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公开(公告)号：US10081643B2
公开(公告)日：2018-09-25
申请号：US15508563
申请日：2015-11-06
IPC分类号： C07F7/12 , B01J23/889 , B01J23/86 , B01J23/89 , B01J23/745 , B01J23/75 , B01J23/755 , B01J37/02 , B01J38/42 , C08G77/60 , C01B33/033 , B01J37/18 , B01J21/18 , B01J23/70
CPC分类号： C07F7/126 , B01J21/18 , B01J23/70 , B01J23/745 , B01J23/75 , B01J23/755 , B01J23/868 , B01J23/8892 , B01J23/8926 , B01J23/8946 , B01J23/8986 , B01J37/0201 , B01J37/0205 , B01J37/0236 , B01J37/024 , B01J37/16 , B01J37/18 , B01J38/42 , C01B33/033 , C07F7/12 , C07F7/122 , C08G77/60
摘要： A method for preparing a reaction product including an aryl-functional silane includes sequential steps (1) and (2). Step (1) is contacting, under silicon deposition conditions, (A) an ingredient including (I) a halosilane such as silicon tetrahalide and optionally (II) hydrogen (H2); and (B) a metal combination comprising copper (Cu) and at least one other metal, where the at least one other metal is selected from the group consisting of gold (Au), cobalt (Co), chromium (Cr), iron (Fe), magnesium (Mg), manganese (Mn), nickel (Ni), palladium (Pd), and silver (Ag); thereby forming a silicon alloy catalyst comprising Si, Cu and the at least one other metal. Step (2) is contacting the silicon alloy catalyst and (C) a reactant including an aryl halide under silicon etching conditions.
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公开(公告)号：US20150191832A1
公开(公告)日：2015-07-09
申请号：US14410776
申请日：2013-06-26
发明人： Dimitris Katsoulis , Robert Larsen , Robert Morgan
CPC分类号： C25B1/18 , C01B33/043 , C01B33/06 , C25B1/14 , C25B1/26
摘要： An electrolytic process may be used to generate reactive metal silicides with Group 1 metals of the periodic table and/or Group 2 metals of the periodic table, and/or aluminum. Exemplary reactive metal silicides include magnesium silicide (Mg2Si).
摘要翻译： 可以使用电解方法来生成与元素周期表中的第1族金属和/或周期表的第二族金属和/或铝的反应性金属硅化物。 示例性的活性金属硅化物包括硅化镁（Mg 2 Si）。
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3.发明申请Method of Selectively Forming a Reaction Product in the Presence of a Metal Silicide 有权在金属硅化物存在下选择性形成反应产物的方法公开(公告)号：US20130334459A1
公开(公告)日：2013-12-19
申请号：US13688813
申请日：2012-11-29
CPC分类号： C07F7/0803 , C07F7/0805 , C07F7/0827 , C07F7/0896 , C07F7/125 , C07F7/21 , C08G77/60 , C08L83/16
摘要： A reaction product is formed utilizing a method that includes the step of combining a metal silicide and an aliphatic hydrocarbyl halide at a temperature of from 200° C. to 600° C. The aliphatic hydrocarbyl halide has the formula HaCbXc, wherein a is 0 or more, b is 1 or more, c is one or more, and X is halo. The method allows the reaction product to be formed in a predictable and controlled manner. Moreover, the components used in this method can be easily recycled and/or re-used in other processes.
摘要翻译： 使用包括在200℃至600℃的温度下组合金属硅化物和脂族烃基卤化物的步骤的方法形成反应产物。脂族烃基卤化物具有式HaCbXc，其中a为0或 更多的是，b为1以上，c为1以上，X为卤素。 该方法允许以可预测和受控的方式形成反应产物。 此外，在该方法中使用的组分可以容易地在其他方法中再循环和/或再次使用。
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公开(公告)号：US09469909B2
公开(公告)日：2016-10-18
申请号：US14410776
申请日：2013-06-26
发明人： Dimitris Katsoulis , Robert Larsen , Robert Morgan
CPC分类号： C25B1/18 , C01B33/043 , C01B33/06 , C25B1/14 , C25B1/26
摘要： An electrolytic process may be used to generate reactive metal silicides with Group 1 metals of the periodic table and/or Group 2 metals of the periodic table, and/or aluminum. Exemplary reactive metal silicides include magnesium silicide (Mg2Si).
摘要翻译： 可以使用电解方法来生成与元素周期表中的第1族金属和/或周期表的第二族金属和/或铝的反应性金属硅化物。 示例性的活性金属硅化物包括硅化镁（Mg 2 Si）。
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5.发明授权Method of selectively forming a reaction product in the presence of a metal silicide 有权在金属硅化物的存在下选择性地形成反应产物的方法公开(公告)号：US08865850B2
公开(公告)日：2014-10-21
申请号：US13688813
申请日：2012-11-29
CPC分类号： C07F7/0803 , C07F7/0805 , C07F7/0827 , C07F7/0896 , C07F7/125 , C07F7/21 , C08G77/60 , C08L83/16
摘要： A reaction product is formed utilizing a method that includes the step of combining a metal silicide and an aliphatic hydrocarbyl halide at a temperature of from 200° C. to 600° C. The aliphatic hydrocarbyl halide has the formula HaCbXc, wherein a is 0 or more, b is 1 or more, c is one or more, and X is halo. The method allows the reaction product to be formed in a predictable and controlled manner. Moreover, the components used in this method can be easily recycled and/or re-used in other processes.
摘要翻译： 使用包括在200℃至600℃的温度下组合金属硅化物和脂族烃基卤化物的步骤的方法形成反应产物。脂族烃基卤化物具有式HaCbXc，其中a为0或 更多的是，b为1以上，c为1以上，X为卤素。 该方法允许以可预测和受控的方式形成反应产物。 此外，在该方法中使用的组分可以容易地在其他方法中再循环和/或再次使用。
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