公开(公告)号：US10005702B2

公开(公告)日：2018-06-26

申请号：US13927751

申请日：2013-06-26

Applicant: BASF SE

Inventor： Kirsten Spannhoff ,  Florina Corina Patcas ,  Ekkehard Schwab ,  Alexander Weck ,  Kerem Bay ,  Matthias Mielke ,  Oliver Seel

IPC: B01J29/06 ,  C07C1/22 ,  B01J29/40 ,  B01J37/02 ,  C07C1/20 ,  B01J38/02 ,  B01J23/02 ,  B01J23/10 ,  B01J29/70 ,  B01J29/80 ,  B01J29/90 ,  B01J35/04

CPC classification number: C07C1/22 ,  B01J23/02 ,  B01J23/10 ,  B01J29/061 ,  B01J29/40 ,  B01J29/70 ,  B01J29/7038 ,  B01J29/80 ,  B01J29/90 ,  B01J35/04 ,  B01J37/0215 ,  B01J37/0246 ,  B01J38/02 ,  B01J2029/062 ,  C07C1/20 ,  C07C2529/40 ,  C07C2529/70 ,  C07C2529/80 ,  Y02P20/584 ,  C07C11/02

Abstract: The present invention relates to a catalyst for the conversion of oxygenates to olefins, comprising a support substrate and a layer applied to the substrate, wherein the layer comprises one or more zeolites of the MFI, MEL and/or MWW structure type, the one or more zeolites comprising one or more alkaline earth metals, to the preparation and use thereof, and to a process for converting oxygenates to olefins using the catalyst.

公开(公告)号：US09266092B2

公开(公告)日：2016-02-23

申请号：US14157865

申请日：2014-01-17

Applicant: BASF Corporation ,  BASF SE

Inventor： Mirko Arnold ,  Stefan Kotrel ,  Attilio Siani ,  Stephan Siemund ,  Thomas Schmitz ,  Burkhard Rabe ,  Gary A Gramiccioni ,  Oliver Seel ,  Torsten Neubauer ,  Knut Wassermann

IPC: B01D50/00 ,  B01D53/34 ,  F01N3/00 ,  F23J11/00 ,  B01D53/56 ,  B01D53/94 ,  B01J23/00 ,  B01J23/02 ,  B01J23/08 ,  B01J23/10 ,  B01J23/42 ,  B01J23/44 ,  B01J23/56 ,  B01J23/58 ,  B01J21/04 ,  B01J23/63 ,  B01J37/02 ,  F01N3/10 ,  B01J35/00 ,  B01J35/10

CPC classification number: B01J23/63 ,  B01D53/945 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/1025 ,  B01D2255/407 ,  B01D2255/9022 ,  B01D2255/908 ,  B01D2258/014 ,  B01J35/0006 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1061 ,  B01J37/0244 ,  B01J37/0248 ,  F01N3/101 ,  F01N2510/0684 ,  Y02A50/2324 ,  Y02T10/22

Abstract: Provided are catalyst composites whose catalytic material is effective to substantially simultaneously oxidize carbon monoxide and hydrocarbons and reduce nitrogen oxides. The catalyst composites have a two-metal layer on a carrier, the two-metal layer comprising a rhodium component supported by a first support comprising a refractory metal oxide component or a first ceria-zirconia composite; a palladium component supported by a second support comprising a second ceria-zirconia composite; one or more of a promoter, stabilizer, or binder; wherein the amount of the total of the first and second ceria-zirconia composites in the two-metal layer is equal to or greater than the amount of the refractory metal oxide component. Methods of making and using the same are also provided.

Abstract translation: 提供催化剂复合材料，其催化材料有效地基本上同时氧化一氧化碳和碳氢化合物并还原氮氧化物。 催化剂复合材料在载体上具有双金属层，所述双金属层包含由包含难熔金属氧化物组分或第一氧化铈 - 氧化锆复合材料的第一载体负载的铑组分; 由包含第二氧化铈 - 氧化锆复合材料的第二载体负载的钯组分; 一种或多种促进剂，稳定剂或粘合剂; 其中所述二金属层中的所述第一和第二氧化铈 - 氧化锆复合材料的总量的量等于或大于所述难熔金属氧化物组分的量。 还提供了制备和使用它们的方法。

公开(公告)号：US20140205523A1

公开(公告)日：2014-07-24

申请号：US14157865

申请日：2014-01-17

Applicant: BASF SE ,  BASF Corporation

Inventor： Mirko Arnold ,  Stefan Kotrel ,  Attilio Siani ,  Stephan Siemund ,  Thomas Schmitz ,  Burkhard Rabe ,  Gary A. Gramiccioni ,  Oliver Seel ,  Torsten Neubauer ,  Knut Wassermann

IPC: B01J23/63 ,  B01D53/94

CPC classification number: B01J23/63 ,  B01D53/945 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/1025 ,  B01D2255/407 ,  B01D2255/9022 ,  B01D2255/908 ,  B01D2258/014 ,  B01J35/0006 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1061 ,  B01J37/0244 ,  B01J37/0248 ,  F01N3/101 ,  F01N2510/0684 ,  Y02A50/2324 ,  Y02T10/22

Abstract: Provided are catalyst composites whose catalytic material is effective to substantially simultaneously oxidize carbon monoxide and hydrocarbons and reduce nitrogen oxides. The catalyst composites have a two-metal layer on a carrier, the two-metal layer comprising a rhodium component supported by a first support comprising a refractory metal oxide component or a first ceria-zirconia composite; a palladium component supported by a second support comprising a second ceria-zirconia composite; one or more of a promoter, stabilizer, or binder; wherein the amount of the total of the first and second ceria-zirconia composites in the two-metal layer is equal to or greater than the amount of the refractory metal oxide component. Methods of making and using the same are also provided.

Abstract translation: 提供催化剂复合材料，其催化材料有效地基本上同时氧化一氧化碳和碳氢化合物并还原氮氧化物。 催化剂复合材料在载体上具有双金属层，所述双金属层包含由包含难熔金属氧化物组分或第一氧化铈 - 氧化锆复合材料的第一载体负载的铑组分; 由包含第二氧化铈 - 氧化锆复合材料的第二载体负载的钯组分; 一种或多种促进剂，稳定剂或粘合剂; 其中所述二金属层中的所述第一和第二氧化铈 - 氧化锆复合材料的总量的量等于或大于所述难熔金属氧化物组分的量。 还提供了制备和使用它们的方法。