Process for synthesizing overbased additives under constant pressure of
carbon dioxide
    1.
    发明授权
    Process for synthesizing overbased additives under constant pressure of carbon dioxide 失效
    在二氧化碳恒压下合成高碱性添加剂的方法

    公开(公告)号:US4758360A

    公开(公告)日:1988-07-19

    申请号:US910947

    申请日:1986-09-24

    CPC分类号: C10M159/24 C10M159/20

    摘要: The present invention relates to a process for the synthesis of overbased additives obtained by carbonation under constant pressure of carbon dioxide, the process consisting of carbonating a reaction mixture comprising a derivative of an alkaline-earth metal and at least one surfactant in a diluent oil and a hydrocarbon solvent in the presence of an oxygeneous accelerator and a nitrogeneous accelerator, while maintaining a constant pressure of carbon dioxide above the reaction mixture, the carbon dioxide is thus progressively introduced as it is consumed, thereby allowing its concentration in the liquid medium not to become too high which could thereafter provoke the formation of insoluble over-carbonated products, the reaction to be self-controlled and to obtain excellent yields of overbased products having very high alkaline values and alkaline-earth contents, while however remaining fluid and stable.

    摘要翻译: 本发明涉及一种合成通过碳酸化在二氧化碳的恒定压力下获得的高碱性添加剂的方法,该方法包括在稀释油中将包含碱土金属和至少一种表面活性剂的衍生物的反应混合物碳酸化, 在含氧促进剂和硝化促进剂存在下的烃溶剂,同时保持二氧化碳在反应混合物上方的恒定压力,因此二氧化碳在消耗时逐渐引入,从而使其在液体介质中的浓度不能 变得过高,这可能引起不溶性过碳酸化产物的形成,该反应是自我控制的,并获得具有非常高的碱性值和碱土含量的高碱性产物的优异产率,而剩余的流体和稳定性。

    Fuel with low sulphur content for diesel engines
    2.
    发明授权
    Fuel with low sulphur content for diesel engines 有权
    用于柴油发动机的低硫含量的燃料

    公开(公告)号:US06592639B2

    公开(公告)日:2003-07-15

    申请号:US09147604

    申请日:1999-03-17

    IPC分类号: C10L118

    摘要: The invention concerns a fuel for diesel engines, with a sulphur content of less than 500 ppm containing in a major proportion at least one average distillate from a straight-run distilling cup of crude oil, with temperature ranges between 150 and 400° C. and in a minor proportion a lubricating additive containing monocarboxylic and polycyclic acids. The said fuel is characterized in that it contains at least 20 ppm of the additive consisting of at least one monocarboxylic aliphatic hydrocarbon, saturated or unsaturate, of linear chain between 12 and 14 carbon atoms, and at least one polcyclic hydrocarbon compound, containing at least two cycles each formed of 5 to 6 atoms one of which at most is optionally a heteroatom such as nitrogen or oxygen and the other atoms are carbon atoms, these two cycles having further two carbon atoms in common, preferably vicinal, these said cycles being saturated or unsaturated, substituted or non-substituted by at least one single grouping selected among the carboxylic, amine carboxyl, ester and nitrile groupings, the fuel containing more than 60 ppm of additive when the said combination is tall oil.

    摘要翻译: 本发明涉及用于柴油发动机的燃料,其硫含量小于500ppm,主要部分含有来自直馏蒸馏杯原油的至少一种平均馏出物,温度范围为150-400℃, 少量的含有单羧酸和多环酸的润滑添加剂。 所述燃料的特征在于其含有至少20ppm的添加剂,其由至少一种12至14个碳原子的直链的至少一种饱和或不饱和的单羧酸脂族烃和至少一种至少含有一个以上的环状烃化合物 两个循环各自由5至6个原子形成,其中一个最多为任选的杂原子,例如氮或氧,其它原子为碳原子,这两个循环具有共同的另外两个碳原子,优选连续的,这些所述循环是饱和的 或不饱和的,被选自羧基,胺羧基,酯和腈基中的至少一个单个取代基或不被取代的,当所述组合为妥尔油时,所述燃料含有大于60ppm的添加剂。

    Fuel with low sulphur content for diesel engines
    5.
    发明授权
    Fuel with low sulphur content for diesel engines 有权
    用于柴油发动机的低硫含量的燃料

    公开(公告)号:US07374589B2

    公开(公告)日:2008-05-20

    申请号:US10446851

    申请日:2003-05-29

    IPC分类号: C10L1/22 C10L1/18

    摘要: The invention concerns a fuel for diesel engines, with a sulphur content of less than 500 ppm containing in a major proportion at least one average distillate from a straight-run distilling cup of crude oil, with temperature ranges between 150 and 400° C. and in a minor proportion a lubricating additive containing monocarboxylic and polycyclic acids. The said fuel is characterized in that it contains at least 20 ppm of the additive consisting of at least one monocarboxylic aliphatic hydrocarbon, saturated or unsaturated, of linear chain between 12 and 14 carbon atoms, and at least one polcyclic hydrocarbon compound, containing at least two cycles each formed of 5 to 6 atoms one of which at most is optionally a heteroatom such as nitrogen or oxygen and the other atoms are carbon atoms, these two cycles having further two carbon atoms in common, preferably vicinal, these said cycles being saturated or unsaturated, substituted or non-substituted by at least one single grouping selected among the carboxylic, amine carboxyl, ester and nitrile groupings, the fuel containing more than 60 ppm of additive when the said combination is tall oil.

    摘要翻译: 本发明涉及用于柴油发动机的燃料,其硫含量小于500ppm,主要部分含有来自直馏蒸馏杯原油的至少一种平均馏出物,温度范围为150-400℃, 少量的含有单羧酸和多环酸的润滑添加剂。 所述燃料的特征在于其含有至少20ppm的添加剂由至少一种饱和或不饱和的12至14个碳原子的直链的单羧酸脂族烃和至少一种至少含有一个以上的多环烃化合物 两个循环各自由5至6个原子形成,其中一个最多为任选的杂原子,例如氮或氧,其它原子为碳原子,这两个循环具有共同的另外两个碳原子,优选连续的,这些所述循环是饱和的 或不饱和的,被选自羧基,胺羧基,酯和腈基中的至少一个单个取代基或不被取代的,当所述组合为妥尔油时,所述燃料含有大于60ppm的添加剂。