COMPOSITIONS, COMPRISING PLATELET-SHAPED TRANSITION METAL PARTICLES

    公开(公告)号:US20240287281A1

    公开(公告)日:2024-08-29

    申请号:US18559811

    申请日:2022-05-11

    Applicant: BASF SE

    Abstract: The present invention relates to compositions, comprising



    (A) platelet-shaped transition metal particles, wherein the number mean diameter of the platelet-shaped transition metal particles, present in the composition, is in the range of from 15 nm to 1000 nm, the transition metal is selected from silver, copper, gold and palladium, especially silver and copper, very especially silver;
    (B) one, or more reactive diluents (B);
    (C) one, or more oligomers (C);
    (D) one, or more photoinitiators (D);
    (E) at least a surfactant (E), which is a block copolymer, comprising at least a block A and a block B, wherein
    a) the block A comprises
    a1) monomer units (A1) derived from a compound selected from alkyl (meth)acrylates, alkyl (meth)acrylamides, or any mixture thereof, and
    a2) monomer units (A2) derived from a hydroxy group, or ether group containing alkyl (meth)acrylate;
    b) the block B comprises monomer units (B) derived from a compound selected from fluorinated (meth)acrylic esters of formula






    H2C═CR46(C(O)ORF-1)  (XX), wherein



    R46 is H, or a methyl group; and
    RF-1 is an organic residue containing a perfluorinated alkyl group;
    (F) optionally one, or more polymeric binders;
    (F) optionally one, or more solvents; and
    (H) optionally further additives.




    The coatings, obtained with said compositions, show one color, when observed in transmission and another color, when observed in reflection on both sides of the cured coating.

    FLUORINATED ACRYLATE BLOCK COPOLYMERS WITH LOW DYNAMIC SURFACE TENSION
    7.
    发明申请
    FLUORINATED ACRYLATE BLOCK COPOLYMERS WITH LOW DYNAMIC SURFACE TENSION 审中-公开
    具有低动态表面张力的氟化丙烯酸酯嵌段共聚物

    公开(公告)号:US20170009096A1

    公开(公告)日:2017-01-12

    申请号:US15210748

    申请日:2016-07-14

    Applicant: BASF SE

    Abstract: The present invention relates to a composition, comprising a binder resin, a block copolymer which comprises at least a block A and a block B, wherein the block A comprises monomer units derived from a compound selected from (meth)acrylic acid, a (meth)acrylic acid ester, a (meth)acrylamide, a vinyl aromatic compound, or any mixture thereof, the block B comprises monomer units derived from a compound selected from a fluorinated (meth)acrylic ester having the following formula (I): H2C═C(R1)(C(O)ORF−1)  (I) wherein R1 is H or methyl; and RF−1 is an organic residue containing a perfluorinated C4-6 alkyl group, a fluorinated alpha-olefin having the following formula (II): H2C═CH(RF−2)  (II) wherein RF−2 is an organic residue containing a perfluorinated C4-6 alkyl group, i.e., —(CF2)3-5—CF3 or any mixture thereof.

    Abstract translation: 本发明涉及包含粘合剂树脂,至少包含嵌段A和嵌段B的嵌段共聚物的组合物,其中嵌段A包含衍生自选自(甲基)丙烯酸,(甲基)丙烯酸, )丙烯酸酯,(甲基)丙烯酰胺,乙烯基芳族化合物或其任何混合物,嵌段B包含衍生自选自具有下式(I)的氟化(甲基)丙烯酸酯的化合物的单体单元:H 2 C = C(R 1)(C(O)ORF-1),其中R 1为H或甲基; 并且RF-1是含有全氟化C 4-6烷基的有机残基,具有下式(II)的氟化α-烯烃:H 2 C = CH(RF-2)(II)其中RF-2是含有 全氟化C 4-6烷基,即 - (CF 2)3-5-CF 3或其任何混合物。

    POLYACRYLATE POLYMER
    8.
    发明申请

    公开(公告)号:US20220064348A1

    公开(公告)日:2022-03-03

    申请号:US17415948

    申请日:2019-12-18

    Applicant: BASF SE

    Abstract: The present invention relates to a polymer comprising a polyacrylate homo- or co-polymer backbone incorporating at least one benzylic derivative which is covalently bonded to at least one end of the homo- or co-polymer backbone and its use as a flow and levelling agent, additive, dispersant etc.

    BLOCK COPOLYMERS HAVING A POLYDIMETHYLSILOXANE BLOCK
    10.
    发明申请
    BLOCK COPOLYMERS HAVING A POLYDIMETHYLSILOXANE BLOCK 审中-公开
    具有聚二硅氧烷嵌段的嵌段共聚物

    公开(公告)号:US20150337086A1

    公开(公告)日:2015-11-26

    申请号:US14759821

    申请日:2014-01-17

    Applicant: BASF SE

    Abstract: The present invention relates to novel block copolymers of general formula (I). The invention further relates to a method for producing such block copolymers and to the use of such block copolymers, particularly as additives in liquid coating-agent compositions. A{X—[O—C(O)NH—Y—NH—C(O)—O-M-B]k}n (I). In formula (I), the variables have the following meanings: n is a number in the range from 1 to 40 or 2 to 40, particularly 1 to 10 or 2 to 10 and especially 2 to 5; k is 1 or 2; A is a poly(dimethylsiloxane) block; B is a polymer block constructed of ethylenically unsaturated monomers, which optionally comprises a terminal group different from hydrogen; X is a bivalent or trivalent group having 2 to 20 C atoms, which is saturated or unsaturated and which optionally bears 1, 2, 3, or 4 substituents selected from among OH, COOH, CONH2, C1-C4 alkoxy, C1-C4 alkoxycarbonyl, and halogen; Y is a bivalent hydrocarbon group having 2 to 20 C atoms, which is saturated or unsaturated, and M is a chemical bond or C2-C10 alkylene, which can be interrupted by one or two groups not directly adjacent, selected from among O, C(═O)O, and (C═O)NH and which optionally bears 1, 2, 3, or 4 substituents selected from among OH, COOH, CONH2, C1-C4 alkoxy, C1-C4 alkoxycarbonyl, and phenyl.

    Abstract translation: 本发明涉及通式(I)的新型嵌段共聚物。 本发明进一步涉及这种嵌段共聚物的制备方法以及这种嵌段共聚物的使用,特别是作为液体涂料剂组合物中的添加剂。 A {X- [O-C(O)NH-Y-NH-C(O)-O-M-B] k} n(I)。 在式(I)中,变量具有以下含义:n是1至40或2至40,特别是1至10或2至10,特别是2至5的数字; k为1或2; A是聚(二甲基硅氧烷)嵌段; B是由烯属不饱和单体构成的聚合物嵌段,其任选地包含不同于氢的端基; X是具有2至20个C原子的二价或三价基团,其是饱和或不饱和的,并且任选地具有1,2,3或4个选自OH,COOH,CONH 2,C 1 -C 4烷氧基,C 1 -C 4烷氧基羰基 ,和卤素; Y是具有2至20个C原子的二价烃基,其为饱和或不饱和的,M为化学键或C2-C10亚烷基,其可被不直接相邻的一个或两个基团中断,选自O,C (= O)O和(C = O)NH,并且其任选地带有1,2,3或4个选自OH,COOH,CONH 2,C 1 -C 4烷氧基,C 1 -C 4烷氧基羰基和苯基的取代基。

Patent Agency Ranking