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1.发明申请Ethylene Oxide/Propylene Oxide Polyether Polyols and Polyurethanes Made Therefrom 有权环氧乙烷/环氧丙烷聚醚多元醇和聚氨酯制成公开(公告)号：US20150376332A1
公开(公告)日：2015-12-31
申请号：US14849538
申请日：2015-09-09
CPC分类号： C08G65/12 , C08G18/18 , C08G18/24 , C08G18/3203 , C08G18/4833 , C08G18/4845 , C08G18/485 , C08G18/7621 , C08G65/2609 , C08G65/2624 , C08G2101/0008 , C08L71/02
摘要： Copolymers of propylene oxide and ethylene oxide have an inner block that contains from 65-90 weight percent oxyethylene units and from 10 to 35 weight percent oxypropylene units. This block has a molecular weight of from 150 to 350. The copolymer has an outer block which contains at least 95 weight % oxypropylene units and from 0 to 5% oxyethylene units. The equivalent weight of the copolymer is from 800 to 2000. The copolymers are useful in making polyurethane foams that have unexpectedly high tensile and/or tear strengths.
摘要翻译： 环氧丙烷和环氧乙烷的共聚物具有含有65-90重量％氧化乙烯单元和10-35重量％氧化丙烯单元的内部嵌段。 该嵌段具有150至350的分子量。该共聚物具有含有至少95重量％氧化丙烯单元和0-5重量％氧化乙烯单元的外嵌段。 共聚物的当量为800至2000.该共聚物可用于制备具有出乎意料的高拉伸强度和/或撕裂强度的聚氨酯泡沫。
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公开(公告)号：US20130143977A1
公开(公告)日：2013-06-06
申请号：US13812501
申请日：2011-08-11
IPC分类号： C08G18/32
CPC分类号： C08G65/12 , C08G18/18 , C08G18/24 , C08G18/3203 , C08G18/4833 , C08G18/4845 , C08G18/485 , C08G18/7621 , C08G65/2609 , C08G65/2624 , C08G2101/0008 , C08L71/02
摘要： Copolymers of propylene oxide and ethylene oxide have an inner block that contains from 65-90 weight percent oxyethylene units and from 10 to 35 weight percent oxypropylene units. This block has a molecular weight of from 150 to 350. The copolymer has an outer block which contains at least 95 weight % oxypropylene units and from 0 to 5% oxyethylene units. The equivalent weight of the copolymer is from 800 to 2000. The copolymers are useful in making polyurethane foams that have unexpectedly high tensile and/or tear strengths.
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公开(公告)号：US09725559B2
公开(公告)日：2017-08-08
申请号：US14849538
申请日：2015-09-09
IPC分类号： C08G65/12 , C08G65/26 , C08G18/32 , C08L71/02 , C08G18/18 , C08G18/24 , C08G18/48 , C08G18/76 , C08G101/00
CPC分类号： C08G65/12 , C08G18/18 , C08G18/24 , C08G18/3203 , C08G18/4833 , C08G18/4845 , C08G18/485 , C08G18/7621 , C08G65/2609 , C08G65/2624 , C08G2101/0008 , C08L71/02
摘要： Copolymers of propylene oxide and ethylene oxide have an inner block that contains from 65-90 weight percent oxyethylene units and from 10 to 35 weight percent oxypropylene units. This block has a molecular weight of from 150 to 350. The copolymer has an outer block which contains at least 95 weight % oxypropylene units and from 0 to 5% oxyethylene units. The equivalent weight of the copolymer is from 800 to 2000. The copolymers are useful in making polyurethane foams that have unexpectedly high tensile and/or tear strengths.
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4.发明授权Ethylene oxide/propylene oxide polyether polyols and polyurethanes made therefrom 有权环氧乙烷/环氧丙烷聚醚多元醇和由其制成的聚氨酯公开(公告)号：US09156936B2
公开(公告)日：2015-10-13
申请号：US13812501
申请日：2011-08-11
CPC分类号： C08G65/12 , C08G18/18 , C08G18/24 , C08G18/3203 , C08G18/4833 , C08G18/4845 , C08G18/485 , C08G18/7621 , C08G65/2609 , C08G65/2624 , C08G2101/0008 , C08L71/02
摘要： Copolymers of propylene oxide and ethylene oxide have an inner block that contains from 65-90 weight percent oxyethylene units and from 10 to 35 weight percent oxypropylene units. This block has a molecular weight of from 150 to 350. The copolymer has an outer block which contains at least 95 weight % oxypropylene units and from 0 to 5% oxyethylene units. The equivalent weight of the copolymer is from 800 to 2000. The copolymers are useful in making polyurethane foams that have unexpectedly high tensile and/or tear strengths.
摘要翻译： 环氧丙烷和环氧乙烷的共聚物具有含有65-90重量％氧化乙烯单元和10-35重量％氧化丙烯单元的内部嵌段。 该嵌段具有150至350的分子量。该共聚物具有含有至少95重量％氧化丙烯单元和0-5重量％氧化乙烯单元的外嵌段。 共聚物的当量为800至2000.该共聚物可用于制备具有出乎意料的高拉伸强度和/或撕裂强度的聚氨酯泡沫。
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5.发明申请PROCESS FOR MAKING POLYETHER ALCOHOLS HAVING OXYETHYLENE UNITS BY POLYMERIZATION OF ETHYLENE CARBONATE IN THE PRESENCE OF DOUBLE METAL CYANIDE CATALYSTS 有权在双金属氰化物催化剂存在下通过聚合乙烯碳酸酯制备具有乙烯基单体的聚醚的方法公开(公告)号：US20140163197A1
公开(公告)日：2014-06-12
申请号：US14234577
申请日：2012-08-15
申请人： Esther E. Quintanilla , Hanno R. Van Der Wal , Daniel C. Floyd , Myriam Linke , Francois M. Casati , Carlos M. Villa , Jean-Paul Masy , Ricco B. Borella , Paul Cookson
发明人： Esther E. Quintanilla , Hanno R. Van Der Wal , Daniel C. Floyd , Myriam Linke , Francois M. Casati , Carlos M. Villa , Jean-Paul Masy , Ricco B. Borella , Paul Cookson
IPC分类号： C08G65/34
CPC分类号： C08G65/34 , C08G65/00 , C08G65/2663
摘要： Ethylene carbonate is polymerized by itself or together with another cyclic monomer such as 1,2-propylene oxide in the presence of a double metal cyanide catalyst. Most of the ethylene carbonate adds to the chain to form a terminal carbonate group, which decarboxylates to produce a hydroxyethyl group at the end of the polymer chain. The polymerization of more ethylene carbonate onto the chain end results in the formation of poly(ethyleneoxy) units. Therefore, the process provides a method for making poly(ethyleneoxy) polymers without the need to polymerize ethylene oxide. The process is useful for making polyethers that are useful as water-absorbable polymers, surfactants and as raw materials for polyurethanes. The process is also useful for increasing the primary hydroxyl content of a polyether.
摘要翻译： 在双金属氰化物催化剂存在下，碳酸亚丙酯本身或其它环状单体如1,2-环氧丙烷聚合。 大多数碳酸亚乙酯添加到链上以形成末端碳酸酯基团，其在聚合物链末端脱羧以产生羟乙基。 更多的碳酸亚乙酯在链末端的聚合导致聚（乙烯氧基）单元的形成。 因此，该方法提供了制备聚（乙烯氧基）聚合物而不需要聚合环氧乙烷的方法。 该方法可用于制备可用作吸水聚合物，表面活性剂和聚氨酯原料的聚醚。 该方法也可用于增加聚醚的伯羟基含量。
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公开(公告)号：US09758619B2
公开(公告)日：2017-09-12
申请号：US14234577
申请日：2012-08-15
申请人： Esther E. Quintanilla , Hanno R. Van Der Wal , Daniel C. Floyd , Myriam Linke , Francois M. Casati , Carlos M. Villa , Jean-Paul Masy , Ricco B. Borella , Paul Cookson
发明人： Esther E. Quintanilla , Hanno R. Van Der Wal , Daniel C. Floyd , Myriam Linke , Francois M. Casati , Carlos M. Villa , Jean-Paul Masy , Ricco B. Borella , Paul Cookson
CPC分类号： C08G65/34 , C08G65/00 , C08G65/2663
摘要： Ethylene carbonate is polymerized by itself or together with another cyclic monomer such as 1,2-propylene oxide in the presence of a double metal cyanide catalyst. Most of the ethylene carbonate adds to the chain to form a terminal carbonate group, which decarboxylates to produce a hydroxyethyl group at the end of the polymer chain. The polymerization of more ethylene carbonate onto the chain end results in the formation of poly(ethyleneoxy) units. Therefore, the process provides a method for making poly(ethyleneoxy) polymers without the need to polymerize ethylene oxide. The process is useful for making polyethers that are useful as water-absorbable polymers, surfactants and as raw materials for polyurethanes. The process is also useful for increasing the primary hydroxyl content of a polyether.
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7.发明申请FINE PARTICLE, HIGH CONCENTRATION, POLYISOCYANATE POLYADDITION/POLYURETHANE-UREA POLYOLS 审中-公开精细颗粒，高浓度，聚异氰酸酯多元醇/聚氨酯 - 尿素多元醇公开(公告)号：US20140051778A1
公开(公告)日：2014-02-20
申请号：US14113675
申请日：2012-05-09
CPC分类号： C08G18/771 , C08G18/14 , C08G18/163 , C08G18/165 , C08G18/1833 , C08G18/2063 , C08G18/222 , C08G18/227 , C08G18/244 , C08G18/3206 , C08G18/3819 , C08G18/4009 , C08G18/4072 , C08G18/409 , C08G18/4841 , C08G18/4854 , C08G18/632 , C08G18/6677 , C08G18/7621 , C08G18/7862 , C08G2101/00 , C08G2101/005 , C08G2101/0083
摘要： Embodiments of the invention include a method of producing polymer polyol dispersions is. The method includes providing at least one reaction system, and the reaction system includes: a) at least one polyol, b) at least one seed population, c) at least one catalyst, d) at least one co-reactant having an equivalent weight of up to 400 and at least one active hydrogen attached to a nitrogen or oxygen atom, and e) at least one polyisocyanate. The at least one seed population includes less than about 5% by weight of the total weight of the at least one reaction system and includes seed particles having diameters of less than 5 μm. The at least one reaction mixture reacts to form at least one of a polyurea and polyurethane-urea particle population in the at least one polyol without the addition of any catalysts comprising tin. The polymer polyol dispersion has a solids content of at least 15% of the weight of the polymer polyol dispersion.
摘要翻译： 本发明的实施方案包括制备聚合物多元醇分散体的方法。 该方法包括提供至少一个反应体系，反应体系包括：a）至少一种多元醇，b）至少一种种子群，c）至少一种催化剂，d）至少一种具有当量重量的共反应物 至多400和至少一个与氮或氧原子连接的活性氢，和e）至少一种多异氰酸酯。 所述至少一种种子群体包含小于所述至少一种反应体系总重量的约5重量％，并且包括直径小于5μm的种子颗粒。 所述至少一种反应混合物在所述至少一种多元醇中反应形成聚脲和聚氨酯 - 尿素颗粒群中的至少一种，而不加入任何包含锡的催化剂。 聚合物多元醇分散体的固体含量为聚合物多元醇分散体重量的至少15％。
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公开(公告)号：US09399696B2
公开(公告)日：2016-07-26
申请号：US14378189
申请日：2013-03-14
CPC分类号： C08G18/7621 , C08G18/222 , C08G18/242 , C08G18/3281 , C08G18/409 , C08G18/4829
摘要： Embodiments include polymer polyol dispersions which include a polyol liquid phase and solid particle phase. Embodiments include methods of making the polymer polyol dispersions. The polymer polyol dispersions are essentially free of tin, have a solid content of between about 20 and 50 wt % based on the total weight of the polymer polyol dispersion, and have a viscosity at 20 C. of less than 9000 mPas. The solid particle phase has more than 90% by weight of particles in the solid particle phase having a particle diameter of less than 5 μm.
摘要翻译： 实施方案包括聚合物多元醇分散体，其包括多元醇液相和固体颗粒相。 实施方案包括制备聚合物多元醇分散体的方法。 聚合物多元醇分散体基本上不含锡，固体含量基于聚合物多元醇分散体的总重量为约20至50重量％，并且在20℃下的粘度小于9000mPas。 固体颗粒相具有超过90重量％的固体颗粒相中的粒径小于5μm的颗粒。
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公开(公告)号：US20150038653A1
公开(公告)日：2015-02-05
申请号：US14378189
申请日：2013-03-14
CPC分类号： C08G18/7621 , C08G18/222 , C08G18/242 , C08G18/3281 , C08G18/409 , C08G18/4829
摘要： Embodiments include polymer polyol dispersions which include a polyol liquid phase and solid particle phase. Embodiments include methods of making the polymer polyol dispersions. The polymer polyol dispersions are essentially free of tin, have a solid content of between about 20 and 50 wt % based on the total weight of the polymer polyol dispersion, and have a viscosity at 20C of less than 9000 mPas. The solid particle phase has more than 90% by weight of particles in the solid particle phase having a particle diameter of less than 5 μm.
摘要翻译： 实施方案包括聚合物多元醇分散体，其包括多元醇液相和固体颗粒相。 实施方案包括制备聚合物多元醇分散体的方法。 聚合物多元醇分散体基本上不含锡，基于聚合物多元醇分散体的总重量，其固体含量为约20至50重量％，并且在20℃下的粘度小于9000mPas。 固体颗粒相具有超过90重量％的固体颗粒相中的粒径小于5μm的颗粒。
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