公开(公告)号：US20130197288A1

公开(公告)日：2013-08-01

申请号：US13753661

申请日：2013-01-30

Applicant: BASF SE ,  Linde AG

Inventor： Alexander Schäfer ,  Kirsten Spannhoff ,  Ekkehard Schwab ,  Christian Thaller ,  Harald Schmaderer ,  Nicole Schödel ,  Ernst Haidegger ,  Holger Schmigalle ,  Axel Behrens ,  Volker Göke

IPC: C07C1/04

CPC classification number: C07C1/0425 ,  C07C1/20 ,  C07C41/01 ,  C07C2529/40 ,  Y02P30/42 ,  C07C11/04 ,  C07C11/06 ,  C07C11/08 ,  C07C43/043

Abstract: The present invention relates to a process for converting a gas mixture comprising CO and H2 to olefins, comprising (1) providing a gas mixture (G0) comprising CO and H2; (2) providing a catalyst (C1) for conversion of CO and H2 to dimethyl ether; (3) contacting the gas mixture (G0) with the catalyst (C1) to obtain a gas mixture (G1) comprising dimethyl ether and CO2; (4) providing a catalyst (C2) for conversion of dimethyl ether to olefins; (5) contacting the gas mixture (G1) comprising dimethyl ether with the catalyst (C2) to obtain an olefin-comprising gas mixture (G2).

Abstract translation: 本发明涉及将包含CO和H 2的气体混合物转化为烯烃的方法，其包括（1）提供包含CO和H 2的气体混合物（G0）; （2）提供用于将CO和H 2转化为二甲醚的催化剂（C1）; （3）使气体混合物（G0）与催化剂（C1）接触以获得包含二甲醚和CO 2的气体混合物（G1）; （4）提供用于将二甲醚转化为烯烃的催化剂（C2）; （5）使包含二甲醚的气体混合物（G1）与催化剂（C2）接触以获得含烯烃的气体混合物（G2）。

公开(公告)号：US20140005457A1

公开(公告)日：2014-01-02

申请号：US13927839

申请日：2013-06-26

Applicant: Basf Se

Inventor： Kirsten Spannhoff ,  Florina Corina Patcas ,  Kerem Bay ,  Manuela Gaab ,  Ekkehard Schwab ,  Michael Hesse

IPC: B01J29/40

CPC classification number: B01J29/40 ,  B01J23/02 ,  B01J23/10 ,  B01J29/061 ,  B01J29/70 ,  B01J29/7038 ,  B01J29/80 ,  B01J29/90 ,  B01J35/04 ,  B01J37/0009 ,  B01J37/0215 ,  B01J37/28 ,  B01J38/02 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/42 ,  C07C1/20 ,  C07C11/04 ,  C07C11/06 ,  C07C11/08 ,  C07C2521/04 ,  C07C2527/173 ,  C07C2529/40 ,  C07C2529/70 ,  Y02P20/584 ,  C07C11/02

Abstract: The present invention relates to a catalyst for the conversion of oxygenates to olefins, wherein the catalyst comprises one or more zeolites of the MFI, MEL and/or MWW structure type and particles of one or more metal oxides, the one or more zeolites of the MFI, MEL and/or MWW structure type comprising one or more alkaline earth metals, and the particles of the one or more metal oxides comprising phosphorus, the phosphorus being present at least partly in oxidic form, and the one or more alkaline earth metals being selected from the group consisting of Mg, Ca, Sr, Ba and combinations of two or more thereof, to the preparation and use thereof, and to a process for converting oxygenates to olefins using the catalyst.

Abstract translation: 本发明涉及用于将含氧化合物转化为烯烃的催化剂，其中催化剂包含一种或多种MFI，MEL和/或MWW结构类型的沸石和一种或多种金属氧化物的颗粒，一种或多种沸石 MFI，MEL和/或包含一种或多种碱土金属的MWW结构类型，以及一种或多种包含磷的金属氧化物的颗粒，磷至少部分为氧化形式存在，一种或多种碱土金属为 选自Mg，Ca，Sr，Ba及其两种或更多种的组合，以及使用该催化剂将含氧物转化为烯烃的方法。

公开(公告)号：US20140005456A1

公开(公告)日：2014-01-02

申请号：US13927751

申请日：2013-06-26

Applicant: BASF SE

Inventor： Kirsten Spannhoff ,  Florina Corina Patcas ,  Ekkehard Schwab ,  Alexander Weck ,  Kerem Bay

IPC: C07C1/22 ,  B01J29/40

CPC classification number: C07C1/22 ,  B01J23/02 ,  B01J23/10 ,  B01J29/061 ,  B01J29/40 ,  B01J29/70 ,  B01J29/7038 ,  B01J29/80 ,  B01J29/90 ,  B01J35/04 ,  B01J37/0215 ,  B01J37/0246 ,  B01J38/02 ,  B01J2029/062 ,  C07C1/20 ,  C07C2529/40 ,  C07C2529/70 ,  C07C2529/80 ,  Y02P20/584 ,  C07C11/02

Abstract: The present invention relates to a catalyst for the conversion of oxygenates to olefins, comprising a support substrate and a layer applied to the substrate, wherein the layer comprises one or more zeolites of the MFI, MEL and/or MWW structure type, the one or more zeolites comprising one or more alkaline earth metals, to the preparation and use thereof, and to a process for converting oxygenates to olefins using the catalyst.

Abstract translation: 本发明涉及用于将含氧化合物转化为烯烃的催化剂，其包含支撑基材和施加到基材上的层，其中该层包含一种或多种MFI，MEL和/或MWW结构类型的沸石， 包含一种或多种碱土金属的更多沸石，其制备和用途，以及使用该催化剂将含氧物转化为烯烃的方法。

公开(公告)号：US09598326B2

公开(公告)日：2017-03-21

申请号：US14076723

申请日：2013-11-11

Applicant: BASF SE

Inventor： Manuela Gaab ,  Ulrich Müller ,  Milan Kostur ,  Kirsten Spannhoff ,  Kerem Bay ,  Andrei-Nicolae Parvulescu

IPC: C07C1/22 ,  C07C1/20

CPC classification number: C07C1/20 ,  C07C2529/40 ,  C07C11/02

Abstract: The present invention relates to a process for the conversion of oxygenates to olefins comprising (i) providing a gas stream comprising one or more oxygenates; and (ii) contacting the gas stream with a catalyst; wherein the catalyst comprises a zeolitic material having an MFI, MEL, and/or MWW-type framework structure comprising YO2 and X2O3, wherein Y is a tetravalent element, and X is a trivalent element, said zeolitic material being obtainable and/or obtained according to a method comprising (1) preparing a mixture comprising one or more sources for YO2, one or more sources for X2O3, and one or more solvents; and (2) crystallizing the mixture obtained in step (1) to obtain a zeolitic material having an MFI, MEL and/or MWW-type framework structure; wherein the mixture crystallized in step (2) contains 3 wt.-% or less of the one or more elements M based on 100 wt.-% of YO2, wherein M stands for sodium.

公开(公告)号：US20140135556A1

公开(公告)日：2014-05-15

申请号：US14076651

申请日：2013-11-11

Applicant: BASF SE

Inventor： Manuela Gaab ,  Ulrich Müller ,  Milan Kostur ,  Kirsten Spannhoff ,  Kerem Bay ,  Andrei-Nicolae Parvulescu

IPC: B01J29/70 ,  C07C1/22

CPC classification number: B01J29/7038 ,  B01J23/02 ,  B01J29/40 ,  B01J29/7034 ,  B01J37/0009 ,  B01J37/0201 ,  C07C1/20 ,  C07C2523/02 ,  C07C2529/035 ,  C07C2529/40 ,  C07C2529/70 ,  Y02P20/52 ,  C07C11/06 ,  C07C11/08

Abstract: Described is a process for the production of a zeolitic material having an MFI, MEL, and/or MWW-type framework structure comprising YO2 and X2O3. The process comprises (1) preparing a mixture comprising one or more sources for YO2, one or more sources for X2O3, and one or more solvents; (2) crystallizing the mixture obtained in step (1) to obtain a zeolitic material having an MFI, MEL and/or MWW-type framework structure; and (3) impregnating the zeolitic material obtained in step (2) with one or more elements selected from the group of alkaline earth metals. Y is a tetravalent element, and X is a trivalent element. The mixture crystallized in step (2) contains 3 wt.-% or less of one or more elements M based on 100 wt-% of YO2, wherein M stands for sodium.

Abstract translation: 描述了一种生产具有包含YO 2和X 2 O 3的MFI，MEL和/或MWW型骨架结构的沸石材料的方法。 该方法包括（1）制备包含一种或多种YO源的混合物，一种或多种X 2 O 3源和一种或多种溶剂的混合物; （2）使步骤（1）中获得的混合物结晶，得到具有MFI，MEL和/或MWW型骨架结构的沸石材料; 和（3）用一种或多种选自碱土金属的元素浸渍步骤（2）中获得的沸石材料。 Y是四价元素，X是三价元素。 在步骤（2）中结晶的混合物含有3重量％或更少的一种或多种基于100重量％YO 2的元素M，其中M代表钠。

公开(公告)号：US10005702B2

公开(公告)日：2018-06-26

申请号：US13927751

申请日：2013-06-26

Applicant: BASF SE

Inventor： Kirsten Spannhoff ,  Florina Corina Patcas ,  Ekkehard Schwab ,  Alexander Weck ,  Kerem Bay ,  Matthias Mielke ,  Oliver Seel

IPC: B01J29/06 ,  C07C1/22 ,  B01J29/40 ,  B01J37/02 ,  C07C1/20 ,  B01J38/02 ,  B01J23/02 ,  B01J23/10 ,  B01J29/70 ,  B01J29/80 ,  B01J29/90 ,  B01J35/04

CPC classification number: C07C1/22 ,  B01J23/02 ,  B01J23/10 ,  B01J29/061 ,  B01J29/40 ,  B01J29/70 ,  B01J29/7038 ,  B01J29/80 ,  B01J29/90 ,  B01J35/04 ,  B01J37/0215 ,  B01J37/0246 ,  B01J38/02 ,  B01J2029/062 ,  C07C1/20 ,  C07C2529/40 ,  C07C2529/70 ,  C07C2529/80 ,  Y02P20/584 ,  C07C11/02

Abstract: The present invention relates to a catalyst for the conversion of oxygenates to olefins, comprising a support substrate and a layer applied to the substrate, wherein the layer comprises one or more zeolites of the MFI, MEL and/or MWW structure type, the one or more zeolites comprising one or more alkaline earth metals, to the preparation and use thereof, and to a process for converting oxygenates to olefins using the catalyst.

公开(公告)号：US09878965B2

公开(公告)日：2018-01-30

申请号：US14897379

申请日：2014-06-13

Applicant: BASF SE

Inventor： Kirsten Spannhoff ,  Andrei-Nicolae Parvulescu ,  Armin Lange de Oliveira ,  Stefan Marx ,  Mathias Feyen ,  Ulrich Müller ,  Ekkehard Schwab

IPC: C07C1/24 ,  C07C1/20 ,  B01J29/89 ,  B01J37/00 ,  C01B39/02 ,  C01B39/08 ,  C01B39/12 ,  C07C1/207

CPC classification number: C07C1/20 ,  B01J29/89 ,  B01J37/0045 ,  B01J2229/183 ,  B01J2229/37 ,  B01J2229/62 ,  C01B39/026 ,  C01B39/08 ,  C01B39/085 ,  C01B39/12 ,  C01P2006/12 ,  C07C1/2076 ,  C07C2529/70 ,  C07C2529/78 ,  C07C2529/86 ,  C07C2529/89 ,  C07C11/167

Abstract: The present invention relates to a gas-phase process for the preparation of butadiene comprising (i) providing a gas stream G-1 comprising ethanol; (ii) contacting the gas stream G-1 comprising ethanol with a catalyst, thereby obtaining a gas stream G-2 comprising butadiene, wherein the catalyst comprises a zeolitic material having a framework structure comprising YO2, Y standing for one or more tetravalent elements, wherein at least a portion of Y comprised in the framework structure is isomorphously substituted by one or more elements X, as well as to a zeolitic material having a framework structure comprising YO2, Y standing for one or more tetravalent elements, wherein at least a portion of Y comprised in the framework structure is isomorphously substituted by one or more elements X, wherein the zeolitic material displays a specific X-ray powder diffraction pattern, and to its use.

公开(公告)号：US09636668B2

公开(公告)日：2017-05-02

申请号：US14076651

申请日：2013-11-11

Applicant: BASF SE

Inventor： Manuela Gaab ,  Ulrich Müller ,  Milan Kostur ,  Kirsten Spannhoff ,  Kerem Bay ,  Andrei-Nicolae Parvulescu

IPC: B01J29/40 ,  B01J37/02 ,  B01J29/70 ,  B01J23/02 ,  B01J37/00 ,  C07C1/20

CPC classification number: B01J29/7038 ,  B01J23/02 ,  B01J29/40 ,  B01J29/7034 ,  B01J37/0009 ,  B01J37/0201 ,  C07C1/20 ,  C07C2523/02 ,  C07C2529/035 ,  C07C2529/40 ,  C07C2529/70 ,  Y02P20/52 ,  C07C11/06 ,  C07C11/08

Abstract: Described is a process for the production of a zeolitic material having an MFI, MEL, and/or MWW-type framework structure comprising YO2 and X2O3. The process comprises (1) preparing a mixture comprising one or more sources for YO2, one or more sources for X2O3, and one or more solvents; (2) crystallizing the mixture obtained in step (1) to obtain a zeolitic material having an MFI, MEL and/or MWW-type framework structure; and (3) impregnating the zeolitic material obtained in step (2) with one or more elements selected from the group of alkaline earth metals. Y is a tetravalent element, and X is a trivalent element. The mixture crystallized in step (2) contains 3 wt.-% or less of one or more elements M based on 100 wt-% of YO2, wherein M stands for sodium.

公开(公告)号：US20140142361A1

公开(公告)日：2014-05-22

申请号：US14076723

申请日：2013-11-11

Applicant: BASF SE

Inventor： Manuela Gaab ,  Ulrich Müller ,  Milan Kostur ,  Kirsten Spannhoff ,  Kerem Bay ,  Andrei-Nicolae Parvulescu

IPC: C07C1/22

CPC classification number: C07C1/20 ,  C07C2529/40 ,  C07C11/02

Abstract: The present invention relates to a process for the conversion of oxygenates to olefins comprising (i) providing a gas stream comprising one or more oxygenates; and (ii) contacting the gas stream with a catalyst; wherein the catalyst comprises a zeolitic material having an MFI, MEL, and/or MWW-type framework structure comprising YO2 and X2O3, wherein Y is a tetravalent element, and X is a trivalent element, said zeolitic material being obtainable and/or obtained according to a method comprising (1) preparing a mixture comprising one or more sources for YO2, one or more sources for X2O3, and one or more solvents; and (2) crystallizing the mixture obtained in step (1) to obtain a zeolitic material having an MFI, MEL and/or MWW-type framework structure; wherein the mixture crystallized in step (2) contains 3 wt.-% or less of the one or more elements M based on 100 wt.-% of YO2, wherein M stands for sodium.

Abstract translation: 本发明涉及一种将含氧化合物转化为烯烃的方法，包括（i）提供包含一种或多种含氧化合物的气流; 和（ii）使气流与催化剂接触; 其中所述催化剂包含具有包含YO 2和X 2 O 3的MFI，MEL和/或MWW型骨架结构的沸石材料，其中Y是四价元素，X是三价元素，所述沸石材料可根据 涉及一种方法，包括（1）制备包含一种或多种YO源的混合物，一种或多种X 2 O 3源和一种或多种溶剂的混合物; 和（2）使步骤（1）中获得的混合物结晶，得到具有MFI，MEL和/或MWW型骨架结构的沸石材料; 其中在步骤（2）中结晶的混合物含有基于100重量％的YO 2的一种或多种元素M的3重量％或更少，其中M代表钠。

公开(公告)号：US10213773B2

公开(公告)日：2019-02-26

申请号：US15183506

申请日：2016-06-15

Applicant: BASF SE

Inventor： Kirsten Spannhoff ,  Florina Corina Patcas ,  Ekkehard Schwab ,  Alexander Weck ,  Kerem Bay

IPC: C07C1/20 ,  B01J29/40 ,  B01J29/70 ,  C07C1/22 ,  B01J38/04 ,  B01J38/02 ,  B01J23/02 ,  B01J23/10 ,  B01J29/80 ,  B01J29/90 ,  B01J35/04 ,  B01J37/02 ,  B01J19/24 ,  B01J37/08

Abstract: The present invention relates to a process for converting oxygenates to olefins, comprising (1) providing a gas stream comprising one or more ethers; (2) contacting the gas stream provided in (1) with a catalyst, the catalyst comprising a support substrate and a layer applied to the substrate, the layer comprising one or more zeolites of the MFI, MEL and/or MWW structure type.