公开(公告)号：US20200165460A1

公开(公告)日：2020-05-28

申请号：US16604347

申请日：2018-04-17

Applicant: DSM IP Assets B.V.

Inventor： Carlo VERMEULEN ,  Michael Alphonsus Cornelis Johannes VAN DIJCK

IPC: C09D5/00 ,  C09D133/12 ,  C09D151/10 ,  C09D133/08 ,  C08K3/36

Abstract: The disclosure relates to a process to provide a substrate having improved anti-soiling properties. The disclosure also relates to an anti-soiling coating composition, and to a process of making an anti-soiling coating composition. Use of the coating composition to improve anti-soiling properties of a substrate.

公开(公告)号：US20190235133A1

公开(公告)日：2019-08-01

申请号：US16380766

申请日：2019-04-10

Applicant: DSM IP ASSETS B.V.

Inventor： Michael Alphonsus Cornelis Johannes VAN DIJCK ,  Hermanus Adrianus LANGERMANS ,  Jacobus Adriaan Antonius VERMEULEN

IPC: G02B1/111 ,  C09D133/08 ,  C09D5/02 ,  C09D133/12 ,  C09D133/14 ,  C09D5/00

CPC classification number: G02B1/111 ,  C09D5/006 ,  C09D5/022 ,  C09D133/08 ,  C09D133/12 ,  C09D133/14 ,  C08F220/14 ,  C08F220/34 ,  C08F2220/1875 ,  C08K5/5415

Abstract: The invention relates to a process of making an anti-reflective coating composition comprising the steps of 1) preparing an oil-in-water emulsion by mixing an apolar organic compound A; a cationic addition copolymer C as emulsion stabilizer; and aqueous medium of pH 2-6; at a mass ratio C/A of 0.1 to 2, to result in 1-50 mass % (based on emulsion) of emulsified droplets of average particle size 30-300 nm; and 2) providing an inorganic oxide shell layer to the emulsified droplets by adding to the emulsion obtained in step 1) at least one inorganic oxide precursor, to result in organic-inorganic core-shell nano-particles with mass ratio core/shell of from 0.2 to 25. An advantage of this process is that the dispersion of nano-particles obtained is stable under different conditions, and allows altering its concentration and solvent system, and addition of different binders and auxiliary components.The invention also relates to a coating composition as obtained with said process, and to a process of applying a porous anti-reflective coating on a substrate using such composition, and to the resulting coated substrate.

公开(公告)号：US20170368525A1

公开(公告)日：2017-12-28

申请号：US15700026

申请日：2017-09-08

Applicant: DSM IP ASSETS B.V.

Inventor： Nanning Joerg ARFSTEN ,  Roberto Arnoldus Dominicus Maria HABETS ,  Michael Alphonsus Cornelis Johannes VAN DIJCK

IPC: B01J13/12 ,  B01J13/18 ,  B05D3/02 ,  B05D5/06 ,  C01B33/143 ,  C01B33/145 ,  H01L31/0232 ,  H01L31/0216 ,  G02B1/111 ,  G02B1/11 ,  C09D7/12 ,  C09D5/00 ,  C08J3/12 ,  C03C17/00 ,  C01G25/02 ,  C01G23/047 ,  C01B33/149 ,  H01L31/0236

CPC classification number: B01J13/125 ,  B01J13/18 ,  B05D3/0254 ,  B05D5/061 ,  C01B33/143 ,  C01B33/145 ,  C01B33/149 ,  C01G23/047 ,  C01G25/02 ,  C01P2004/34 ,  C01P2004/64 ,  C03C17/007 ,  C03C2217/425 ,  C03C2217/732 ,  C08J3/128 ,  C09D5/006 ,  C09D7/67 ,  C09D7/70 ,  G02B1/11 ,  G02B1/111 ,  H01L31/02168 ,  H01L31/02325 ,  H01L31/02366 ,  Y02E10/50 ,  Y10T428/24997

Abstract: The invention relates to a method of making hybrid organic-inorganic core-shell nano-particles, comprising the steps of a) providing colloidal organic particles comprising a synthetic polyampholyte as a template; b) adding at least one inorganic oxide precursor; and c) forming a shell layer from the precursor on the template to result in core-shell nano-particles. With this method it is possible to make colloidal organic template particles having an average particle size in the range of 10 to 300 nm; which size can be controlled by the comonomer composition of the polyampholyte, and/or by selecting dispersion conditions.The invention also relates to organic-inorganic or hollow-inorganic core-shell nano-particles obtained with this method, to compositions comprising such nano-particles, to different uses of said nano-particles and compositions, and to products comprising or made from said nano-particles and compositions, including anti-reflective coatings and composite materials.

公开(公告)号：US20160291206A1

公开(公告)日：2016-10-06

申请号：US15036909

申请日：2014-11-24

Applicant: DSM IP ASSETS B.V.

Inventor： Michael Alphonsus Cornelis Johannes VAN DIJCK ,  Hermanus Adrianus LANGERMANS ,  Jacobus Adriaan Antonius VERMEULEN

IPC: G02B1/111 ,  C09D133/08 ,  C09D133/12 ,  C09D5/00 ,  C09D5/02

CPC classification number: G02B1/111 ,  C09D5/006 ,  C09D5/022 ,  C09D133/08 ,  C09D133/12 ,  C09D133/14 ,  C08F220/14 ,  C08F220/34 ,  C08F2220/1875 ,  C08K5/5415

Abstract: The invention relates to a process of making an anti-reflective coating composition comprising the steps of 1) preparing an oil-in-water emulsion by mixing an apolar organic compound A; a cationic addition copolymer C as emulsion stabilizer; and aqueous medium of pH 2-6; at a mass ratio C/A of 0.1 to 2, to result in 1-50 mass % (based on emulsion) of emulsified droplets of average particle size 30-300 nm; and 2) providing an inorganic oxide shell layer to the emulsified droplets by adding to the emulsion obtained in step 1) at least one inorganic oxide precursor, to result in organic-inorganic core-shell nano-particles with mass ratio core/shell of from 0.2 to 25. An advantage of this process is that the dispersion of nano-particles obtained is stable under different conditions, and allows altering its concentration and solvent system, and addition of different binders and auxiliary components. The invention also relates to a coating composition as obtained with said process, and to a process of applying a porous anti-reflective-coating on a substrate using such composition, and to the resulting coated substrate.

Abstract translation: 本发明涉及一种制备抗反射涂层组合物的方法，包括以下步骤：1）通过混合非极性有机化合物A制备水包油乳液; 阳离子加成共聚物C作为乳液稳定剂; 和pH2-6的水性介质; 质量比C / A为0.1〜2，得到平均粒径30〜300nm的乳化液滴的1-50质量％（基于乳液） 和2）通过向步骤1）获得的乳液中添加至少一种无机氧化物前体，使乳化液滴提供无机氧化物壳层，得到质量比核/壳的有机 - 无机核 - 壳纳米颗粒 该方法的优点是所获得的纳米颗粒的分散体在不同条件下是稳定的，并允许改变其浓度和溶剂体系，并添加不同的粘合剂和辅助组分。 本发明还涉及通过所述方法获得的涂料组合物，以及使用这种组合物在基材上施加多孔抗反射涂层的方法，以及所得涂覆的基材。