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    Sulfonated bismuth compounds
    5.
    发明授权
    Sulfonated bismuth compounds 失效
    磺化铋化合物

    公开(公告)号：US5536424A

    公开(公告)日：1996-07-16

    申请号：US378375

    申请日：1995-01-25

    申请人： Bruno Delfort ,  Maurice Born ,  Bertrand Daoudal ,  Jacques Lallement

    发明人： Bruno Delfort ,  Maurice Born ,  Bertrand Daoudal ,  Jacques Lallement

    IPC分类号： B01F17/00 ,  B01F17/12 ,  C07C309/31 ,  C07F9/94 ,  C07G99/00 ,  C10L1/24 ,  C10M135/10 ,  C10M139/00 ,  C10M159/24

    CPC分类号： C10M159/24 ,  B01F17/0057 ,  C07C309/31 ,  C07G17/008 ,  C10L1/2437 ,  C10M135/10 ,  C10M2219/044 ,  C10M2219/046 ,  Y10S516/03

    摘要： New sulfonated bismuth compounds and the preparation thereof are described. These new compounds can be represented by the following general formulae: ##STR1## where R.sub.1 represents a monovalent linear or branched aliphatic hydrocarbonaceous radical containing 8 to 36 atoms of carbon, and R.sub.2 represents an atom of hydrogen or a monovalent linear or branched aliphatic hydrocarbonaceous radical containing 8 to 36 atoms of carbon. These compounds, which possess surface-active and wear-fighting properties, are used as fuel additives. They can also serve as starting materials in the manufacture of overbased colloidal products usable as lubricant additives by carbonation of at least one calcium, barium, or magnesium oxide or hydroxide, the carbonate formed being kept as a colloidal dispersion in an organic medium by using at least one of the sulfonated bismuth compounds (I) and (II).

    摘要翻译： 描述了新的磺化铋化合物及其制备方法。 这些新化合物可以由以下通式表示：含有8至36个碳原子的一价直链或支链脂族烃基，R2表示氢原子或含有8至36个碳原子的一价直链或支链脂族烃基 。 具有表面活性和耐磨性的这些化合物用作燃料添加剂。 它们也可以用作制造用作润滑剂添加剂的高碱性胶体产品的起始材料，其通过碳化至少一种钙，钡或氧化镁或氢氧化物，所形成的碳酸酯通过使用在有机介质中作为胶体分散体保持在有机介质中 磺化铋化合物（I）和（II）中的至少一种。

    Polysulphurized olefin compositions, their preparation and their use as additives for lubricants
    9.
    发明授权
    Polysulphurized olefin compositions, their preparation and their use as additives for lubricants 失效
    多硫化烯烃组合物，它们的制备及其作为润滑剂添加剂的用途

    公开(公告)号：US5045221A

    公开(公告)日：1991-09-03

    申请号：US403968

    申请日：1989-09-07

    申请人： Maurice Born ,  Lucienne Briquet ,  Jacques Lallement ,  Guy Parc

    发明人： Maurice Born ,  Lucienne Briquet ,  Jacques Lallement ,  Guy Parc

    IPC分类号： C07C319/14 ,  C07C321/00 ,  C10M135/04 ,  C10N30/06 ,  C10N40/04 ,  C10N40/22

    CPC分类号： C10M135/04

    摘要： Polysulphurized olefin compositions used as additives for gear oils, cutting oils, and as sulphurizing agents in organic media are obtained by a process comprising:a stage (1) in which at least one compound chosen from among sulphur dichloride and monochloride is reacted with at least one aliphatic monpolefin with 2 to 12 carbon atoms, thus forming an adduct;a stage (2) in which sulphurized hydrogen and at least one mercaptan is reacted with ammonium or alkali metal hydroxide dissolved in at least one aliphatic monoalcohol with 1 to 4 carbon atoms, which is substantially anhydrous, so as to give an alcoholic solution;a stage (3) in which contacting takes place between the adduct obtained in stage (1) and the alcoholic solution obtained in stage (2);a stage (4), in which the resulting mixture is heated and then the aliphatic monoalcohol is eliminated by distillation, while adding water in a quantity adequate for maintaining in solution the reagents and the mineral products formed during the reaction; anda stage (5) in which elimination takes place of the aqueous phase and recovery takes place of the organic phase mainly constituted by the polysulphurized olefin composition.

    摘要翻译： 用于齿轮油，切削油和作为有机介质中的硫化剂的添加剂的多硫化烯烃组合物通过以下方法获得，该方法包括：其中至少一种选自二氯化硫和一氯化物的化合物至少与 一种具有2至12个碳原子的脂族单烯烃，从而形成加合物; 使硫化氢和至少一种硫醇与溶解在至少一种具有1-4个碳原子的脂族一元醇中的铵或碱金属氢氧化物反应的阶段（2），其基本上是无水的，以得到醇溶液; 在阶段（1）中获得的加合物和阶段（2）中获得的醇溶液之间发生接触的阶段（3）; 加热得到的混合物，然后通过蒸馏除去脂肪族一元醇的阶段（4），同时加入足以维持溶液中的水，反应物中形成的试剂和矿物产物; 以及主要由多硫化烯烃组合物构成的有机相进行水相脱除发生阶段（5）。