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1.发明授权Method of preparing storage-stable aqueous sodium peroxymonsulfate solutions 失效制备储存稳定的过硫酸过氧硫酸钠溶液的方法
公开(公告)号：US5250280A
公开(公告)日：1993-10-05
申请号：US721779
申请日：1991-06-28
CPC分类号： C01B15/085 , C01B15/08
摘要： Previously known peroxymonosulfate solutions exhibit an unsatisfactory storage stability and/or can only be used with technical limitations. According to the invention, storage-stable, aqueous sodium peroxymonosulfate solutions can be prepared with a content of 5% to 50% by weight NaHSO.sub.5 in an economic manner by means of the partial neutralization of a solution containing sulfuric acid and Caro's acid if a such a solution containing H.sub.2 SO.sub.4 and H.sub.2 SO.sub.5 is added which contains less than 3 parts by weight hydrogen peroxide per 100 parts by weight Caro's acid and the partial neutralization is carried out up to an equivalent proportion of total SO.sub.3 to sodium ions in a range of 1 to 1 up to 1 to 1.3 and if the solution is diluted or concentrated as required.
摘要翻译： 以前已知的过一硫酸盐溶液表现出不令人满意的储存稳定性和/或仅可用于技术上的限制。 根据本发明，通过部分中和含硫酸和卡罗酸的溶液，经济的方法可以以5％至50％（重量）的NaHSO 5的含量制备储存稳定的过一硫酸钠溶液。 添加含有H 2 SO 4和H 2 SO 5的溶液，其含有每100重量份Caro酸小于3重量份的过氧化氢，并且部分中和进行到等于1至1范围内的总SO 3与钠离子的当量比例 高达1至1.3，如果溶液根据需要稀释或浓缩。
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2.发明授权
公开(公告)号：US5039643A
公开(公告)日：1991-08-13
申请号：US550746
申请日：1990-07-10
CPC分类号： B01J37/0215 , B01J23/40 , B01J27/24 , C01C3/0229
摘要： A method for the production of catalytically active coatings on shaped articles of aluminum oxide for the production of hydrogen cyanide according to the BMA method. A suspension is used for the coating which suspension contains at least one platinum metal and aluminum in finely divided elementary form in a carrier liquid. According to especially preferred embodiments, the suspension additionally contains glass frits or organic silicon compounds. After the moistening of the shaped article and evaporation of the carrier liquid, the catalyst is formed during heating to 1000.degree. to 1350.degree. C. in the presence of nitrogen and/or ammonia.Essential advantages of the method over the previously known method of coating with solutions of Pt and Al compounds are: the application of different coating thicknesses are possible in a single coating stage, the previously-necessary hydrogenation stage after each impregnation is eliminated and the health risk is reduced.
摘要翻译： 根据BMA方法生产氰化氢的成型制品上的催化活性涂层的方法。 悬浮液用于涂层，该悬浮液在载体液体中含有至少一种细金属元素形式的铂金属和铝。 根据特别优选的实施方案，悬浮液另外含有玻璃料或有机硅化合物。 在成型制品的润湿和载液的蒸发之后，在氮和/或氨的存在下加热至1000℃至1350℃期间形成催化剂。 该方法相对于先前已知的Pt和Al化合物溶液涂布方法的重要优点是：在单一涂层阶段可以应用不同的涂层厚度，每次浸渍后先前必要的氢化步骤被消除，并且健康风险 降低了。
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公开(公告)号：US4328010A
公开(公告)日：1982-05-04
申请号：US174180
申请日：1980-07-31
申请人： Friedrich Bittner , Werner Heimberger , Kurt Henkel , Norbert Kriebitzsch , Martin Petzold , Kurt Puschner
发明人： Friedrich Bittner , Werner Heimberger , Kurt Henkel , Norbert Kriebitzsch , Martin Petzold , Kurt Puschner
摘要： To obtain a cyanogen chloride which is practically free from water and preferably also free from hydrogen cyanide, hydrogen chloride and organic compounds, the crude cyanogen chloride is fractionally distilled. The return is led in countercurrent flow to the crude gas, thereby takes up the impurities and is further evaporated in the lower portion of the column, respectively in a special apparatus, by a liquid whose temperature is higher than the boiling temperature of cyanogen chloride. Thereby this liquid also takes up the impurities. The purification action is aided by a wash for the crude cyanogen chloride connected in series before it enters the fractionating column. It is very advantageous to combine the process with a plant for the production of cyanogen chloride.
摘要翻译： 为了获得实际上不含水的氰氯化物，优选也不含氰化氢，氯化氢和有机化合物，分馏了粗氯化氰。 回流以逆流流向粗气体，从而占据杂质，并在专用设备中通过温度高于氯化氰沸点的液体分别在塔的下部蒸发。 因此，这种液体也会占据杂质。 纯化作用通过在进入分馏塔之前串联连接的氯化氰原料的洗涤来辅助。 将该方法与用于生产氯化氰的设备相结合是非常有利的。
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公开(公告)号：US5039505A
公开(公告)日：1991-08-13
申请号：US510267
申请日：1990-04-19
申请人： Friedrich Bittner , Walter Hinrichs , Lutz Hippe , Ludwig Lange , Erich Splett
发明人： Friedrich Bittner , Walter Hinrichs , Lutz Hippe , Ludwig Lange , Erich Splett
IPC分类号： C01B17/22
CPC分类号： C01B17/22 , C01P2004/60 , C01P2006/80
摘要： A method of preparing sodium monosulfide by means of reacting sodium and sulfur under protective gas, wherein sodium monosulfide is placed in a first stage in a receiver in a finely distributed, solid state, the initial material is preheated to 120.degree.-150.degree. C. and sulfur and sodium are alternately added in the required amount ratio under intensive mixing, whereby the temperature of the reation mixture is maintained at 120.degree.-250.degree. C., and in a second stage the formed initial product is allowed to continue to react or postreact under continuation of the mixing at 250.degree.-480.degree. C., until a Na.sub.2 S content of at least 95% by weight has been attained.
摘要翻译： 通过在保护气体下使钠和硫反应制备单硫化钠的方法，其中单硫化钠以细分散的固体状态放置在接收器中的第一阶段中，将初始材料预热至120℃-150℃。 在浓缩混合下以所需量的比率交替地添加硫和钠，由此将该回收混合物的温度保持在120〜-250℃，在第二阶段使形成的初始产物继续反应或 在250°-480℃的混合下继续反应，直至达到至少95重量％的Na 2 S含量。
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公开(公告)号：US4391988A
公开(公告)日：1983-07-05
申请号：US347476
申请日：1982-02-10
IPC分类号： C07C319/20 , A23K1/16 , C07C67/00 , C07C313/00 , C07C323/58 , C07C149/247
CPC分类号： A23K20/142
摘要： Aqueous sodium methioninate solutions having a low content of sodium carbonate can be recovered from the crude hydrolysis mixture resulting from the saponification of 5-(.beta.-methylmercaptoethyl)-hydantoin with 1.1 to 6 equivalents of sodium hydroxide and/or sodium carbonate by distilling off the water from the crude hydrolysis mixture until the sodium methioninate content is 40 to 65 weight percent, and after cooling to at most room temperature separating off the precipitated sodium carbonate.
摘要翻译： 可从粗制水解混合物中回收由5-（β-甲基巯基乙基） - 乙内酰脲与1.1〜6当量的氢氧化钠和/或碳酸钠的皂化而得到的含碳酸钠含量低的甲酸甲酯水溶液。 来自粗水解混合物的水直到甲硫氨酸钠含量为40至65重量％，并在冷却至至多室温后分离析出的碳酸钠。
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6.发明授权Process for the production of solutions or suspensions of cyanuric chloride in aqueous organic solvents 失效用于生产氰尿酰氯在含水有机溶剂中的溶液或悬浮液的方法
公开(公告)号：US4017413A
公开(公告)日：1977-04-12
申请号：US632952
申请日：1975-11-18
IPC分类号： C07D251/28 , B01F3/08
CPC分类号： C07D251/28
摘要： There is provided a process for the production of a solution or suspension of cyanuric chloride in a water containing organic solvent wherein the liquid cyanuric chloride and the organic-aqueous solvent are mixed together while being agitated, the liquid cyanuric chloride at a temperature between its melting point and 200.degree. C. is led into the flowing organic-aqueous solvent with a velocity of Vcy (in kg per hour) wherein ##EQU1## where P is the desired concentration of cyanuric chloride in the solution or suspension to be produced in weight %, P.sub.LM is the concentration of cyanuric chloride in the solvent used which also includes O,V.sub.lm is the velocity of the solvent added in kg/h,And P.sub.LM, V.sub.LM and T.sub.LM, the temperature of the added solvent, are so selected that the expression ##EQU2## does not exceed the boiling temperature in .degree. C. of the solvent used and wherein C.sub.p (LM) and C.sub.p (Cy) signify the specific heat capacities in cal. x g.sup.-.sup.1 .times. (.degree.degree C).sup.-.sup.1 of the solvent and cyanuric chloride respectively, whereupon in a given case within at most 3 minutes after bringing the cyanuric chloride and solvent into contact the flowing mixture is cooled to the desired storage temperature.
摘要翻译： 提供了一种在含有有机溶剂的水中制备氰尿酰氯的溶液或悬浮液的方法，其中液体氰尿酰氯和有机 - 水溶剂在搅拌下混合在一起，液态氰尿酰氯在其熔融 点和200℃以Vcy速度（以kg /小时计）流入有机 - 水溶剂，其中P是待生成的溶液或悬浮液中所需浓度的氰尿酰氯，其重量％ PLM是所用溶剂中氰尿酰氯的浓度，其还包括O，VLM是以kg / h加入的溶剂的速度，而PLM，VLM和TLM，加入的溶剂的温度如此选择，使得表达式 ＆lt; IMAGE＆gt;不超过使用的溶剂的沸点（℃），其中Cp（LM）和Cp（Cy）表示比热容。 xg <1>（℃C）-1的溶剂和氰尿酰氯，因此在给出的情况下，在将氰尿酰氯和溶剂接触之前的最多3分钟内，将流动的混合物冷却至所需的 储存温度。
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公开(公告)号：US5075098A
公开(公告)日：1991-12-24
申请号：US510269
申请日：1990-04-19
申请人： Friedrich Bittner , Walter Hinrichs , Lutz Hippe , Ludwig Lange , Erich Splett
发明人： Friedrich Bittner , Walter Hinrichs , Lutz Hippe , Ludwig Lange , Erich Splett
IPC分类号： C01B17/22
CPC分类号： C01B17/22 , C01P2004/60 , C01P2006/80
摘要： A method of preparing sodium monosulfide by means of reacting a sodium polysulfide with sodium under protective gas, the sodium polysulfide is placed in a first stage in a finely distributed, solid state in a receiver, preheated to temperatures of 100.degree.-150.degree. C., liquid sodium is gradually added in the required amount to the material in the receiver under intensive mixing, whereby the temperature of the reaction mixture is maintained at 120.degree.-250.degree. C. and in a second stage the formed initial product is allowed to continue to react, or postreact under continuation of the mixing at 250.degree.-480.degree. C., until a Na.sub.2 S content of at least 95% by weight has been attained.
摘要翻译： 通过在保护气体下使多硫化钠与钠反应制备单硫化钠的方法，将多硫化钠置于接收器中以细分散的固态的第一阶段，预热至100-150℃的温度。 在密集混合下，将液态钠逐渐加入接收器中的物质，由此将反应混合物的温度保持在120-250℃，在第二阶段中使形成的初始产物继续 在250-480℃下继续混合反应或反应，直至达到至少95重量％的Na 2 S含量。
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8.发明授权
公开(公告)号：US4640832A
公开(公告)日：1987-02-03
申请号：US772395
申请日：1985-09-04
CPC分类号： C01B17/34 , C01P2006/80
摘要： There is described a process for the production of pure sodium polysulfides directly from the elements sodium and sulfur. For this purpose, the sodium and the sulfur under a protective gas and in a stoichiometrical ratio corresponding to the desired polysulfide are alternatingly dosed into a previously present melt of a polysulfide with vigorous stirring, the dosing being in portions such that upon introduction of the sodium the reaction mixture remains in the condition of a stirrable suspension and upon introduction of the sulfur this is completely reacted to a polysulfide of the desired or higher sulfur content.
摘要翻译： 描述了直接从元素钠和硫生产纯多硫化钠的方法。 为此，将保护气体下的钠和硫与化学计量比对应于所需的多硫化物交替计量到先前存在的多硫化物的熔体中，同时剧烈搅拌，该给药部分使得在引入钠 反应混合物保持在可搅拌悬浮液的状态，并且在引入硫时，其与所需或更高硫含量的多硫化物完全反应。
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9.发明授权
公开(公告)号：US4271298A
公开(公告)日：1981-06-02
申请号：US94875
申请日：1979-11-16
IPC分类号： B01D1/18 , B01F3/08 , B01F3/12 , B01F5/20 , C07D251/28
CPC分类号： C07D251/28 , B01D1/18 , B01F3/08 , B01F3/1214 , B01F5/20
摘要： Suspension or solutions of cyanuric chloride in water are prepared at high mixing velocities and low temperatures with resulting low degree of hydrolysis by introducing liquid cyanuric chloride through a nozzle in the upper portion of the mixing apparatus in countercurrent flow to upwardly flowing water introduced from at least one lower nozzle above a breast shaped constriction in the lower, open portion of the apparatus. In this way the chamber walls are always covered with an unbroken layer of liquid. The process can be carried out at normal, reduced or elevated pressure. At reduced pressure by evaporation of the water there is simultaneously a cooling of the system.
摘要翻译： 在高混合速度和低温下制备氰尿酰氯在水中的悬浮液或溶液，并通过在混合装置的上部引入液态氰尿酰氯通过喷嘴逆流向至少从至少引入的向上流动的水中导致低水解度 在设备的下部，开口部分中的乳房形收缩件上方的一个下部喷嘴。 以这种方式，室壁总是被不间断的液体覆盖。 该方法可以在正常的，降低的或升高的压力下进行。 在通过蒸发水的减压下，系统同时进行冷却。
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10.发明授权Process for the production of optionally substituted 2-mercapto-4,6-di-chloro-s-triazines 失效用于制备任选取代的2-巯基-4,6-二氯-s-三嗪的方法
公开(公告)号：US4259487A
公开(公告)日：1981-03-31
申请号：US94802
申请日：1979-11-15
申请人： Klaus Hentschel , Friedrich Bittner
发明人： Klaus Hentschel , Friedrich Bittner
IPC分类号： B01J10/02 , C07D251/38
CPC分类号： C07D251/38 , B01J10/02 , B01J19/26
摘要： 2-mercapto-4,6-dichloro-s-triazines or substituted 2-mercapto-4,6-dichloro-s-triazines are produced by the known reaction of cyanuric chloride with a mercaptan or mercaptide in the presence of an acid binding agent in an improved manner by working at high mixing velocities and thus at high reaction speed and thereby obtaining high throughputs in small tubular containers by introducing liquid cyanuric chloride through a nozzle in the upper portion of the mixing apparatus in countercurrent flow to upwardly flowing reactants plus acid binding agent introduced from at least one lower nozzle above a breast shaped constriction in the lower, open portion of the apparatus. The process can be carried out at normal, reduced or elevated pressure.
摘要翻译： 2-巯基-4,6-二氯-s-三嗪或取代的2-巯基-4,6-二氯-s-三嗪是通过氰尿酰氯与硫醇或硫醇在已知的酸结合剂存在下反应制备的 通过以高混合速度工作，因此以高反应速度工作，从而通过在混合装置的上部通过喷嘴将液体氰尿酰氯引入到向上流动的反应物加酸的逆流中，从而获得高的通量 在装置的下部开放部分中从乳房形收缩器上方的至少一个下部喷嘴引入的粘合剂。 该方法可以在正常的，降低的或升高的压力下进行。
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