manganese oxides, and lithiated layered nickel-cobalt-manganese oxides, (b) treating the cathode active material with a metal alkoxide, a metal halide, a metal chloride, a metal amide, or an alkyl metal compound, (c) treating the material obtained in step (b) with a gas containing HF, and, optionally, repeating the sequence of steps (b) and (c), wherein step (b) is carried out in a mechanical mixer, or step (b) is carried out using a moving bed or fixed bed wherein steps (b) and (c) are carried out at a pressure that is in the range of from 5 mbar to 1 bar above ambient pressure.

公开(公告)号：US20210098782A1

公开(公告)日：2021-04-01

申请号：US16970775

申请日：2019-03-08

Applicant: BASF SE

Inventor： Manuel Alejandro MENDEZ AGUDELO ,  Maraike AHLF ,  Heino SOMMER ,  Jacob HAAG ,  Hannes WOLF ,  Johannes David HOECKER

IPC: H01M4/36 ,  H01M4/505 ,  H01M4/48 ,  H01M4/525 ,  H01M10/0567 ,  H01M10/0525 ,  C01G53/00 ,  C07F9/40

Abstract: An electrochemical cell has a cathode active material selected from mixed lithium transition metal oxides containing Mn and at least one second transition metal; lithium intercalating mixed oxides containing Ni, Al and at least one second transition metal; and lithium metal phosphates, wherein the outer surface of the particulate cathode active material is at least partially coated with an oxide selected from transition metal oxides, lanthanide oxides, and oxides of metals and half metals of groups 2, 13, and 14 of the periodic system; and an electrolyte composition containing at least one silyl ester phosphonate of formula (I) and at least one silyl ester phosphonate of formula (II)

公开(公告)号：US20210083285A1

公开(公告)日：2021-03-18

申请号：US16968322

申请日：2019-01-31

Applicant: BASF SE

Inventor： Heino SOMMER ,  Maraike AHLF ,  Jacob HAAG ,  Regina VOGELSANG ,  Fatih CETINEL

IPC: H01M4/525 ,  H01M10/0525 ,  H01M4/505 ,  H01M4/36 ,  H01M4/62 ,  C01G53/00

Abstract: Process for making a partially coated electrode active material wherein said process comprises the following steps: (a) Providing an electrode active material according to general formula Li1+x, TM1+XO2, wherein TM is a combination of Ni, Co and, optionally, Mn, and, optionally, at least one metal selected from Al, Ti and Zr, and x is in the range of from zero to 0.2, wherein at least 60 mole-% of the transition metal of TM is Ni, and wherein said electrode active material has a residual moisture content in the range of from 50 to 1,000 ppm, (b) treating said electrode active material with a metal alkoxide or metal halide or metal amide or alkyl metal compound, (c) treating the material obtained in step (b) with moisture, (d) repeating the sequence of steps (b) and (c) twice to ten times, (e) performing a post-treatment by heating the material obtained after the last step (d) at a temperature from 200 to 400° C.

公开(公告)号：US20210083284A1

公开(公告)日：2021-03-18

申请号：US16963714

申请日：2019-01-31

Applicant: BASF SE

Inventor： Jacob HAAG ,  Maraike AHLF ,  Heino SOMMER

IPC: H01M4/525 ,  H01M4/505 ,  H01M4/131 ,  H01M4/134 ,  H01M4/1391 ,  H01M4/1395 ,  H01M4/36 ,  H01M10/0525 ,  C01F7/02

Abstract: A process for making a partially coated electrode active material may involve: (a) providing an electrode active material of the formula Li1+xTM1−xO2, wherein TM is a combination of Ni, Co and, optionally, Mn, and, optionally, at least one metal selected from Al, Ti, Mo, W, and Zr, and x is in the range of from zero to 0.2, wherein at least 60 mole-% of the transition metal of TM is Ni, and wherein the electrode active material has a residual moisture content in the range of from 50 to 1,000 ppm; (b) treating the electrode active material with a metal alkoxide or metal halide or metal amide or alkyl metal compound; (c) treating the material obtained in (b) with moisture; and (d) repeating the sequence of (b) and (c) twice to 4 times, wherein, in the last sequence of (b) and (c), moisture is at least partially substituted by ozone.