摘要:
A field effect transistor in which a continuous semiconductor layer comprises: a) an organic semiconductor; and, b) an organic binder which has an inherent conductivity of less than 10−6Scm−1 and a permittivity at 1,000 Hz of less than 3.3 and a process for its production comprising: coating a substrate with a liquid layer which comprises the organic semiconductor and a material capable of reacting to form the binder; and, converting the liquid layer to a solid layer comprising the semiconductor and the binder by reacting the material to form the binder.
摘要:
This invention relates to organic light emitting diodes (OLEDs) and to methods for their manufacture. The invention provides an OLED element or display which enables contrast to be produced in an image. In accordance with the invention a layer of ink is patterned as a blocking layer between two OLED layers. The ink reduces or prevents conduction, i.e. movement of charge, between the two OLED layers in that area of the device. The ink may be dark in color, e.g. black, to increase the contrast ratio of the OLED. The blocking layer is provided between any two layers in the OLED and blocks the charge movement in these areas. The blocking layer may comprise a multiplicity of ink dots, the density of which determines the extent to which conduction is hindered. The blocking layer may be produced as a “grey-scale” pattern wherein the density of dots is varied across the pattern.
摘要:
A method for forming an organic electronic device, which method comprises the steps of: a) forming a negative image of a desired pattern on a substrate or device layer with a lift-off ink; b) coating a first device layer to be patterned on top of the negative image; c) coating one or more further device layers to be patterned on top of the first device layer to be patterned; and d) removing the lift-off ink and unwanted portions of the device layers above it, thereby leaving the desired pattern of device layers. The method allows the formation of a device structure wherein the device layers to be patterned are self-aligned. The method enables a multiplicity of layers to be patterned in a single set of printing and lift-off steps using one pattern which ensures the excellent vertical alignment of edges, which would be difficult to achieve by direct printing. Horizontal alignment can also be achieved. The size of the device features can be reduced below the actual printing resolution. Examples of organic electronic devices include OFETs, OLEDs, memory, sensing elements, solar cells, photo-sensors, photoreceptors for electrophotography and the like.
摘要:
A process for preparing a modified particulate solid comprising reacting a dispersant with a compound in the presence of a particulate solid and a liquid medium, characterised in that: a) the dispersant has at least one reactable group selected from keto, aldehyde and beta-diketoester groups, b) the compound has at least two groups reactive towards said keto, aldehyde and/or beta-diketoester groups. The process provides a modified particulate solid having improved stability which is particularly useful for liquid vehicles having and range of polarities and for incorporation into ink jet printing inks.
摘要:
A temperature recorder comprises a sensing cell which comprises a reactant mixture. The reactant mixture comprises a liquid crystalline material, a reactive monomer, and an initiator configured to initiate cross-linking of the reactive monomer and thereby form a sensing material which provides a record of the temperature of the sensing cell when cross-linking occurs. The sensing material comprises a cross-linked network dispersed within the liquid crystalline material, the cross-linked network being formed from the reactive monomer. The sensing cell additionally comprises first and second electrically conductive electrodes having a spaced relationship there between and being connectable to an electric property measuring device arranged to measure an electric property of the sensing material.
摘要:
A process for preparing a patterned, cross-linked, acrylic-polymer, film coating on a substrate; the process comprising the steps of: a) applying to the substrate by an ink-jet printing process a mixture comprising: i) one or more cross-linkable, thermally ink-jettable, water-dissipatable, precursor(s) for one or more cross-linked acrylic-polymer(s); ii) one or more cross-linker(s) capable of cross-linking the precursor(s) for the acrylic-polymer(s); and iii) one or more colorant(s); and b) thereafter curing the mixture in situ to form the patterned, cross-linked, acrylic-polymer, film coating on the substrate. Preferably the substrate is a color filter suitable for use in an LCD display and the mixture is applied in a single pass. The precursor may itself comprise polymers, e.g. acrylic polymers. Ink for use in this process and substrates printed by this process are also described.
摘要:
An ink-jet printing process comprising the steps (a) and (b) in any order or simultaneously: (a) applying an ink to a substrate by means of an ink-jet printer to form an image on a substrate; and (b) applying to the substrate a fixing composition comprising a liquid medium and a polymer containing a plurality of monoguanide and/or biguanide groups by means of an ink jet printer; characterised in that in the fixing composition has a chloride concentration less than 400 ppm by weight.
摘要:
A polymeric material comprising at least first and second polymer parts, which first part has a number average molecular weight higher than that of the second part and which first and second polymer parts each comprise a respective polymer part derived from at least one ethylenically unsaturated monomer, is prepared by a process which comprises the steps of (1) preparing, by aqueous suspension polymerisation the first, higher molecular weight polymer part in the presence of a free radical initiator, but in the absence of a chain transfer agent to form a suspension of the first, higher molecular weight part and thereafter (2) preparing by aqueous suspension polymerisation the second, lower molecular weight part, which preparation step (2) is carried out in the presence of the suspension of the first, higher molecular weight part, a free radical initiator and a catalytic chain transfer agent (CCTA). Step (2) may be continued to provide, additionally, a third polymer of a molecular weight intermediate that of the first and second polymers. A polymeric material thus obtainable has a PDi of at least 5 and a skewed molecular weight distribution in which the first-third polymers are present in successively increasing amounts. The polymeric material is especially suitable for use as a binder in a toner composition.
摘要:
A coating composition comprising pigment, medium and a binder characterised in that (i) the binder comprises a cationic polymer comprising a repeat unit of Formula (1): wherein: X and Y are the same or different and represent divalent organic linking groups; and (ii) the weight ratio of pigment to binder in the composition is at least 2:1. The compositions are useful for preparing ink jet recording materials with good water resistance, print quality and dry time.
摘要:
A composition comprising water-dissipatable polyurethane, water, colorant, a water-miscible organic solvent and a water-immiscible organic solvent. The compositions are useful as inks for ink jet printers.