摘要:
A micro-spherical iron-based catalyst and a preparation method thereof are disclosed. The catalyst contains a potassium promoter, and at least one transitional metal promoter M which is one or more kinds of metals selected from Cr, Cu, Mn and Zn. It also contains a structure promoter S, which is SiO2 and/or Al2O3, wherein both of SiO2 and Al2O3 are modified by MoO3, TiO2 and/or ZrO2. The weight ratio of components is Fe:M:K:S=100:3-50:1-8:3-50, in which the metal components are calculated based on metal elements, the structure promoter is calculated based on oxides. The catalyst is prepared by co-precipitation method.
摘要翻译:公开了一种微球铁基催化剂及其制备方法。 催化剂含有钾促进剂和至少一种过渡金属促进剂M,它是选自Cr,Cu,Mn和Zn中的一种或多种金属。 它还含有SiO 2和/或Al 2 O 3的结构促进剂S,其中SiO 2和Al 2 O 3都被MoO 3,TiO 2和/或ZrO 2改性。 组分的重量比为Fe:M:K:S = 100:3-50:1-8:3-50,其中金属成分基于金属元素计算,结构促进剂基于氧化物计算。 催化剂通过共沉淀法制备。
摘要:
This invention relates to a Fe-based catalyst for Fischer-Tropsch synthesis, preparation method and application thereof. The catalyst contains Fe, oxide(s) of IB group metal Cu and/or Ag as a reducing promoter, IA group metal Li, Na, K or Rb as an electron promoter, VIII group noble metal Ru, Rh, Pd or Pt as a hydrogenation promoter and SiO2 as a structure promoter. The preparation method comprises the following steps: preparing a solution of Fe salt; co-precipitating the solution rapidly with an alkaline compound, then washing and pulping again; and adding a solution of IB group metal salt as a reducing promoter, a IA group metal salt solution and silica sol, or adding a solution of IB group metal salt as a reducing promoter and a silicate of IA group metal; then molding by spray-drying, impregnating in a solution of VIII group noble metal salt, and drying and roasting to obtain the catalyst. The catalyst is suitable for producing hydrocarbons by a low temperature Fischer-Tropsch synthesis process. The process has a high yield of heavy hydrocarbons and a low selectivity to methane and significantly reduces the selectivity to olefins.
摘要:
A micro-spherical iron-based catalyst and a preparation method thereof are disclosed. The catalyst contains a potassium promoter, and at least one transitional metal promoter M which is one or more kinds of metals selected from Cr, Cu, Mn and Zn. It also contains a structure promoter S, which is SiO2 and/or Al2O3, wherein both of SiO2 and Al2O3 are modified by MoO3, TiO2 and/or ZrO2. The weight ratio of components is Fe:M:K:S=100:3-50:1-8:3-50, in which the metal components are calculated based on metal elements, the structure promoter is calculated based on oxides. The catalyst is prepared by co-precipitation method.
摘要翻译:公开了一种微球铁基催化剂及其制备方法。 催化剂含有钾促进剂和至少一种过渡金属促进剂M,它是选自Cr,Cu,Mn和Zn中的一种或多种金属。 它还含有SiO 2和/或Al 2 O 3的结构促进剂S,其中SiO 2和Al 2 O 3都被MoO 3,TiO 2和/或ZrO 2改性。 组分的重量比为Fe:M:K:S = 100:3-50:1-8:3-50,其中金属成分基于金属元素计算,结构促进剂基于氧化物计算。 催化剂通过共沉淀法制备。
摘要:
A method for continuously preparing a metal oxides catalyst comprises the following steps: dissolving metal materials using nitric acid solution to produce a metal nitrate solution, and also to produce NOx and water vapor; hydrolyzing the metal nitrate solution by introducing pressurized superheated water vapor into the metal nitrate solution to obtain a slurry of the hydrates of metal oxides as well as acidic gas, the main components of the acidic gas are NO2, NO, O2 and water vapor; filtrating and drying the slurry to obtain the hydrates of metal oxides and/or metal oxides; and then utilizing the obtained hydrates of metal oxides and/or metal oxides as raw materials and preparing the metal oxides catalyst by the conventional method for preparing a catalyst. The NOx gas produced can be absorbed to produce nitric acid which can be reused. An apparatus used for preparing metal oxides comprises a metal salt solution preparation system, a metal salt solution hydrolysis system, a product preparation system and a nitric acid preparation and recycling use system. The method and the apparatus can achieve continuous production, enclosed circulation and zero release in the whole process and can reduce the cost of production.
摘要:
A method for continuously preparing a metal oxides catalyst comprises the following steps: dissolving metal materials using nitric acid solution to produce a metal nitrate solution, and also to produce NOx and water vapor; hydrolyzing the metal nitrate solution by introducing pressurized superheated water vapor into the metal nitrate solution to obtain a slurry of the hydrates of metal oxides as well as acidic gas, the main components of the acidic gas are NO2, NO, O2 and water vapor; filtrating and drying the slurry to obtain the hydrates of metal oxides and/or metal oxides; and then utilizing the obtained hydrates of metal oxides and/or metal oxides as raw materials and preparing the metal oxides catalyst by the conventional method for preparing a catalyst. The NOx gas produced can be absorbed to produce nitric acid which can be reused. An apparatus used for preparing metal oxides comprises a metal salt solution preparation system, a metal salt solution hydrolysis system, a product preparation system and a nitric acid preparation and recycling use system. The method and the apparatus can achieve continuous production, enclosed circulation and zero release in the whole process and can reduce the cost of production.
摘要:
A micro-spherical Fe-based catalyst for a slurry bed Fischer-Tropsch synthesis (FTS) comprises Fe as its active component, a transitional metal promoter M, a structure promoter S and a K promoter. The transitional metal promoter M is one or more selected from the group consisting of Mn, Cr and Zn, and the structure promoter S is SiO2 and/or Al2O3. The weight ratio of the catalyst components is Fe: transitional metal promoter: structure promoter: K=100:1-50:1-50:0.5-10. Preparation method of the catalyst comprises: adding the structure promoter S into a mixed solution of Fe/M nitrates, then co-precipitating with ammonia water to produce a slurry, filtering and washing the slurry to produce a filter cake, adding the required amount of the K promoter and water to the filter cake, pulping and spray drying, and roasting to produce the micro-spherical Fe-based catalyst for the slurry bed Fischer-Tropsch synthesis. The catalyst has good abrasion resistance and narrow particle size distribution, furthermore, it has high conversion capability of synthesis gas, good product selectivity and high space time yield, and the catalyst also can be used for the slurry bed Fischer-Tropsch synthesis in a wide temperature range.
摘要:
A method for determining parameters of a wind turbine is disclosed. The method may generally include receiving signals from at least one Micro Inertial Measurement Unit (MIMU) mounted on or within a component of the wind turbine and determining at least one parameter of the wind turbine based on the signals received from the at least one MIMU.
摘要:
A Policy and Charging Rules Function, a PCRF (120), for use with a Policy and Charging Enforcement Function, a PCEF (135), over a Gx interface, and arranged to communicate with an Application Function, an AF (110), over an Rx interface. The PCRF (120) is arranged to receive a request from the AF (110) regarding Access Network Charging Correlation Information for the AF, and if such a request is received from the AF, the PCRF (120) checks if the Access Network Charging Correlation Information is known to the PCRF, in which case the PCRF (120) provides the information to the AF (110), and if the Access Network Charging Correlation Information is not known to the PCRF (120), it subscribes to the Access Network Charging Correlation Information from the PCEF (135) and to supply the Access Network Charging Correlation Information to the AF (110) after reception from the PCEF (135).
摘要:
A biaxial linear-motion micro drive apparatus includes: a mounting base A on an upper surface of a Z-direction sliding base; a Z-direction micro actuator fixed within the mounting base A and connected with a Z-direction micro-motion platform connected with an X-direction sliding base; Z-direction guide rail strips arranged on the Z-direction sliding; two Z-direction guide rail blocks provided on one Z-direction guide rail strip fixedly mounted on a lower surface of the X-direction sliding base; a mounting base B provided on an upper surface of the X-direction sliding base; an X-direction micro actuator in the mounting base B and connected with an X-direction micro-motion platform connected with an XZ biaxial motion platform; two X-direction guide rail strips arranged on the upper surface of the X-direction sliding base; two X-direction guide rail blocks provided on each X-direction guide rail strip mounted on a lower surface of the XZ biaxial motion platform.
摘要:
Method for a switching unit (MSC_I) in a network in which a user equipment is being adapted to be attached and connected to a 2G/3G network for performing circuit switched, CS, communication with the network, or being adapted to be attached to a LTE network, for performing packet switched, PS, communication, wherein the PS communication is adapted to be performed via a mobility management entity, MME, which may be arranged in a pool of MME's, the user equipment being adapted to receive page signals so as to inform the user of incoming calls, the switching unit (MSC_I) being adapted for issuing page signals to MME nodes, receiving an incoming external CS call; performing detection of a first selected MME, as to whether the first selected MME is ready or not; if detecting a not ready state concerning the selected MME (MME_I1), selecting an alternative MME and issuing a page message.