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1.发明授权
公开(公告)号：US4965318A
公开(公告)日：1990-10-23
申请号：US218977
申请日：1988-07-14
摘要： Thermoplastic molding materials contain(A) from 5 to 95% by weight of a nylon and(B) from 5 to 95% by weight of a copolymer composed of(B.sub.1) from 50 to 99.9% by weight of a styrene of the general formula I ##STR1## where R.sup.1 is alkyl or 1 to 4 carbon atoms or hydrogen, R.sup.2 is alkyl of 1 to 6 carbon atoms or halogen and m is 0, 1, 2 or 3,(B.sub.2) from 0.1 to 30% by weight of a monomer containing epoxide groups (II) ##STR2## or of a monomer containing lactam groups (III) ##STR3## or of a monomer containing halobenzyl groups (IV) ##STR4## where R.sup.3 is a divalent, branched or straight-chain alkyl group of 2 to 15 carbon atoms, R.sup.4 is alkyl of not more than 6 carbon atoms, X is halogen, n is 1, 2 or 3 and r is 0, 1, 2 or 3, and(B.sub.3) from 0 to 48% by weight of further comonomers.
摘要翻译： 热塑性成型材料含有（A）5至95重量％的尼龙和（B）5至95重量％的由（B1）50-99.9重量％的通式 （I）其中R1是烷基或1-4个碳原子或氢，R2是1至6个碳原子的烷基或卤素，m是0,1,2或3，（B2）0.1-30％ （II）或含有内酰胺基团（III）的单体（III）或含有卤代苄基（IV）的单体的单体（Ⅳ）其中 R3是2至15个碳原子的二价，支链或直链烷基，R4是不大于6个碳原子的烷基，X是卤素，n是1,2或3，r是0,1,2或 3和（B3）0至48重量％的另外的共聚单体。
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2.发明授权Thermoplastic molding materials based on polyphenylene ethers, nylons and styrene copolymers 失效基于聚苯醚，尼龙和苯乙烯共聚物的热塑性成型材料
公开(公告)号：US4959415A
公开(公告)日：1990-09-25
申请号：US179991
申请日：1988-04-11
CPC分类号： C08L53/02 , C08L71/123 , C08L77/00 , C08L67/00 , Y10S525/905
摘要： Thermoplastic molding materials containing(A) not less than 5% by weight of a polyphenylene ether and(B) not less than 5% by weight of a nylon furthermore contain(C) not less than 0.1% by weight of a copolymer composed of(C.sub.1) not less than 30% by weight of a styrene of the general formula I ##STR1## where R and R.sup.1 are alkyl of 1 to 8 carbon atoms, hydrogen and/or halogen and n is 0, 1, 2 or 3,(C.sub.2) not less than 0.5% by weight of an epoxide-containing polymerizable monomer and/or(C.sub.3) not less than 0.05% by weight of a halobenzyl-containing polymerizable monomer possessing a structural unit (II) ##STR2## where X is halogen, R.sup.2 and R.sup.3 are each alkyl of 1 to 8 carbon atoms or hydrogen and n is 1, 2 or 3, and/or(C.sub.4) not less than 0.05% by weight of a polymerizable monomer containing oxazoline groups and(C.sub.5) from 0 to 20% by weight of acrylonitrile, methacrylonitrile and/or other nonionic comonomers, and(D) from 0 to 35% by weight of a toughened rubber, and possess particularly good impact strength.
摘要翻译： 含有（A）不小于5重量％的聚苯醚的热塑性成型材料和（B）不小于5重量％的尼龙，还含有（C）不小于0.1重量％的由（ C1）不小于30重量％的通式I（I）的苯乙烯，其中R和R 1是1至8个碳原子的烷基，氢和/或卤素，n是0,1,2或 3，（C2）不小于0.5重量％的含环氧化物的可聚合单体和/或（C3）不少于0.05重量％的具有结构单元（II）的卤代苄基的可聚合单体（IMAGE） II）其中X是卤素，R2和R3各自为1-8个碳原子的烷基或氢，n为1,2或3，和/或（C4）不小于0.05重量％的含有恶唑啉基团的可聚合单体 和（C5）0至20重量％的丙烯腈，甲基丙烯腈和/或其它非离子共聚单体，和（D）0至35重量％的增韧橡胶，并且具有特定的 良好的冲击强度。
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公开(公告)号：US4774286A
公开(公告)日：1988-09-27
申请号：US2238
申请日：1987-01-12
IPC分类号： C08L67/00 , C08L7/00 , C08L21/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L67/02 , C08L69/00
摘要： Thermoplastic molding materials based on(A) polycarbonates and(B) polyesters containing from 1 to 30% by weight, based on (A)+(B)+(C),(C) of a graft copolymer based on(C.sub.1) from 60 to 99% by weight of an elastomeric component based on acrylic acid esters, methacrylic acid esters and/or conjugated dienes as well as, if desired, further comonomers, as graft base and(C.sub.2) from 1 to 40% by weight of an expoxy-containing monomer as applied graft.
摘要翻译： 基于（A）聚碳酸酯和（B）含有1至30重量％的基于（A）+（B）+（C），（C）的基于（C1）的接枝共聚物的聚酯的热塑性模塑材料 60至99重量％的基于丙烯酸酯，甲基丙烯酸酯和/或共轭二烯的弹性体组分，以及如果需要，作为接枝基的另外的共聚单体，和（C2）1至40重量％ 含环氧基的单体作为移植物。
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公开(公告)号：US4618633A
公开(公告)日：1986-10-21
申请号：US772662
申请日：1985-09-05
摘要： A halogen-free self-extinguishing thermoplastic composition comprising as the flame retardant, one or more phosphorus-containing compounds or elemental phosphorous, a polyphenylene ether, a styrene-acrylonitrile copolymer, a phenol/aldehyde resin, a terpolymer of styrene, acrylonitrile and a hydroxy-containing ester of acrylic or methacrylic acid on which a polyphenylene ether is grafted, and optionally, a diene elastomer having grafted thereon styrene and acrylonitrile monomers.
摘要翻译： 一种无卤自熄型热塑性组合物，其包含阻燃剂，一种或多种含磷化合物或元素磷，聚苯醚，苯乙烯 - 丙烯腈共聚物，苯酚/醛树脂，苯乙烯，丙烯腈和 含有聚苯醚的丙烯酸或甲基丙烯酸的含羟基酯，以及任选地，其上接枝有苯乙烯和丙烯腈单体的二烯弹性体。
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公开(公告)号：US4797453A
公开(公告)日：1989-01-10
申请号：US63687
申请日：1987-06-19
IPC分类号： C08F283/06 , C08F283/08 , C09D151/08 , C08L71/02
CPC分类号： C09D151/08 , C08F283/08
摘要： Graft polymers of(A) a polyphenylene ether as a base polymer and(B) a half ester of an unsaturated dicarboxylic acid of the general formula ##STR1## as a graft monomer, where R.sup.1 is C.sub.1 -C.sub.25 -alkyl, C.sub.2 -C.sub.25 -alkylene or aryl, R.sup.2 and R.sup.3 are each H, Br, Cl or one of the radicals R.sup.1, and Q is H or an alkali metal, an alkaline earth metal or an ammonium cation,with or without(C) further olefinically unsaturated monomers,and their preparation.
摘要翻译： （A）聚苯醚作为基础聚合物的接枝聚合物和（B）作为接枝单体的通式为不饱和二羧酸的半酯，其中R 1是C 1 -C 25烷基，C 2 -C 25 - 亚烷基或芳基，R 2和R 3各自为H，Br，Cl或基团R 1中的一个，Q为H或碱金属，碱土金属或铵阳离子，具有或不具有（C）另外的烯属不饱和单体 ，及其准备。
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6.发明授权
公开(公告)号：US5019626A
公开(公告)日：1991-05-28
申请号：US161135
申请日：1988-02-26
CPC分类号： C08L71/12 , C08L67/00 , Y10S525/905
摘要： Thermoplastic molding materials contain, as essential components,A) 5-92% by weight of a polyphenylene ether which can contain up to 50% by weight of a styrene polymer which differs from C),B) 5-92% by weight of a nylon,C) 3-50% by weight of a copolymer composed of C.sub.1) 97-99.9% by weight of styrene and/or substituted styrenes of the general formula I ##STR1## where R is hydrogen, alkyl of 1 to 8 carbon atoms or halogen, R.sup.1 is alkyl of 1 to 8 carbon atoms or halogen and n is 0, 1, 2 or 3,C.sub.2) 0.1-3% by weight of an .alpha.,.beta.-unsaturated dicarbonyl compound andC.sub.3) 0-10% by weight of further, nonionic comonomers, andD) 0-35% by weight of a rubber impact modifier.
摘要翻译： 热塑性成型材料作为必要组分含有A）5-92重量％的聚苯醚，其可以含有至多50重量％的与C）不同的苯乙烯聚合物，B）5-92重量％的 尼龙，C）3-50重量％的由C1）97-99.9重量％的苯乙烯和/或通式I（I）的取代苯乙烯组成的共聚物，其中R是氢，1至 8个碳原子或卤素，R1是1至8个碳原子的烷基或卤素，n是0,1,2或3，C2）0.1-3重量％的α，β-不饱和二羰基化合物和C3）0- 10重量％的另外的非离子共聚单体，和D）0-35重量％的橡胶抗冲改性剂。
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7.发明授权
公开(公告)号：US4962157A
公开(公告)日：1990-10-09
申请号：US209210
申请日：1988-06-20
CPC分类号： C08L67/02 , C08L71/123 , C08L67/00 , Y10S525/905
摘要： Thermoplastic molding materials contain(A) not less than 5% by weight of a polymer component consisting of from 50 to 10 % by weight by polyphenylene ethers and from 0 to 50% by weight of a styrene polymer differing from component (C),(B) not less than 5% by weight of a polyester,(C) not less than 0.1% by weight of a copolymer consisting of(C.sub.1) not less than 20% by weight of .alpha.-olefins of 2 to 8 carbon atoms, styrene or substituted styrenes of the general formula I ##STR1## where R and R.sup.1 is alkyl of 1 to 8 carbon atoms, hydrogen and/or halogen and n is 0, 1 or 2, or a mixture of these monomers,(C.sub.2) not less than 0.5% by weight of a polymerizable monomer containing epoxide groups,and/or(C.sub.3) not less than 0.05% by weight of a halobenzyl-containing polymerizable monomer having the structural unit (II) ##STR2## where X is halogen and R.sup.2 and R.sup.3 are each alkyl of 1 to 8 carbon atoms or hydrogen and n is 1, 2 or 3,and/or(C.sub.4) not less than 0.05% by weight of a polymerizable monomer containing oxazoline groups,and(C.sub.5) from 0 to 65% by weight of acrylonitrile, methacrylonitrile and further nonionic comonomers, and(D) from 0 to 40% by weight of a rubber impact modifier.
摘要翻译： 热塑性成型材料含有（A）不少于5重量％的由聚苯醚组成的聚合物组分50至10重量％和0至50重量％不同于组分（C）的苯乙烯聚合物，（C） B）不小于5重量％的聚酯，（C）不小于0.1重量％的由（C1）不低于20重量％的2-8个碳原子的α-烯烃组成的共聚物，苯乙烯 或通式I的取代苯乙烯（I）其中R和R 1是1至8个碳原子的烷基，氢和/或卤素和n是0,1或2，或这些单体的混合物（C2 ）不小于0.5重量％的含有环氧基的可聚合单体，和/或（C3）不小于0.05重量％的具有结构单元（II）的卤代苄基的可聚合单体（II）其中 X是卤素，R 2和R 3各自是1至8个碳原子的烷基或氢，n是1,2或3，和/或（C 4）不小于0.05重量％的聚合物 包含恶唑啉基的单体，和（C5）0至65重量％的丙烯腈，甲基丙烯腈和其它非离子共聚单体，和（D）0至40重量％的橡胶抗冲改性剂。
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8.发明授权
公开(公告)号：US4943399A
公开(公告)日：1990-07-24
申请号：US349968
申请日：1989-05-08
IPC分类号： C08J3/20 , C08F283/08 , C08G65/48 , C08L71/12 , C08L77/00
CPC分类号： C08L71/126 , C08F283/08 , C08G65/485 , C08L77/00 , Y10S525/905
摘要： Thermoplastic molding materials based on polyphenylene ethers and nylons are prepared in an extruder by a continuous process in which a modified polyphenylene ether is prepared in a first zone of the extruder and is then mixed with nylons and, if required, further additives in one or more further zones.
摘要翻译： 在挤出机中通过连续方法制备基于聚苯醚和尼龙的热塑性成型材料，其中在挤出机的第一区域中制备改性聚苯醚，然后与尼龙混合，如果需要，在一个或多个 进一步的区域。
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公开(公告)号：US4780509A
公开(公告)日：1988-10-25
申请号：US43492
申请日：1987-04-28
IPC分类号： C08F285/00 , C08F257/02
CPC分类号： C08F285/00
摘要： Impact-resistant thermoplastic molding materials based on a resin A containing one or more vinylaromatic monomers are prepared by reacting the resin A (component A) with one or more monomers from the group consisting of the .alpha.,.beta.-unsaturated dicarbonyl compounds (component B) by a process in which the reaction is carried out in a melt of A in the presence of B and in the absence of initiators, and the resin A used is one which contains from 3 to 50% by weight, based on A, of one or more elastomers a.sub.1 (rubber) and has been prepared in a conventional manner by polymerizing one or more vinylaromatic monomers of 8 to 12 carbon atoms in the presence of the elastomer a.sub.1 are used for the production of moldings.
摘要翻译： 基于含有一种或多种乙烯基芳族单体的树脂A的耐冲击热塑性成型材料通过使树脂A（组分A）与一种或多种来自α，β-不饱和二羰基化合物（组分B）的单体反应制备， 通过在B的存在下和不存在引发剂的情况下在A的熔体中进行反应的方法，所用的树脂A是含有基于A的3至50重量％的树脂A，其中A为 或更多的弹性体a1（橡胶），并且在弹性体a1的存在下通过聚合一种或多种具有8至12个碳原子的乙烯基芳族单体以常规方式制备，用于制备模制品。
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10.发明授权
公开(公告)号：US5180778A
公开(公告)日：1993-01-19
申请号：US574073
申请日：1990-08-29
CPC分类号： C08L67/02 , C08L71/123 , C08L67/00 , Y10S525/905
摘要： Thermoplastic molding materials containA) not less than 5% by weight of a polymer component consisting of from 50 to 100% by weight of polyphenylene ethers and from 0 to 50% by weight of a styrene polymer differing from component C),B) not less than 5% by weight of a polyester,C) not less than 0.1% by weight of a copolymer consisting ofC.sub.1) not less than 20% by weight of .alpha.-olefins of 2 to 8 carbon atoms, styrene or substituted styrenes of the general formula I ##STR1## where R and R.sup.1 is alkyl of 1 to 8 carbon atoms, hydrogen and/or halogen and n is 0, 1 or 2, or a mixture of these monomers,C.sub.2) not less than 0.5% by weight of a polymerizable monomer containing epoxide groups, and/orC.sub.3) not less than 0.05% by weight of a halobenzyl-containing polymerizable monomer having the structural unit (II) ##STR2## where X is halogen and R.sup.2 and R.sup.3 are each alkyl of 1 to 8 carbon atoms or hydrogen and n is 1, 2 or 3, and/orC.sub.4) not less than 0.05% by weight of a polymerizable monomer containing oxazoline groups, andC.sub.5) from 0 to 65% by weight of acrylonitrile, methacrylonitrile and further nonionic comonomers, andD) from 0 to 40% by weight of a rubber impact modifier.
摘要翻译： 热塑性成型材料包含A）不小于5重量％的由50至100重量％的聚苯醚和0至50重量％的不同于组分C）的苯乙烯聚合物组成的聚合物组分，B）不 小于5重量％的聚酯，C）不小于0.1重量％的由C1组成的共聚物，不少于20重量％的碳原子数2〜8的α-烯烃，苯乙烯或苯乙烯的取代苯乙烯 通式I其中R和R 1是1至8个碳原子的烷基，氢和/或卤素，n是0,1或2，或这些单体的混合物，C2）不小于0.5％ 重量的含有环氧基的可聚合单体和/或C3）不少于0.05重量％的具有结构单元（II）的卤代苄基的可聚合单体（II），其中X是卤素，R 2和R 3 各自为1至8个碳原子的烷基或氢，n为1,2或3，和/或C 4）不小于0.05重量％的可聚合单体 r为0〜65重量％的丙烯腈，甲基丙烯腈和其它非离子共聚单体，和D）0〜40重量％的橡胶抗冲改性剂。
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