摘要:
A process is described whereby aluminum chlorohydroxide having a controlled chlorine content is prepared by subjecting a mineral containing aluminum oxide or hydroxide (e.g. bayerite, gibbsite, diaspore, boehmite or alumina bayer) is subjected to a preliminary etching with hydrochloric acid at a temperature in the range from 110.degree. to 150.degree. C, the solution so obtained is neutralized with ammonia and the desired aluminum chlorohydroxide (e.g. Al.sub.2 (OH).sub.5 Cl) is crystallized out.
摘要:
Aluminum chlorohydroxide represented by the formula Al.sub.2 (OH).sub.x Cl.sub.y in which x and y range from 1 to 4 and 5 to 2, respectively, is produced by reacting hydrochloric acid with an amount of aluminum oxide or hydroxide which is equal to or slightly greater than the stoichiometric amount for obtaining aluminum trichloride, in the temperature range of from 160.degree. to 270.degree. C, and in the pressure range of from 0.1 to 50 kg/cm.sup.2.
摘要:
Process for the purification of olefins by removing oxygen and acetylene from them which comprises passing the olefins over a contact material consisting essentially of a metallic element from the first B group of the period system which element is homogeneously and finely dispersed on a carrier selected from zeolites, spheroidal alumina, silica gel, Kieselghur or colloidal silica stabilized in an aqueous suspension. The purification process is carried out at temperatures of from -50 to 50.degree. C. under pressures of from 0.01 to 60 atmospheres. The contact material is prepared by mixing a suitable compound of the metallic element such as a carbonate or ammonia complex with the selected carrier, thereafter atomizing the mixture to obtain microspheroids, granulating the spheroids into the desired shape and size and finally subjecting the carrier material to a reducing treatment to obtain the metallic element thereon. The contact material for the purification preferably utilizes the element copper with the contact material having the size of 1-250.mu. and is most suitably used in the purification of ethylene.
摘要:
An ammonium organic salt is recovered from an aqueous solution in which it is contained at a concentration in the range from 0.2% to the salt solubility limit by atomizing the solution in hot air at a temperature in the range of 100.degree. to 150.degree.C.
摘要:
The invention discloses a catalyst on the basis of silicon and titanium having the form of microspheres and constituted by oligomeric silica and by titanium-silicalite crystals having an oligomeric silica/titanium-silicalite molar ratio comprised within the range of from 0.05 to 0.11, wherein the crystals of titanium-silicalite are encaged by means of Si-O-Si bridges.
摘要:
In the process for dehydrating an aliphatic alcohol to convert same into the corresponding ether, the improvement consisting in that the catalyst is an active alumina on the surface of which a layer of a silicon compound has been deposited. Long life of the catalyst and improved conversion rates are the main advantages.
摘要:
The invention discloses a catalyst on the basis of silicon and titanium having the form of microspheres and constituted by oligomeric silica and by titanium-silica-lite crystals having an oligomeric silica/titanium-silicalite molar ratio comprised within the range of from 0.05 to 0.11, wherein the crystals of titanium-silicalite are encaged by means of Si-O-Si bridges.
摘要:
A process for olefin bond isomerization by means of a gamma alumina-based catalyst containing SiO.sub.2 and oxides of a metal chosen from those of Group II A and/or VIII and/or III B and/or Lanthanides, with particular molar ratios between the various oxides. The catalyst is thermally stable, and in the conversion of butene-2 to butene-1 enables butene-1 to be obtained with an isobutene content below the allowable limits for butene-1 grade polymerization.
摘要:
A catalytic system and process for producing mixtures of methanol and higher alcohols from synthesis gas, the catalytic system comprising zinc, chromium, copper, one or more alkaline metals, and possibly one or more metals chosen from molybdenum, manganese, lanthanium, cerium, aluminium, titanium and vanadium, either all or only part of said elements being chemically bonded to oxygen and/or together.
摘要:
The invention relates to a method for the preparation of a catalyst for the dehydrogenation of C.sub.3 -C.sub.5 paraffins consisting in impregnating calcined aluminum oxide with a solution of chromium and potassium compounds, in drying and then impregnating the product obtained with a solution of a compound of silicon, the catalyst obtained being finally dried and calcined.