摘要:
Polybenzyls of high molecular weight and high crystallinity are obtained by polymerizing aralkyl halides in the presence of a catalyst comprising a complex of a Friedel-Crafts catalyst with a complexing agent which can be a nitroarene or a nitroalkane. The complex catalyst allows the polymerization to be run at higher temperatures and with higher rates. Yields are obtained up to 100%.
摘要:
Ethylene is homopolymerized or copolymerized with another olefin monomer in the presence of a catalyst system comprising organo metal cocatalyst and a titanium-containing catalyst component, said titanium-containing catalyst component being obtained by reacting together a porous particulate material, an organic magnesium compound, a halogen or interhalogen compound and titanium tetrachloride.
摘要:
Highly unusual and useful novel high-performance, oriented, low-crystalline, essentially heterocyclic structures, e.g. films, are prepared from certain novel and important process sequences. These structures, e.g. films and fibers, possess a unique combination of minimal shrinkage at high temperatures, after orientation, coupled with negligible coefficient of expansion over an unusually wide temperature range.
摘要:
Highly useful novel microcellular polymeric structures, especially films and fibers, are prepared from certain solid polymers. Aromatic polysulfones, polyimides, polyhydantoins, polyamides and polyparabanic acid are the preferred ones for the novel structures of the invention.
摘要:
Copper chelates of 2-hydroxybenzophenones useful as UV light absorbers are employed to stabilize organic compositions such as polymer compositions against degradation on embrittlement on exposure to UV light.
摘要:
Normally intractable polymers of the structure: ##STR1## wherein X is O or NH, provided at least one X is O, R is an organic moiety, such as poly(parabanic acids) are plasticized by composition with from 15 to 60 weight percent of an aromatic sulfone or aromatic sulfoxide such as diphenyl sulfone, diphenyl sulfoxide or dibutyl-4,4'-sulfonyl dibenzoate.
摘要:
Novel high impact plastics are prepared by the inclusion of 2 to 30 weight percent of bromobutyl rubber in polymers of styrene and styrene-acrylonitrile and the grafting of said polymers onto said rubber. The graft copolymers are obtained by polymerizing the monomers of styrene or styrene-acrylonitrile in the presence of the bromobutyl rubber, which is preferably precrosslinked.
摘要:
High temperature resistant polymers containing a methylene monoarylene, methylene diarylene, -aromatic ring--CH.sub.2 -- or -aromatic ring--CH.sub.2 --aromatic ring-group are made more effective at even higher temperatures against thermal oxidative degradation by incorporating small quantities of special antioxidant stabilizers therein either singly or in combination to result in novel and unobvious compositions.
摘要:
Ethylene is homopolymerized or copolymerized with another olefin monomer in the presence of a catalyst system comprising organo metal cocatalyst and a titanium-containing catalyst component, such titanium-containing catalyst component being obtained by reacting together a porous particulate material, an organo magnesium compound, a halogen or interhalogen compound and titanium tetrachloride.