公开(公告)号：US20140051778A1

公开(公告)日：2014-02-20

申请号：US14113675

申请日：2012-05-09

申请人： Paul Cookson ,  Ricco B. Borella ,  Daniel Hoehener ,  Francois M. Casati

发明人： Paul Cookson ,  Ricco B. Borella ,  Daniel Hoehener ,  Francois M. Casati

IPC分类号： C08G18/22 ,  C08G18/38

CPC分类号： C08G18/771 ,  C08G18/14 ,  C08G18/163 ,  C08G18/165 ,  C08G18/1833 ,  C08G18/2063 ,  C08G18/222 ,  C08G18/227 ,  C08G18/244 ,  C08G18/3206 ,  C08G18/3819 ,  C08G18/4009 ,  C08G18/4072 ,  C08G18/409 ,  C08G18/4841 ,  C08G18/4854 ,  C08G18/632 ,  C08G18/6677 ,  C08G18/7621 ,  C08G18/7862 ,  C08G2101/00 ,  C08G2101/005 ,  C08G2101/0083

摘要： Embodiments of the invention include a method of producing polymer polyol dispersions is. The method includes providing at least one reaction system, and the reaction system includes: a) at least one polyol, b) at least one seed population, c) at least one catalyst, d) at least one co-reactant having an equivalent weight of up to 400 and at least one active hydrogen attached to a nitrogen or oxygen atom, and e) at least one polyisocyanate. The at least one seed population includes less than about 5% by weight of the total weight of the at least one reaction system and includes seed particles having diameters of less than 5 μm. The at least one reaction mixture reacts to form at least one of a polyurea and polyurethane-urea particle population in the at least one polyol without the addition of any catalysts comprising tin. The polymer polyol dispersion has a solids content of at least 15% of the weight of the polymer polyol dispersion.

摘要翻译： 本发明的实施方案包括制备聚合物多元醇分散体的方法。 该方法包括提供至少一个反应体系，反应体系包括：a）至少一种多元醇，b）至少一种种子群，c）至少一种催化剂，d）至少一种具有当量重量的共反应物 至多400和至少一个与氮或氧原子连接的活性氢，和e）至少一种多异氰酸酯。 所述至少一种种子群体包含小于所述至少一种反应体系总重量的约5重量％，并且包括直径小于5μm的种子颗粒。 所述至少一种反应混合物在所述至少一种多元醇中反应形成聚脲和聚氨酯 - 尿素颗粒群中的至少一种，而不加入任何包含锡的催化剂。 聚合物多元醇分散体的固体含量为聚合物多元醇分散体重量的至少15％。

公开(公告)号：US09399696B2

公开(公告)日：2016-07-26

申请号：US14378189

申请日：2013-03-14

申请人： Ricco B. Borella ,  Paul Cookson ,  Daniel Hoehener ,  Francois M. Casati

发明人： Ricco B. Borella ,  Paul Cookson ,  Daniel Hoehener ,  Francois M. Casati

IPC分类号： C08G18/76 ,  C08G18/22 ,  C08G18/48 ,  C08G18/24 ,  C08G18/32 ,  C08G18/40

CPC分类号： C08G18/7621 ,  C08G18/222 ,  C08G18/242 ,  C08G18/3281 ,  C08G18/409 ,  C08G18/4829

摘要： Embodiments include polymer polyol dispersions which include a polyol liquid phase and solid particle phase. Embodiments include methods of making the polymer polyol dispersions. The polymer polyol dispersions are essentially free of tin, have a solid content of between about 20 and 50 wt % based on the total weight of the polymer polyol dispersion, and have a viscosity at 20 C. of less than 9000 mPas. The solid particle phase has more than 90% by weight of particles in the solid particle phase having a particle diameter of less than 5 μm.

摘要翻译： 实施方案包括聚合物多元醇分散体，其包括多元醇液相和固体颗粒相。 实施方案包括制备聚合物多元醇分散体的方法。 聚合物多元醇分散体基本上不含锡，固体含量基于聚合物多元醇分散体的总重量为约20至50重量％，并且在20℃下的粘度小于9000mPas。 固体颗粒相具有超过90重量％的固体颗粒相中的粒径小于5μm的颗粒。

公开(公告)号：US20150038653A1

公开(公告)日：2015-02-05

申请号：US14378189

申请日：2013-03-14

申请人： Ricco B. Borella ,  Paul Cookson ,  Daniel Hoehener ,  Francois M. Casati

发明人： Ricco B. Borella ,  Paul Cookson ,  Daniel Hoehener ,  Francois M. Casati

IPC分类号： C08G18/76 ,  C08G18/22 ,  C08G18/48 ,  C08G18/24

CPC分类号： C08G18/7621 ,  C08G18/222 ,  C08G18/242 ,  C08G18/3281 ,  C08G18/409 ,  C08G18/4829

摘要： Embodiments include polymer polyol dispersions which include a polyol liquid phase and solid particle phase. Embodiments include methods of making the polymer polyol dispersions. The polymer polyol dispersions are essentially free of tin, have a solid content of between about 20 and 50 wt % based on the total weight of the polymer polyol dispersion, and have a viscosity at 20C of less than 9000 mPas. The solid particle phase has more than 90% by weight of particles in the solid particle phase having a particle diameter of less than 5 μm.

摘要翻译： 实施方案包括聚合物多元醇分散体，其包括多元醇液相和固体颗粒相。 实施方案包括制备聚合物多元醇分散体的方法。 聚合物多元醇分散体基本上不含锡，基于聚合物多元醇分散体的总重量，其固体含量为约20至50重量％，并且在20℃下的粘度小于9000mPas。 固体颗粒相具有超过90重量％的固体颗粒相中的粒径小于5μm的颗粒。

公开(公告)号：US20140163197A1

公开(公告)日：2014-06-12

申请号：US14234577

申请日：2012-08-15

申请人： Esther E. Quintanilla ,  Hanno R. Van Der Wal ,  Daniel C. Floyd ,  Myriam Linke ,  Francois M. Casati ,  Carlos M. Villa ,  Jean-Paul Masy ,  Ricco B. Borella ,  Paul Cookson

发明人： Esther E. Quintanilla ,  Hanno R. Van Der Wal ,  Daniel C. Floyd ,  Myriam Linke ,  Francois M. Casati ,  Carlos M. Villa ,  Jean-Paul Masy ,  Ricco B. Borella ,  Paul Cookson

IPC分类号： C08G65/34

CPC分类号： C08G65/34 ,  C08G65/00 ,  C08G65/2663

摘要： Ethylene carbonate is polymerized by itself or together with another cyclic monomer such as 1,2-propylene oxide in the presence of a double metal cyanide catalyst. Most of the ethylene carbonate adds to the chain to form a terminal carbonate group, which decarboxylates to produce a hydroxyethyl group at the end of the polymer chain. The polymerization of more ethylene carbonate onto the chain end results in the formation of poly(ethyleneoxy) units. Therefore, the process provides a method for making poly(ethyleneoxy) polymers without the need to polymerize ethylene oxide. The process is useful for making polyethers that are useful as water-absorbable polymers, surfactants and as raw materials for polyurethanes. The process is also useful for increasing the primary hydroxyl content of a polyether.

摘要翻译： 在双金属氰化物催化剂存在下，碳酸亚丙酯本身或其它环状单体如1,2-环氧丙烷聚合。 大多数碳酸亚乙酯添加到链上以形成末端碳酸酯基团，其在聚合物链末端脱羧以产生羟乙基。 更多的碳酸亚乙酯在链末端的聚合导致聚（乙烯氧基）单元的形成。 因此，该方法提供了制备聚（乙烯氧基）聚合物而不需要聚合环氧乙烷的方法。 该方法可用于制备可用作吸水聚合物，表面活性剂和聚氨酯原料的聚醚。 该方法也可用于增加聚醚的伯羟基含量。

公开(公告)号：US09758619B2

公开(公告)日：2017-09-12

申请号：US14234577

申请日：2012-08-15

申请人： Esther E. Quintanilla ,  Hanno R. Van Der Wal ,  Daniel C. Floyd ,  Myriam Linke ,  Francois M. Casati ,  Carlos M. Villa ,  Jean-Paul Masy ,  Ricco B. Borella ,  Paul Cookson

发明人： Esther E. Quintanilla ,  Hanno R. Van Der Wal ,  Daniel C. Floyd ,  Myriam Linke ,  Francois M. Casati ,  Carlos M. Villa ,  Jean-Paul Masy ,  Ricco B. Borella ,  Paul Cookson

IPC分类号： C08G65/34 ,  C08G65/00 ,  C08G65/26

CPC分类号： C08G65/34 ,  C08G65/00 ,  C08G65/2663

摘要： Ethylene carbonate is polymerized by itself or together with another cyclic monomer such as 1,2-propylene oxide in the presence of a double metal cyanide catalyst. Most of the ethylene carbonate adds to the chain to form a terminal carbonate group, which decarboxylates to produce a hydroxyethyl group at the end of the polymer chain. The polymerization of more ethylene carbonate onto the chain end results in the formation of poly(ethyleneoxy) units. Therefore, the process provides a method for making poly(ethyleneoxy) polymers without the need to polymerize ethylene oxide. The process is useful for making polyethers that are useful as water-absorbable polymers, surfactants and as raw materials for polyurethanes. The process is also useful for increasing the primary hydroxyl content of a polyether.

公开(公告)号：US20120123005A1

公开(公告)日：2012-05-17

申请号：US13384927

申请日：2010-07-22

申请人： Bruno Cesar Motta ,  Marcos Franca ,  Vinicius Serves ,  Paul Cookson ,  Imran Munshi ,  Francois M. Casati

发明人： Bruno Cesar Motta ,  Marcos Franca ,  Vinicius Serves ,  Paul Cookson ,  Imran Munshi ,  Francois M. Casati

IPC分类号： C08G18/06

CPC分类号： C08G18/4891 ,  C08G18/165 ,  C08G18/409 ,  C08G18/4812 ,  C08G18/482 ,  C08G18/5021 ,  C08G18/7621 ,  C08G77/46 ,  C08G2101/005 ,  C08G2101/0083 ,  C08L83/00

摘要： The embodiments of the present invention provide for polyurethane foams that include renewable resources while keeping desired properties of the polyurethane product. For example, described herein, according to embodiments of the invention, are polyurethane foams that have a high concentration of renewable resources while retaining favorable airflow, tensile strength, tear resistance, elongation, indentation force deflection, and/or resilience. These foams may also posses improved yellowing resistance and improved water absorption rates.

摘要翻译： 本发明的实施方案提供了聚氨酯泡沫，其包括可再生资源，同时保持聚氨酯产品的所需性能。 例如，根据本发明的实施例，这里描述的是具有高浓度可再生资源同时保持有利气流，拉伸强度，抗撕裂性，伸长率，压痕力偏转和/或弹性的聚氨酯泡沫。 这些泡沫也可能具有改善的耐黄变性和改善的吸水率。

公开(公告)号：US20110105634A1

公开(公告)日：2011-05-05

申请号：US12675093

申请日：2008-08-26

申请人： Paul Cookson ,  Francois M. Casati ,  Christopher Noakes

发明人： Paul Cookson ,  Francois M. Casati ,  Christopher Noakes

IPC分类号： C08G18/32

CPC分类号： C08G18/227 ,  C08G18/283 ,  C08G18/36 ,  C08G18/409 ,  C08G18/4804 ,  C08G18/4841 ,  C08G18/4891 ,  C08G18/5021 ,  C08G18/7621 ,  C08G2101/0008 ,  C08G2101/005 ,  C08G2101/0083 ,  C08L83/00

摘要： The embodiments of the present invention provide for viscoelastic polyurethane foams made in the presence of a bismuth comprising catalyst. The viscoelastic polyurethane foam may be the reaction product of a reaction mixture including at least one polyol and at least one isocyanate, wherein the at least one polyol and the at least one isocyanate are reacted in the presence of at least one bismuth comprising catalyst, and wherein the viscoelastic polyurethane foam has a density of less than 100 kg/m3 and a resilience of less than about 25%.

摘要翻译： 本发明的实施方案提供了在包含催化剂的铋存在下制备的粘弹性聚氨酯泡沫体。 粘弹性聚氨酯泡沫可以是包括至少一种多元醇和至少一种异氰酸酯的反应混合物的反应产物，其中所述至少一种多元醇和至少一种异氰酸酯在至少一种包含催化剂的铋存在下反应，和 其中所述粘弹性聚氨酯泡沫具有小于100kg / m 3的密度和小于约25％的回弹性。

公开(公告)号：US20110218264A1

公开(公告)日：2011-09-08

申请号：US13128670

申请日：2009-11-16

申请人： Francois M. Casati ,  Pavel L. Shutov ,  Hanno R. Van der Wal ,  Paul Cookson ,  Timothy Morley ,  Nathan Wilmot ,  Luis G. Zalamea ,  Zhizhong Wu ,  Joseph J. Zupancic ,  David E. Vietti

发明人： Francois M. Casati ,  Pavel L. Shutov ,  Hanno R. Van der Wal ,  Paul Cookson ,  Timothy Morley ,  Nathan Wilmot ,  Luis G. Zalamea ,  Zhizhong Wu ,  Joseph J. Zupancic ,  David E. Vietti

IPC分类号： C08G18/00 ,  C07C67/26 ,  C07C69/734 ,  C09D175/04

CPC分类号： C08G18/36 ,  C08G18/4255 ,  C08G18/4891

摘要： A modified natural oil made from reacting at least one natural oil or fat comprising at least one ene moiety with at least one of an enophile or dienophile mixture to form at least one modified natural oil, and reacting the at least one modified natural oil which may be used in a variety of processes.

摘要翻译： 将至少一种包含至少一个烯部分的天然油或脂肪与至少一种亲烯体或亲双烯体混合物反应形成至少一种改性天然油而制备的改性天然油，并使所述至少一种改性天然油与 可用于各种过程。

公开(公告)号：US20140051779A1

公开(公告)日：2014-02-20

申请号：US14111634

申请日：2012-05-09

申请人： Francois M. Casati ,  Paul Cookson ,  Hanno R. Van dr Wal

发明人： Francois M. Casati ,  Paul Cookson ,  Hanno R. Van dr Wal

IPC分类号： C08G18/08 ,  C08G18/76

CPC分类号： C08G18/409 ,  C08G18/0838 ,  C08G18/0876 ,  C08G18/7621 ,  C08G2101/0008

摘要： Embodiments of the invention provide for polymer polyols and methods of producing polymer polyols. Methods include providing at least one first composition which includes at least one polyol, at least one isocyanate non-reactive seed population, and at least one of a co-reactant having an equivalent weight of up to 400 and at least one active hydrogen attached to a nitrogen or oxygen atom. The at least one isocyanate non-reactive seed population includes less than about 5% by weight of the total weight of the first composition, and the seed population has a maximum particle diameter of less than 10 The first composition is combined with at least one polyisocyanate under mixing to form at least one of a polyurea, polyurethane, and a polyurethane-urea particle population dispersed in the first composition, wherein at least 90% by weight of the particle population has a particle diameter of less than 100 μm.

摘要翻译： 本发明的实施方案提供聚合物多元醇和制备聚合物多元醇的方法。 方法包括提供至少一种第一组合物，其包含至少一种多元醇，至少一种异氰酸酯非反应性种子群体，以及至少一种当量重量至多为400的共反应物和至少一种连接至 氮或氧原子。 所述至少一种异氰酸酯非反应性种子群包括小于所述第一组合物总重量的约5重量％，并且所述种子群体具有小于10的最大粒径。所述第一组合物与至少一种多异氰酸酯 在混合下形成分散在第一组合物中的聚脲，聚氨酯和聚氨酯 - 尿素颗粒群中的至少一种，其中至少90重量％的颗粒群具有小于100μm的粒径。

公开(公告)号：US20140206787A1

公开(公告)日：2014-07-24

申请号：US13578658

申请日：2011-02-25

申请人： Francois M. Casati ,  Esther E. Quintanilla ,  Hanno R. Van der Wal ,  Timothy A. Morley ,  Peter Mullaert

发明人： Francois M. Casati ,  Esther E. Quintanilla ,  Hanno R. Van der Wal ,  Timothy A. Morley ,  Peter Mullaert

IPC分类号： C08G18/48 ,  C08G65/34

CPC分类号： C08G18/4866 ,  C08G18/48 ,  C08G65/2609 ,  C08G65/34 ,  C08G65/48 ,  C08G2101/0025 ,  C08G2650/24 ,  C08G2650/54

摘要： A polyglycerine initiated polyether polyol exhibiting a final functionality less than the nominal functionalities of the polyol initiator wherein the initiator is a polyglycerine formed by the polymerization of glycerin having an HEW less than about 35 and exhibiting a nominal functionality between 2 and 16 is provided. Also provided is a process for producing a polyfunctional polyurethane by the reaction of a mixture containing a polyol based on polyglycerine initiator wherein between 5 wt % and 100 wt % of the total initiator is polyglycerine having a nominal functionality between 2 and 16, at least one organic isocyanate, an amine and/or a metal salt catalyst, and optionally a blowing agent. Also provided is a flexible polyurethane foam comprising a reaction product of a polyglycerine or formed by the glycidol polymerization of glycerin, at least one organic isocyanate, and an amine catalyst.

摘要翻译： 提供了最终官能度低于多元醇引发剂的标称官能度的聚甘油引发的聚醚多元醇，其中引发剂是通过HEW低于约35并表现出标称官能度在2和16之间的甘油的聚合形成的聚甘油。 还提供了通过含有基于聚甘油引发剂的多元醇的混合物的反应来制备多官能聚氨酯的方法，其中总引发剂的5重量％至100重量％是标称官能度为2至16的聚甘油，至少一种 有机异氰酸酯，胺和/或金属盐催化剂，以及任选的发泡剂。 还提供了包含聚甘油的反应产物或通过甘油的缩水甘油聚合形成的柔性聚氨酯泡沫，至少一种有机异氰酸酯和胺催化剂。