公开(公告)号：US11820706B2

公开(公告)日：2023-11-21

申请号：US17490633

申请日：2021-09-30

Applicant: CORNING INCORPORATED

Inventor： Matthew John Dejneka ,  Benjamin Zain Hanson ,  Alexander I Priven

IPC: C03C3/097 ,  C03C3/087 ,  G06F1/16 ,  C03C21/00 ,  C03C3/091 ,  C03C3/093

CPC classification number: C03C3/097 ,  C03C3/087 ,  C03C3/091 ,  C03C3/093 ,  C03C21/002 ,  G06F1/1626 ,  G06F1/1637 ,  G06F2200/1634

Abstract: The embodiments described herein relate to glass articles that include mechanically durable glass compositions having high liquidus viscosity. The glass articles may include glass compositions having from 50 mol. % to 80 mol. % SiO2; from 7 mol. % to 25 mol. % Al2O3; from 2 mol. % to about 14 mol. % Li2O; 0.4 mol. % P2O5; and less than or equal to 0.5 mol. % ZrO2. The quantity (Al2O3 (mol. %)-R2O (mol. %)-RO (mol. %)) is greater than zero, where R2O (mol. %) is the sum of the molar amounts of Li2O, Na2O, K2O, Rb2O, and Cs2O in the glass composition and RO (mol. %) is the sum of the molar amounts of BeO, MgO, CaO, SrO, BaO, and ZnO in the glass composition. A molar ratio of (Li2O (mol. %))/(R2O (mol. %)) may be greater or equal to 0.5. In embodiments, the glass composition may include B2O3. The glass compositions are fusion formable and have high damage resistance.

公开(公告)号：US09815728B2

公开(公告)日：2017-11-14

申请号：US14595805

申请日：2015-01-13

Applicant: CORNING INCORPORATED

Inventor： Matthew John Dejneka ,  Benjamin Zain Hanson ,  Thomas Dale Ketcham

IPC: C03B5/43 ,  C03B17/06 ,  C04B35/10

CPC classification number: C03B17/064 ,  C03B5/43 ,  C03C3/091 ,  C04B35/10 ,  C04B2235/3201 ,  C04B2235/3206 ,  C04B2235/3208 ,  C04B2235/3222 ,  C04B2235/3232 ,  C04B2235/3241 ,  C04B2235/3244 ,  C04B2235/3272 ,  C04B2235/3284 ,  C04B2235/3286 ,  C04B2235/3293 ,  C04B2235/3409 ,  C04B2235/3418 ,  C04B2235/449 ,  C04B2235/72 ,  C04B2235/80 ,  C04B2235/81 ,  C04B2235/95 ,  Y02P40/57

Abstract: Isopipes (13) for making glass sheets using a fusion process are provided. The isopipes are made from alumina materials which have low levels of the elements of group IVB of the periodic chart, i.e., Ti, Zr, and Hf, as well as low levels of Sn. In this way, the alumina isopipes can be used with glasses that contain tin (e.g., as a fining agent or as the result of the use of tin electrodes for electrical heating of molten glass) without generating unacceptable levels of tin-containing defects in the glass sheets, specifically, at the sheets' fusion lines. The alumina isopipes disclosed herein are especially beneficial when used with tin-containing glasses that exhibit low tin solubility, e.g., glasses that have (RO+R2O)/Al2O3 ratios between 0.9 and 1.1, where, in mole percent on an oxide basis, (RO+R2O) is the sum of the concentrations of the glass' alkaline earth and alkali metal oxides and Al2O3 is the glass' alumina concentration.

公开(公告)号：US20160340222A1

公开(公告)日：2016-11-24

申请号：US15111658

申请日：2015-01-12

Applicant: CORNING INCORPORATED

Inventor： Matthew John Dejneka ,  Benjamin Zain Hanson ,  Thomas Dale Ketcham ,  James Robert Rustad ,  Susan Lee Schiefelbein ,  Kochuparambil Deenamma Vargheese

IPC: C03B17/06 ,  C04B41/00 ,  C04B35/48 ,  C04B35/10 ,  C04B41/85 ,  C04B41/50

CPC classification number: C03B17/064 ,  C04B35/10 ,  C04B35/113 ,  C04B35/185 ,  C04B35/443 ,  C04B35/48 ,  C04B35/481 ,  C04B35/66 ,  C04B41/0072 ,  C04B41/5072 ,  C04B41/85 ,  C04B2235/656 ,  C04B2235/6567 ,  C04B2235/6582 ,  C04B2235/6584 ,  C04B2235/6587 ,  C04B2235/664 ,  C04B2235/85

Abstract: A method of making a glass sheet includes exposing a refractory block material comprising at least one multivalent component to a reducing atmosphere for a time and at a temperature sufficient to substantially reduce the at least one multivalent component of the refractory block material. The method also includes flowing molten glass over the refractory block material that has been exposed to the reducing atmosphere while preventing substantial re-oxidation of the at least one multivalent component.

Abstract translation: 制造玻璃板的方法包括将包含至少一种多价成分的耐火块材料暴露于还原性气氛中一段时间​​和足以基本上减少耐火材料块的至少一种多价成分的温度。 该方法还包括将熔融玻璃流过已经暴露于还原气氛的耐火块材料，同时防止至少一种多价成分的显着再氧化。

公开(公告)号：US20140227524A1

公开(公告)日：2014-08-14

申请号：US14174309

申请日：2014-02-06

Applicant: Corning Incorporated

Inventor： Adam James Ellison ,  Benjamin Zain Hanson ,  Rostislav Vatchev Roussev

IPC: C03C21/00

CPC classification number: C03C21/002 ,  C03C3/091 ,  Y10T428/315

Abstract: Ion exchangeable glass compositions that develop concentration profiles and stress profiles that have higher magnitudes of concentration and compressive stress profiles than those provided by the error function (erfc)-shaped compressive stress profile for similar surface concentrations of stress-inducing components such as K+ or K2O and stresses. The advantaged stress profile is the result of a glass composition that is low in K2O (or potassium) in the base glass prior to ion exchange. A glass comprising lower amounts of K+ or K2O has a stronger dependence of diffusivity on concentration, leading to a non-erfc-shaped concentration profile. Several glass compositions that contain low amounts of K+ or K2O exhibit this beneficial effect, whereas other glasses containing higher amounts of K+ or K2O do not exhibit this effect.

Abstract translation: 离子交换玻璃组合物，其形成具有比用于类似表面浓度的应力诱导组分如K +或K2O的误差函数（erfc）形压缩应力分布提供的浓度分布和应力分布更高的浓度分布和压应变曲线 并强调。 有利的应力分布是在离子交换之前在基础玻璃中的K 2 O（或钾）低的玻璃组合物的结果。 包含较低量的K +或K2O的玻璃具有较强的扩散性对浓度的依赖性，导致非erfc形浓度分布。 含有少量K +或K2O的几种玻璃组合物表现出这种有益效果，而含有较高量的K +或K2O的其它玻璃没有表现出这种效果。

公开(公告)号：US10435323B2

公开(公告)日：2019-10-08

申请号：US15111658

申请日：2015-01-12

Applicant: Corning Incorporated

Inventor： Matthew John Dejneka ,  Benjamin Zain Hanson ,  Thomas Dale Ketcham ,  James Robert Rustad ,  Susan Lee Schiefelbein ,  Kochuparambil Deenamma Vargheese

IPC: C03B17/06 ,  C04B35/113 ,  C04B35/185 ,  C04B35/443 ,  C04B35/48 ,  C04B35/66 ,  C04B35/10 ,  C04B41/00 ,  C04B41/50 ,  C04B41/85

Abstract: A method of making a glass sheet includes exposing a refractory block material comprising at least one multivalent component to a reducing atmosphere for a time and at a temperature sufficient to substantially reduce the at least one multivalent component of the refractory block material. The method also includes flowing molten glass over the refractory block material that has been exposed to the reducing atmosphere while preventing substantial re-oxidation of the at least one multivalent component.

公开(公告)号：US20190127265A1

公开(公告)日：2019-05-02

申请号：US16175016

申请日：2018-10-30

Applicant: CORNING INCORPORATED

Inventor： Matthew John Dejneka ,  Benjamin Zain Hanson ,  Alexander I. Priven

IPC: C03C3/097 ,  C03C3/087 ,  G06F1/16

Abstract: The embodiments described herein relate to glass articles that include mechanically durable glass compositions having high liquidus viscosity. The glass articles may include glass compositions having from 50 mol. % to 80 mol. % SiO2; from 7 mol. % to 25 mol. % Al2O3; from 2 mol. % to about 14 mol. % Li2O; 0.4 mol. % P2O5; and less than or equal to 0.5 mol. % ZrO2. The quantity (Al2O3 (mol. %)−R2O (mol. %)−RO (mol. %)) is greater than zero, where R2O (mol. %) is the sum of the molar amounts of Li2O, Na2O, K2O, Rb2O, and Cs2O in the glass composition and RO (mol. %) is the sum of the molar amounts of BeO, MgO, CaO, SrO, BaO, and ZnO in the glass composition. A molar ratio of (Li2O (mol. %))/(R2O (mol. %)) may be greater or equal to 0.5. In embodiments, the glass composition may include B2O3. The glass compositions are fusion formable and have high damage resistance.

公开(公告)号：US10047000B2

公开(公告)日：2018-08-14

申请号：US15111682

申请日：2015-01-12

Applicant: Corning Incorporated

Inventor： Matthew John Dejneka ,  Sinue Gomez ,  Benjamin Zain Hanson ,  James Robert Rustad ,  Susan Lee Schiefelbein ,  Kochuparambil Deenamma Vergheese

IPC: C03B17/06 ,  C04B41/00 ,  C04B35/48 ,  C04B41/50 ,  C04B41/85

Abstract: A method of making a glass sheet includes treating a refractory block material comprising at least one multivalent component with a vehicle comprising at least one redox altering component or precursor. The method also includes flowing molten glass over the refractory block material, wherein the treatment of the refractory block material with the vehicle comprising at least one redox altering component or precursor reduces the amount of oxygen production resulting from interaction between the at least one multivalent component and the molten glass.

公开(公告)号：US20150024210A1

公开(公告)日：2015-01-22

申请号：US14456354

申请日：2014-08-11

Applicant: Corning Incorporated

Inventor： Matthew John Dejneka ,  Adam James Ellison ,  Benjamin Zain Hanson

IPC: C03C3/093 ,  C03C3/083 ,  C03C21/00 ,  C03C3/087 ,  C03C4/18 ,  C03C3/091 ,  C03C3/085

CPC classification number: C03C3/083 ,  C03B17/064 ,  C03C3/085 ,  C03C3/087 ,  C03C3/091 ,  C03C3/093 ,  C03C4/18 ,  C03C21/00 ,  C03C21/002 ,  C03C2204/00 ,  Y10T428/315

Abstract: A glass that is down-drawable and ion exchangeable. The glass has a temperature T35kp which the viscosity is 35 kilopoise. T35kp is less than the breakdown temperature Tbreakdown of zircon.

Abstract translation: 一种可下拉和可离子交换的玻璃。 玻璃的温度T35kp，粘度为35千泊。 T35kp小于锆石的击穿温度。

公开(公告)号：US20240043316A1

公开(公告)日：2024-02-08

申请号：US18382781

申请日：2023-10-23

Applicant: CORNING INCORPORATED

Inventor： Matthew John Dejneka ,  Benjamin Zain Hanson ,  Alexander I. Priven

IPC: C03C3/097 ,  C03C3/087 ,  G06F1/16 ,  C03C21/00 ,  C03C3/091 ,  C03C3/093

CPC classification number: C03C3/097 ,  C03C3/087 ,  G06F1/1626 ,  G06F1/1637 ,  C03C21/002 ,  C03C3/091 ,  C03C3/093 ,  G06F2200/1634

Abstract: The embodiments described herein relate to glass articles that include mechanically durable glass compositions having high liquidus viscosity. The glass articles may include glass compositions having from 50 mol. % to 80 mol. % SiO2; from 7 mol. % to 25 mol. % Al2O3; from 2 mol. % to about 14 mol. % Li2O; 0.4 mol. % P2O5; and less than or equal to 0.5 mol. % ZrO2. The quantity (Al2O3 (mol. %)-R2O (mol. %)-RO (mol. %)) is greater than zero, where R2O (mol. %) is the sum of the molar amounts of Li2O, Na2O, K2O, Rb2O, and Cs2O in the glass composition and RO (mol. %) is the sum of the molar amounts of BeO, MgO, CaO, SrO, BaO, and ZnO in the glass composition. A molar ratio of (Li2O (mol. %))/(R2O (mol. %)) may be greater or equal to 0.5. In embodiments, the glass composition may include B2O3. The glass compositions are fusion formable and have high damage resistance.

公开(公告)号：US20220017405A1

公开(公告)日：2022-01-20

申请号：US17490633

申请日：2021-09-30

Applicant: CORNING INCORPORATED

Inventor： Matthew John Dejneka ,  Benjamin Zain Hanson ,  Alexander I Priven

IPC: C03C3/097 ,  C03C3/087 ,  G06F1/16 ,  C03C21/00 ,  C03C3/091 ,  C03C3/093

Abstract: The embodiments described herein relate to glass articles that include mechanically durable glass compositions having high liquidus viscosity. The glass articles may include glass compositions having from 50 mol. % to 80 mol. % SiO2; from 7 mol. % to 25 mol. % Al2O3; from 2 mol. % to about 14 mol. % Li2O; 0.4 mol. % P2O5; and less than or equal to 0.5 mol. % ZrO2. The quantity (Al2O3 (mol. %)-R2O (mol. %)-RO (mol. %)) is greater than zero, where R2O (mol. %) is the sum of the molar amounts of Li2O, Na2O, K2O, Rb2O, and Cs2O in the glass composition and RO (mol. %) is the sum of the molar amounts of BeO, MgO, CaO, SrO, BaO, and ZnO in the glass composition. A molar ratio of (Li2O (mol. %))/(R2O (mol. %)) may be greater or equal to 0.5. In embodiments, the glass composition may include B2O3. The glass compositions are fusion formable and have high damage resistance.