Nitroxide Compounds for Minimizing Scorch in Crosslinkable Compositions
    5.
    发明申请
    Nitroxide Compounds for Minimizing Scorch in Crosslinkable Compositions 失效
    用于最小化可交联组合物焦烧的硝酸化合物

    公开(公告)号:US20080085973A1

    公开(公告)日:2008-04-10

    申请号:US11539815

    申请日:2006-10-09

    IPC分类号: C07D211/00 C08F2/38

    摘要: Scorch is inhibited during the free-radical crosslinking of a crosslinkable polymer, e.g., an EPDM, by incorporating into the polymer before melt processing and crosslinking a scorch inhibiting amount of a derivative, preferably an ether, ester or urethane derivative, of a TEMPO compound, e.g., 4-hydroxy-tetrahydrocarbylpiperidin-1-oxyl. The scorch inhibitors of this invention perform as well, if not better, than their 4-hydroxy-tetrahydrocarbylpiperidin-1-oxyl counterparts in similar polymer compositions and under similar conditions in terms of scorch inhibition and ultimate degree of crosslinking, but exhibit less volatility and less migration within the polymer composition.

    摘要翻译: 在可交联聚合物(例如EPDM)的自由基交联期间,通过在熔融加工和交联焦烧抑制量的TEMPO化合物的衍生物,优选醚,酯或氨基甲酸酯衍生物的交联之前引入聚合物中,焦烧被抑制 ,例如4-羟基 - 四氢环丁基哌啶-1-基。 在类似的聚合物组合物和类似的条件下,本发明的焦烧抑制剂(如果不是更好)也与其4-羟基 - 四烃基哌啶-1-氧基对应物一样,在焦烧抑制和最终交联度方面也表现出较低的挥发性, 聚合物组合物内迁移少。

    In situ moisture generation and use of polyfunctional alcohols for crosslinking of silane-functionalized resins
    6.
    发明授权
    In situ moisture generation and use of polyfunctional alcohols for crosslinking of silane-functionalized resins 有权
    用于交联硅烷官能化树脂的多官能醇的原位水分产生和使用

    公开(公告)号:US08460770B2

    公开(公告)日:2013-06-11

    申请号:US12740838

    申请日:2008-10-13

    摘要: Polymer compositions comprise a (i) silane-functionalized polymer, e.g., a polyethylene grafted with vinyl triethoxy silane, (H) polyfunctional alcohol e.g., α,α,α′,α′˜tetramethyl-I,3-benzenediethanol and, optionally, (iii) acid, e.g., an alkylated aryl disulfonic acid. The use of polyfunctional alcohols in the absence of a strong acid yields a light-crosslinking of the silane-functionalized polymer and this, in turn, provides a polymer melt with improved extensional properties such as elongational viscosity and melt strength. The use of a polyfunctional alcohol in combination with a blocked strong acid provides a slow rate of crosslinking during melt processing and a high degree of ultimate crosslinking after the polymer composition has been shaped or molded.

    摘要翻译: 聚合物组合物包含(i)硅烷官能化聚合物,例如用乙烯基三乙氧基硅烷接枝的聚乙烯,(H)多官能醇,例如α,α,α',α'-四甲基-1,3-苯二甲醇, (iii)酸,例如烷基化芳基二磺酸。 在不存在强酸的情况下使用多官能醇产生硅烷官能化聚合物的轻交联,这又提供具有改进的拉伸性能如伸长粘度和熔体强度的聚合物熔体。 使用多官能醇与封闭的强酸组合提供了在熔融加工过程中缓慢的交联速率,以及在聚合物组合物成型或模制之后的高度极限交联。

    In Situ Moisture Generation and Use of Polyfunctional Alcohols for Crosslinking of Silane-Functionalized Resins
    7.
    发明申请
    In Situ Moisture Generation and Use of Polyfunctional Alcohols for Crosslinking of Silane-Functionalized Resins 有权
    多官能醇的原位水分产生和使用用于硅烷官能化树脂的交联

    公开(公告)号:US20100297374A1

    公开(公告)日:2010-11-25

    申请号:US12740838

    申请日:2008-10-13

    摘要: Polymer compositions comprise a (i) silane-functionalized polymer, e.g., a polyethylene grafted with vinyl triethoxy silane, (H) polyfunctional alcohol e.g., α,α,α′,α′˜tetramethyl-I,3-benzenediethanol and, optionally, (iii) acid, e.g., an alkylated aryl disulfonic acid. The use of polyfunctional alcohols in the absence of a strong acid yields a light-crosslinking of the silane-functionalized polymer and this, in turn, provides a polymer melt with improved extensional properties such as elongational viscosity and melt strength. The use of a polyfunctional alcohol in combination with a blocked strong acid provides a slow rate of crosslinking during melt processing and a high degree of ultimate crosslinking after the polymer composition has been shaped or molded.

    摘要翻译: 聚合物组合物包含(i)硅烷官能化聚合物,例如用乙烯基三乙氧基硅烷接枝的聚乙烯,(H)多官能醇,例如α,α,α',α'-四甲基-1,3-苯二甲醇, (iii)酸,例如烷基化芳基二磺酸。 在不存在强酸的情况下使用多官能醇产生硅烷官能化聚合物的轻交联,这又提供具有改进的拉伸性能如伸长粘度和熔体强度的聚合物熔体。 使用多官能醇与封闭的强酸组合提供了在熔融加工过程中缓慢的交联速率,以及在聚合物组合物成型或模制之后的高度极限交联。

    Nitroxide Compounds for Minimizing Scorch in Crosslinkable Compositions
    8.
    发明申请
    Nitroxide Compounds for Minimizing Scorch in Crosslinkable Compositions 失效
    用于最小化可交联组合物焦烧的硝酸化合物

    公开(公告)号:US20090069469A1

    公开(公告)日:2009-03-12

    申请号:US12267909

    申请日:2008-11-10

    IPC分类号: C08K5/3435 C07D211/94

    摘要: Scorch is inhibited during the free-radical crosslinking of a crosslinkable polymer, e.g., an EPDM, by incorporating into the polymer before melt processing and crosslinking a scorch inhibiting amount of a derivative, preferably an ether, ester or urethane derivative, of a TEMPO compound, e.g., 4-hydroxy-tetrahydrocarbylpiperidin-1-oxyl. The scorch inhibitors of this invention perform as well, if not better, than their 4-hydroxy-tetrahydrocarbylpiperidin-1-oxyl counterparts in similar polymer compositions and under similar conditions in terms of scorch inhibition and ultimate degree of crosslinking, but exhibit less volatility and less migration within the polymer composition.

    摘要翻译: 在可交联聚合物(例如EPDM)的自由基交联期间,通过在熔融加工和交联焦烧抑制量的TEMPO化合物的衍生物,优选醚,酯或氨基甲酸酯衍生物的交联之前引入聚合物中,焦烧被抑制 ,例如4-羟基 - 四氢环丁基哌啶-1-基。 在类似的聚合物组合物和类似的条件下,本发明的焦烧抑制剂(如果不是更好)也与其4-羟基 - 四烃基哌啶-1-氧基对应物一样,在焦烧抑制和最终交联度方面也表现出较低的挥发性, 聚合物组合物内迁移少。

    Nitroxide compounds for minimizing scorch in crosslinkable compositions
    9.
    发明授权
    Nitroxide compounds for minimizing scorch in crosslinkable compositions 失效
    用于最小化可交联组合物中焦化的硝酸氧化物

    公开(公告)号:US07465769B2

    公开(公告)日:2008-12-16

    申请号:US11539815

    申请日:2006-10-09

    IPC分类号: C08F8/30

    摘要: Scorch is inhibited during the free-radical crosslinking of a crosslinkable polymer, e.g., an EPDM, by incorporating into the polymer before melt processing and crosslinking a scorch inhibiting amount of a derivative, preferably an ether, ester or urethane derivative, of a TEMPO compound, e.g., 4-hydroxy-tetrahydrocarbylpiperidin-1-oxyl. The scorch inhibitors of this invention perform as well, if not better, than their 4-hydroxy-tetrahydrocarbylpiperidin-1-oxyl counterparts in similar polymer compositions and under similar conditions in terms of scorch inhibition and ultimate degree of crosslinking, but exhibit less volatility and less migration within the polymer composition.

    摘要翻译: 在可交联聚合物(例如EPDM)的自由基交联期间,通过在熔融加工和交联焦烧抑制量的TEMPO化合物的衍生物,优选醚,酯或氨基甲酸酯衍生物的交联之前引入聚合物中,焦烧被抑制 ,例如4-羟基 - 四氢环丁基哌啶-1-基。 在类似的聚合物组合物和类似的条件下,本发明的焦烧抑制剂(如果不是更好)也与其4-羟基 - 四烃基哌啶-1-氧基对应物一样,在焦烧抑制和最终交联度方面也表现出较低的挥发性, 聚合物组合物内迁移少。