Abstract:
Adding silica particles having specified collective characteristics to a fluororubber formulation enhances direct adhesion between the fluororubber formulation and a copolymer upon curing. Specifically, as measured before being mixed into the fluororubber formulation, the silica particles have an average value of the product “(particle size)×(circularity)” that is 17.5 nm or higher and 500 μm or lower. The silica particles may also have an average particle size of between 25.0 nm inclusive and 500 μm inclusive, and an average circularity of 0.80 or higher. Alternatively, as measured after being incorporated into the fluororubber formulation and then cured, the silica particles have an apparent average value of the product “(particle size)×(circularity)” that is 32.0 nm or higher and 500 μm or lower. The silica particles may also have an apparent average particle size of between 40.0 nm inclusive and 500 μm inclusive as measured after being incorporated into the fluororubber formulation and then cured.
Abstract:
The invention provides a laminate in which a fluororesin layer and a rubber layer are firmly bonded to each other and the fluororesin layer has low fuel permeability and is less likely to suffer solvent cracking. The laminate includes a rubber layer (A) and a fluororesin layer (B). The fluororesin layer (B) contains a copolymer containing a chlorotrifluoroethylene unit, a tetrafluoroethylene unit, and a perfluoroalkyl vinyl ether unit. The copolymer contains 96.0 to 97.4 mol % of the chlorotrifluoroethylene unit and the tetrafluoroethylene unit relative to all the monomer units constituting the copolymer and 2.6 to 4.0 mol % of the perfluoroalkyl vinyl ether unit relative to all the monomer units constituting the copolymer.
Abstract:
A laminate including: a fluororesin layer (A) containing a fluororesin having a fuel permeability coefficient of 2.0 g·mm/m2/day or lower; and a fluorine-free resin layer (B) containing a fluorine-free resin having a SP value of 11.5 to 13.5 (cal/cm3)1/2 and a fuel permeability coefficient of 1.0 g·mm/m2/day or lower.
Abstract:
The invention provides a laminate having high elastic modulus retention even at high temperature and having moderate hardness. The laminate includes a layer (A) formed from a fluororesin and a layer (B) formed from a polyamide resin. The fluororesin is a copolymer containing a copolymerized unit of tetrafluoroethylene and a copolymerized unit of vinylidene fluoride, and has a storage elastic modulus (E′) of 60 to 400 MPa measured by dynamic mechanical analysis at 170° C.
Abstract:
The present invention aims to provide a laminate in which a fluororesin layer and a fluororubber layer are firmly bonded. The present invention relates to a laminate including: a fluororubber layer (A); and a fluororesin layer (B) stacked on the fluororubber layer (A), the fluororubber layer (A) being formed from a fluororubber composition, the fluororubber composition containing a fluororubber, a low molecular weight polytetrafluoroethylene, and a multifunctional compound, the amount of the multifunctional compound being 5 parts by mass or more relative to 100 parts by mass of the fluororubber.
Abstract:
A laminate including: a rubber layer (A); and a fluororesin layer (B) laminated on the rubber layer (A), the rubber layer (A) being formed of a rubber composition for vulcanization containing: at least one unvulcanized rubber (a1) selected from acrylonitrile-butadiene rubber and its hydride, styrene-butadiene rubber, chloroprene rubber, butadiene rubber, natural rubber, isoprene rubber, ethylene-propylene-termonomer-copolymer rubber, silicone rubber, butyl rubber, and acrylic rubber; at least one compound (a2) selected from 1,8-diazabicyclo(5.4.0)undec-7-ene salts, 1,5-diazabicyclo(4.3.0)-non-5-ene salts, 1,8-diazabicyclo(5.4.0)undec-7-ene, and 1,5-diazabicyclo(4.3.0)-non-5-ene; at least one compound (a3) selected from aldehyde-amine compounds and metal hydrates; magnesium oxide (a4); and silica (a5), the fluororesin layer (B) being formed of a fluoropolymer composition containing a fluoropolymer (b1) having a copolymer unit derived from chlorotrifluoroethylene.
Abstract:
The present invention provides a flexible pipe having excellent blister resistance in a high-temperature and high-pressure environment even though including a thick resin pipe. The flexible pipe includes a resin pipe having a thickness of greater than 5 mm. The resin pipe is formed from a resin having a CO2 permeability coefficient P(CO2) of 20×10−9 cm3·cm/cm2·s·cmHg or lower at 150° C., a CH4 permeability coefficient P(CH4) of 10×10−9 cm3·cm/cm2·s·cmHg or lower at 150° C., a ratio D(CO2)/S(CO2) between a CO2 diffusion coefficient D(CO2) and a CO2 solubility coefficient S(CO2) of 3×10−5 Pa·m2/s or higher at 150° C., and a ratio D(CH4)/S(CH4) between a CH4 diffusion coefficient D(CH4) and a CH4 solubility coefficient S(CH4) of higher than 15×10−5 Pa·m2/s at 150° C.
Abstract:
Provided is a double-sided circuit substrate being a laminate of: a composite material comprising a fluorine resin and a glass cloth; and a copper foil having a two-dimensional roughness Ra in a mat surface (a surface that comes in contact with the resin) of less than 0.2 μm. Ideally, a surface of the fluorine resin has an O content of at least 1.0%, as observed using ESCA.
Abstract:
There is provided a method for producing a PCTFE film having excellent moisture resistance, good tensile elongation, and excellent formability. Provided is a method for producing a polychlcrotrifluoroethylene film, the method including step (1) of melting and molding polychlorotrifluoroethylene into a film, step (2) of maintaining the formed film at a temperature of 100° C. to 170° C., and step (3) of cooling the film to room temperature after the maintaining, wherein the temperature of the film is not allowed to be 170° C. or lower during an interval between step (1) and step (2).
Abstract:
Provided is a fiber-reinforced composite material having a greater maximum stress, maximum elongation, and tensile modulus, which are determined by a tensile test, than conventional fiber-reinforced composite materials containing a fluororesin as a matrix. The invention relates to a fiber-reinforced composite material including a fluororesin and a reinforcing fiber, the fluororesin containing a tetrafluoroethylene unit and a vinylidene fluoride unit, the tetrafluoroethylene unit representing 55 to 95 mol % of all the monomer units constituting the fluororesin, the vinylidene fluoride unit representing 45 to 5 mol % of all the monomer units constituting the fluororesin.