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    Metals tolerant catalytic cracking catalyst, method of manufacture and use thereof
    4.
    发明授权
    Metals tolerant catalytic cracking catalyst, method of manufacture and use thereof 失效
    金属耐受催化裂化催化剂，其制造方法和用途

    公开(公告)号：US4938863A

    公开(公告)日：1990-07-03

    申请号：US206242

    申请日：1988-06-10

    申请人： Thomas F. Degnan ,  Billy K. Huh

    发明人： Thomas F. Degnan ,  Billy K. Huh

    IPC分类号： C10G11/05

    CPC分类号： C10G11/05

    摘要： A catalytic cracking catalyst and process which tolerates high levels of vanadium and coke precursors in the feed is disclosed. A zeolite in an alumina free binder or coating, preferably silica, is used as the cracking catalyst. RE-USY in silica is especially preferred as it has a low affinity for vanadium, low coking characteristics and high stability. Preferably a vanadium getter additive is present as separate particles to act as a vanadium sink. The catalyst and process may be used in fluidized bed catalytic cracking (FCC) or in moving bed catalytic cracking units. A method of making a coated catalyst, by adding a layer of an alumina free material to a core of alumina containing cracking catalyst is also disclosed.

    摘要翻译： 公开了一种催化裂化催化剂和方法，其耐受饲料中高含量的钒和焦炭前体。 使用不含氧化铝的粘合剂或涂层中的沸石，优选二氧化硅作为裂化催化剂。 二氧化硅中的RE-USY是特别优选的，因为它对钒的低亲和力，低焦化特性和高稳定性。 优选地，钒吸附剂添加剂作为单独的颗粒存在以充当钒槽。 催化剂和方法可用于流化床催化裂化（FCC）或移动床催化裂化装置。 还公开了通过向含氧化铝的裂化催化剂的核心添加无氧化铝材料层来制备涂覆的催化剂的方法。

    FCC process with catalyst separation
    5.
    发明授权
    FCC process with catalyst separation 失效
    FCC工艺与催化剂分离

    公开(公告)号：US4895636A

    公开(公告)日：1990-01-23

    申请号：US206240

    申请日：1988-06-10

    申请人： Nai Y. Chen ,  Billy K. Huh ,  Thomas F. Degnan

    发明人： Nai Y. Chen ,  Billy K. Huh ,  Thomas F. Degnan

    IPC分类号： C10G11/18

    CPC分类号： C10G11/18

    摘要： An FCC or fluidized catalytic cracking process and apparatus for converting heavy metals laden crudes is disclosed. The heavy feed, conventional catalyst and an additive or vanadium getter contact the feed in a riser reactor. The additive is segregated from conventional FCC catalyst upstream of the conventional FCC regenerator. An elutriating, upflow riser reactor may be used with a coarse, rapidly settling getter. A fine, slowly settling getter may be used, with getter segregation achieved by using an elutriating cyclone on the riser outlet, an elutriating catalyst stripper, a sieve, or the like. The spent getter may be used once through, regenerated in a separate getter regenerator, or used as a source of fuel. Alumina and sponge coke are preferred getters.

    摘要翻译： 公开了一种FCC或流化催化裂化方法和用于转化重金属负载原油的装置。 重料，常规催化剂和添加剂或钒吸附剂在提升管反应器中接触进料。 该添加剂与常规FCC再生器上游的常规FCC催化剂分离。 淘汰式上升式提升管式反应器可与粗，快速沉降的吸气剂一起使用。 可以使用细的缓慢沉降的吸气剂，通过在提升管出口，淘洗催化剂汽提器，筛子等上使用淘洗旋风来实现吸气剂分离。 废吸气剂可以一次使用，在单独的吸气剂再生器中再生，或用作燃料来源。 氧化铝和海绵焦炭是优选的吸气剂。

    Process for isomerization dewaxing of hydrocarbon streams
    6.
    发明授权
    Process for isomerization dewaxing of hydrocarbon streams 有权
    烃流异构化脱蜡方法

    公开(公告)号：US06652735B2

    公开(公告)日：2003-11-25

    申请号：US09843125

    申请日：2001-04-26

    申请人： Thomas F. Degnan ,  Philip J. Angevine

    发明人： Thomas F. Degnan ,  Philip J. Angevine

    IPC分类号： C10G7338

    CPC分类号： C10G45/62 ,  B01J29/74 ,  B01J29/7415 ,  B01J29/80 ,  B01J2229/20 ,  B01J2229/42 ,  C10G45/64 ,  C10G65/043

    摘要： A process for isomerization dewaxing of a hydrocarbon feed which includes contacting the hydrocarbon feed with a large pore size, small crystal size, crystalline molecular sieve and an intermediate pore size, small crystal size, crystalline molecular sieve to produce a dewaxed product with a reduced pour point and a reduced cloud point. In a preferred embodiment, the feed is contacted with the molecular sieves sequentially, first with the large pore sieve followed by the intermediate pore sieve.

    摘要翻译： 烃原料异构化脱蜡的方法，其包括使烃进料与大孔径，小结晶尺寸，结晶分子筛和中等孔径，小晶体尺寸，结晶分子筛接触以产生具有降低的倾倒的脱蜡产物 点和减少的浊点。 在一个优选的实施方案中，进料与分子筛依次接触，首先用大孔筛，然后是中间孔筛。

    Aromatic alkylation process
    7.
    发明授权
    Aromatic alkylation process 有权
    芳香烷基化工艺

    公开(公告)号：US06313362B1

    公开(公告)日：2001-11-06

    申请号：US09213798

    申请日：1998-12-17

    申请人： John R. Green ,  Thomas F. Degnan ,  Yun-Yang Huang ,  Chaya R. Venkat ,  Ronald A. Weiss

    发明人： John R. Green ,  Thomas F. Degnan ,  Yun-Yang Huang ,  Chaya R. Venkat ,  Ronald A. Weiss

    IPC分类号： C07C264

    CPC分类号： C07C15/085 ,  C07C15/073

    摘要： Akylation product is contacted with a purification medium in a liquid phase pre-reaction step to remove impurities and form a purified stream. The purified stream may then be further processed by liquid phase transalkylation to convert the polyalkylated aromatic compound to a monoalkylated aromatic compound. The process may use a large pore molecular sieve catalyst such as MCM-22 as the purification medium in the pre-reaction step because of its high reactivity for alkylation, strong retention of catalyst poisons and low reactivity for oligomerization under the pre-reactor conditions. Olefins, diolefins, styrene, oxygenated organic compounds, sulfur containing compounds, nitrogen containing compounds and oligomeric compounds are removed.

    摘要翻译： 将Akylation产物在液相预反应步骤中与净化介质接触以除去杂质并形成纯化的物流。 然后可以通过液相烷基转移进一步处理纯化的物流，以将多烷基化芳族化合物转化为单烷基化芳族化合物。 在预反应步骤中，该方法可以使用大孔分子筛催化剂例如MCM-22作为纯化介质，因为其在烷基化反应活性高，催化剂毒物强烈的保留和在反应器前条件下的低聚反应低。 除去烯烃，二烯烃，苯乙烯，含氧有机化合物，含硫化合物，含氮化合物和低聚物。

    Hydrocarbon coversion using improved zeolite Beta catalyst
    8.
    发明授权
    Hydrocarbon coversion using improved zeolite Beta catalyst 失效
    使用改进的沸石β催化剂进行烃转化

    公开(公告)号：US5658454A

    公开(公告)日：1997-08-19

    申请号：US461484

    申请日：1995-06-05

    申请人： Robert P. L. Absil ,  Thomas F. Degnan ,  George H. Hatzikos ,  Jocelyn A. Kowalski ,  Thomas Mebrahtu ,  Grant H. Yokomizo

    发明人： Robert P. L. Absil ,  Thomas F. Degnan ,  George H. Hatzikos ,  Jocelyn A. Kowalski ,  Thomas Mebrahtu ,  Grant H. Yokomizo

    IPC分类号： B01J29/40 ,  B01J29/70 ,  B01J37/00 ,  C10G11/05 ,  C07C4/06 ,  C10G47/04

    CPC分类号： C10G11/05 ,  B01J29/7007 ,  B01J37/0009 ,  B01J2229/26 ,  B01J2229/36 ,  B01J2229/42 ,  B01J29/40 ,  B01J29/7034 ,  B01J29/7042

    摘要： A catalyst composition which comprises a crystalline metallosilicate having the structure of zeolite Beta, phosphor and a matrix that is substantially free of crystalline aluminum phosphate which has improved resistance to steam deactivation which has higher cracking activity than analogous catalysts prepared without phosphorus. The crystalline metallosilicate be used in the as-synthesized form or in the calcined form. included is the method to produce the catalyst composition and methods for the use of catalysts prepared by the present method in organic conversion processes. Specific embodiments of the invention involve various techniques for preparation of catalyst containing phosphorus and crystalline metallosilicates having the structure of zeolite Beta. Catalysts prepared according to the method of this invention are useful for organic compound, e.g., hydrocarbon compound, conversion processes. Organic compound conversion processes include cracking, hydrocracking, and transalkylation, among others.

    摘要翻译： 一种催化剂组合物，其包含具有沸石β，磷光体和基本上不含结晶磷酸铝的结构的结晶金属硅酸盐，其具有改善的对蒸汽失活的抗性，其具有比不用磷制备的类似催化剂更高的裂化活性。 结晶金属硅酸盐以合成形式或煅烧形式使用。 包括制备催化剂组合物的方法和通过本发明方法在有机转化方法中制备的催化剂的使用方法。 本发明的具体实施方案涉及用于制备含有β沸石结构的磷的磷和结晶金属硅酸盐的各种技术。 根据本发明方法制备的催化剂可用于有机化合物，例如烃化合物，转化方法。 有机化合物转化方法包括裂化，加氢裂化和烷基转移等。