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    METHODS FOR PRODUCING TRANSPARENT, THERMOPLASTIC POLYURETHANE HAVING HIGH MECHANICAL STRENGTH AND HARDNESS
    1.
    发明申请
    METHODS FOR PRODUCING TRANSPARENT, THERMOPLASTIC POLYURETHANE HAVING HIGH MECHANICAL STRENGTH AND HARDNESS 审中-公开
    具有高机械强度和硬度的透明，热塑性聚氨酯的生产方法

    公开(公告)号：US20160304659A1

    公开(公告)日：2016-10-20

    申请号：US15034116

    申请日：2014-10-28

    Applicant: BASF SE

    Inventor： Frank PRISSOK ,  Sebastian HARTWIG ,  Stefan BOKERN ,  Julia LIESE

    IPC: C08G18/48 ,  C08G18/40 ,  C08G18/75

    CPC classification number: C08G18/4879 ,  C08G18/0895 ,  C08G18/227 ,  C08G18/244 ,  C08G18/4018 ,  C08G18/4808 ,  C08G18/4816 ,  C08G18/4829 ,  C08G18/6674 ,  C08G18/758 ,  C09D175/04

    Abstract: The present invention relates to thermoplastic polyurethanes obtainable or obtained by reaction of at least one aliphatic polyisocyanate; at least one chain extender; and at least one polyol composition, where the polyol composition comprises a polyol selected from the group consisting of polyetherols and at least one bisphenol derivative selected from the group consisting of bisphenol A derivatives with a molecular weight Mw>315 g/mol and bisphenol S derivatives with a molecular weight Mw>315 g/mol, where at least one of the OH groups of the bisphenol derivative is alkoxylated, and to processes for producing such thermoplastic polyurethanes and to the use of a thermoplastic polyurethane according to the invention for producing extrusion products, films and moldings.

    Abstract translation: 本发明涉及通过至少一种脂族多异氰酸酯反应获得或获得的热塑性聚氨酯; 至少一种扩链剂; 和至少一种多元醇组合物，其中所述多元醇组合物包含选自聚醚酯和选自分子量Mw> 315g / mol的双酚A衍生物和双酚S衍生物的至少一种双酚衍生物的多元醇 分子量Mw> 315g / mol，其中双酚衍生物的OH基团中的至少一个是烷氧基化的，以及用于制备这种热塑性聚氨酯的方法以及根据本发明的用于生产挤出产品的热塑性聚氨酯的用途 ，电影和模具。

    THERMOPLASTIC OPEN-CELL FLEXIBLE POLYURETHANE FOAM
    2.
    发明申请
    THERMOPLASTIC OPEN-CELL FLEXIBLE POLYURETHANE FOAM 有权

    公开(公告)号：US20250002636A1

    公开(公告)日：2025-01-02

    申请号：US18709551

    申请日：2022-12-12

    Applicant: BASF SE

    Inventor： Waldemar SDRUJKOWSKI ,  Stefan BOKERN ,  Iran OTERO MARTINEZ ,  Elmar POESELT

    IPC: C08G18/66 ,  C08G18/10 ,  C08G18/32 ,  C08G18/48 ,  C08J11/06 ,  C08L75/08

    Abstract: Disclosed herein is a method for producing a thermoplastic molded polyurethane flexible foam having a foam density of 15 to 100 g/dm3 including mixing of (a) Diisocyanate, (b) Polyol (c) 3 to 20 wt.-% based on the total weight of components a) to c), of one or more chain extenders, (d) optionally catalyst and (e) optionally fillers and/or polyurethane additives, mixing the reaction mixture with a gas to form a pre-foam having a density of 110 to 800 g/dm3 injecting the pre-foam into a mold, applying vacuum to the mold to further expand the pre-foam and curing the expanded pre-foam. Further disclosed herein are a thermoplastic flexible polyurethane foam, obtained from the method, a composite including the thermoplastic flexible polyurethane foam and a method of recycling the composite.

    CAPROLACTAM-MODIFIED LIQUID MDI AND ITS USE IN POLYURETHANES
    4.
    发明公开
    CAPROLACTAM-MODIFIED LIQUID MDI AND ITS USE IN POLYURETHANES 审中-公开

    公开(公告)号：US20230287166A1

    公开(公告)日：2023-09-14

    申请号：US18019255

    申请日：2021-08-06

    Applicant: BASF SE

    Inventor： Stefan BOKERN ,  Dong LIANG ,  Martin HUFNAGEL ,  Xiao Yu SUN

    IPC: C08G18/28

    CPC classification number: C08G18/2855 ,  C08G2101/00

    Abstract: The present invention is directed to a liquid, storage stable isocyanate composition (Q) comprising monomeric diphenyl methane diisocyanate (MDI) as component (q1) and an amide with a molecular weight of less than 200 g/mol as component (q2) in an amount of 0.1 to 5 wt.-% based on the sum of the weight of components (q1) and (q2) which adds up to 100 wt.-%, wherein the NCO-content is in the range of from 29.5 to 40.0 wt.-% based on the total weight of the respective isocyanate composition (Q). The present invention is also directed to a process for the manufacture of said liquid, storage stable isocyanate composition (Q) as well as the use of an amide with a molecular weight of less than 200 g/mol for the liquification of at room temperature solid isocyanates. Further, the present invention is directed to the use of an isocyanate composition (Q) of the invention for the synthesis of polyurethane foams, compact polyurethane elastomers or thermoplastic polyurethanes.

    POLYURETHANE-POLYISOCYANURATE COMPOUND COMPRISING OUTSTANDING MECHANICAL PROPERTIES
    5.
    发明申请
    POLYURETHANE-POLYISOCYANURATE COMPOUND COMPRISING OUTSTANDING MECHANICAL PROPERTIES 审中-公开

    公开(公告)号：US20180148536A1

    公开(公告)日：2018-05-31

    申请号：US15576135

    申请日：2016-05-18

    Applicant: BASF SE

    Inventor： Julia Goeschel ,  Stefan BOKERN ,  Ragnar Stoll

    IPC: C08G18/66 ,  C08G18/10 ,  C08G18/76 ,  C08G18/48 ,  C08G18/32 ,  C08G18/58 ,  C08G18/40

    Abstract: Polyurethane-polyisocyanurate compounds and processes for preparing polyurethane-polyisocyanurate compounds are disclosed herein. A process includes mixing component (a) polyisocyanate with component (b) a mixture obtainable by introducing an alkali metal or alkaline earth metal salt into a compound R—NH—CO—R′ containing urethane groups, where R is not hydrogen and is not COR″, component (c) compounds containing one or more epoxide groups, component (d) one or more compounds having at least two isocyanate-reactive groups, comprising compounds having NH2 and/or primary OH groups, and component (e) optionally fillers and other additives, to form a reaction mixture, and reacting said reaction mixture to form the polyurethane-polyisocyanurate compound, wherein the molar amount of alkali metal and/or alkaline earth metal ions in the reaction mixture per mole of urethane group in component (b) is 0.0001 to 3.5 and the isocyanate index is greater than 150. Use of polyurethane-polyisocyanate compounds for producing vehicle parts is also disclosed.

    LOW-EMISSION, STABILIZED POLYURETHANE
    6.
    发明申请
    LOW-EMISSION, STABILIZED POLYURETHANE 审中-公开
    低排放，稳定的聚氨酯

    公开(公告)号：US20160137814A1

    公开(公告)日：2016-05-19

    申请号：US14899923

    申请日：2014-06-10

    Applicant: BASF SE

    Inventor： Iran OTERO MARTINEZ ,  Stefan BOKERN

    IPC: C08K5/3435 ,  C08K5/101

    CPC classification number: C08K5/3435 ,  C08G18/288 ,  C08G18/2885 ,  C08G18/3885 ,  C08G18/5084 ,  C08G2290/00 ,  C08K5/101

    Abstract: The present invention relates to a process for preparing polyurethanes, in which (a) polyisocyanate, (b) polymeric compounds with groups that are reactive towards isocyanates, (c) catalysts, (d) 0.01 to 1% by weight of an aliphatic hydrocarbon (d1) having 2 to 15 carbon atoms which comprise at least one heteroatom selected from the group consisting of oxygen, nitrogen and sulfur, and at least one chlorine or bromine atom, and/or phosphoric acid ester (d2), (e) antioxidants and/or light stabilizers and optionally (f) blowing agents, (g) chain extenders and/or crosslinking agents and (h) auxiliaries and/or additives are mixed to give a reaction mixture and the reaction mixture is allowed to fully react to give the polyurethane, where the phosphoric acid ester corresponds to the general formula (R1—O)3—P═O, where the three radicals R1, independently of one another, are organic radicals which comprise one or more phenyl groups, one or more phosphoric acid groups (polyalkyl phosphate with ethylene oxide) or esters thereof and/or one or more atoms selected from the group consisting of nitrogen, oxygen, fluorine, chlorine and bromine. Furthermore, the present invention relates to polyurethanes obtainable by a process according to the invention and to the use of these polyurethanes in the interior of means of transport.

    Abstract translation: 本发明涉及一种制备聚氨酯的方法，其中（a）多异氰酸酯，（b）具有对异氰酸酯具有反应性的基团的聚合物，（c）催化剂，（d）0.01至1重量％的脂族烃（ d1）具有2至15个碳原子，其包含至少一个选自氧，氮和硫的杂原子，以及至少一个氯或溴原子，和/或磷酸酯（d2），（e）抗氧化剂和 /或光稳定剂和任选的（f）发泡剂，（g）增链剂和/或交联剂和（h）助剂和/或添加剂混合以产生反应混合物，并使反应混合物充分反应，得到 聚氨酯，其中磷酸酯对应于通式（R1-O）3-P = O，其中三个基团R1彼此独立地是包含一个或多个苯基的有机基团，一个或多个磷酸 基团（聚烷基磷酸酯 与环氧乙烷）或其酯和/或一种或多种选自氮，氧，氟，氯和溴的原子。 此外，本发明涉及通过根据本发明的方法获得的聚氨酯和这些聚氨酯在运输工具内部的用途。

    PROCESS FOR THE PREPARATION OF AN ASPHALT MIX COMPOSITION
    8.
    发明申请
    PROCESS FOR THE PREPARATION OF AN ASPHALT MIX COMPOSITION 有权

    公开(公告)号：US20220340757A1

    公开(公告)日：2022-10-27

    申请号：US17760796

    申请日：2020-09-17

    Applicant: BASF SE

    Inventor： Waldemar SCHATZ ,  Iran OTERO MARTINEZ ,  Michael ZEILINGER ,  Bernie Lewis MALONSON ,  Dag WIEBELHAUS ,  Karl R. GUST ,  Stefan BOKERN ,  Olivier FLEISCHEL

    IPC: C08L85/00 ,  E01C7/22 ,  E01C7/26

    Abstract: The present invention relates to a process for the preparation of an asphalt mix composition, said process comprising: (1) providing an asphalt composition and heating said composition to a temperature in the range of from 110 to 200° C.; (2) providing a granular material and heating said material to a temperature in the range of from 110 to 240° C.; (3) providing one or more thermosetting reactive compounds; (4) adding the one or more thermosetting reactive compounds provided in (3) to the asphalt composition obtained in (1) and homogenizing the mixture for a duration in the range of from 2 to 180 s; (5) adding the mixture obtained in (4) to the granular material obtained in (2) and homogenizing the slurry for a duration in the range of from 5 to 180 s. Further, the present invention relates to an asphalt mix composition obtained or obtainable by said process and its use.

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