公开(公告)号：US07067186B2

公开(公告)日：2006-06-27

申请号：US10499120

申请日：2002-12-20

申请人： Dai Oguro ,  Takeo Hayashi ,  Masahiro Kurokawa ,  Tsuyoshi Ikeda ,  Takeshi Hirokane

发明人： Dai Oguro ,  Takeo Hayashi ,  Masahiro Kurokawa ,  Tsuyoshi Ikeda ,  Takeshi Hirokane

IPC分类号： C08L69/00 ,  C08L67/02

CPC分类号： C08L67/02 ,  C08G63/672 ,  C08K3/013 ,  C08L67/025 ,  C08L69/00 ,  C08L2666/18 ,  C08L2666/02

摘要： The invention provides a thermoplastic resin composition which is excellent in transparency, heat resistance, resistance to chemicals, and mechanical strength as well as moldability, printability, etc.The thermoplastic resin composition containing a polycarbonate resin in an amount of 2 to 99.5 wt. % and a polyester resin in an amount of 98 to 0.5 wt. %, wherein the polyester resin (B) contains diol units each having a cyclic acetal skeleton in an amount of 20 to 60 mol % with respect to total diol structural units.

摘要翻译： 本发明提供透明性，耐热性，耐化学品性，机械强度以及成型性，印刷性等优异的热塑性树脂组合物。含有2〜99.5重量％的聚碳酸酯树脂的热塑性树脂组合物。 ％的聚酯树脂和98〜0.5重量％的聚酯树脂。 ％，其中聚酯树脂（B）含有相对于二醇结构单元为20〜60摩尔％的环状缩醛骨架的二醇单元。

公开(公告)号：US06447859B2

公开(公告)日：2002-09-10

申请号：US09879100

申请日：2001-06-13

申请人： Dai Oguro ,  Koji Yamamoto ,  Takeo Hayashi ,  Takeshi Hirokane ,  Masahiro Kurokawa

发明人： Dai Oguro ,  Koji Yamamoto ,  Takeo Hayashi ,  Takeshi Hirokane ,  Masahiro Kurokawa

IPC分类号： B29D2200

CPC分类号： C08J9/141 ,  C08G63/672 ,  C08J2201/03 ,  C08J2367/02 ,  Y10T428/1352 ,  Y10T428/1376 ,  Y10T428/24

摘要： The polyester resin of the present invention is produced by polymerizing a monomer mixture comprising a glycol component containing 5 to 60 mol % of a spiroglycol represented by Formula I: and 30 to 95 mol % of ethylene glycol, and a dicarboxylic acid component containing 80 to 100 mol % of terephthalic acid and/or an ester thereof. The polyester resin has (1): an intrinsic viscosity of 0.4 to 1.5 dL/g, (2) a melt viscosity of 700 to 5,000 Pa·s, (3) a molecular weight distribution of 2.5 to 12.0; and (4) a glass transition temperature of 90° C. or higher and a cooling crystallization exotherm peak of 5 J/g or lower. The polyester resin of the present invention is excellent in heat resistance, transparency, mechanical properties, moldability and fabrication qualities and useful for producing shaped articles such as films, sheets, hollow containers and foamed products.

摘要翻译： 本发明的聚酯树脂通过使包含含有5〜60摩尔％的式I所示的螺旋糖的二醇成分和30〜95摩尔％的乙二醇的二醇成分和含有80〜 100摩尔％的对苯二甲酸和/或其酯。 聚酯树脂具有（1）：特性粘度为0.4〜1.5dL / g，（2）熔融粘度为700〜5000Pa·s，（3）分子量分布为2.5〜12.0; 和（4）玻璃化转变温度为90℃以上，冷却结晶放热峰为5J / g以下。 本发明的聚酯树脂的耐热性，透明性，机械性能，成型性和制造性能优异，可用于制造薄膜，片材，中空容器和发泡产品等成型制品。

公开(公告)号：US06740376B2

公开(公告)日：2004-05-25

申请号：US10153619

申请日：2002-05-24

申请人： Dai Oguro ,  Takeo Hayashi ,  Takeshi Hirokane ,  Masahiro Kurokawa

发明人： Dai Oguro ,  Takeo Hayashi ,  Takeshi Hirokane ,  Masahiro Kurokawa

IPC分类号： C08I7700

CPC分类号： C08L77/02 ,  C08L67/02 ,  C08L67/025 ,  C08L77/00 ,  C08L77/06 ,  Y10T428/1352 ,  C08L2666/14 ,  C08L2666/18 ,  C08L67/00

摘要： There is disclosed A polyester based resin composition (D) which comprises a polyamide resin (A) and a polyester resin (B), or a polyamide resin (A), a polyester resin (B) and a polyethylene terephthalate resin (C), characterized in that the polyester resin (B) is obtained by polycondensation of a dicarboxylic acid component containing 0.5 to 60 mol % of a dicarboxylic acid having a cyclic acetal skeleton and/or a diol component containing 0.5 to 60 mol % of a diol having a cyclic acetal skeleton, and that the blending proportions of the polyamide resin (A), the polyester resin (B) and the polyethylene terephthalate resin (C) are each in the range of 1 to 99% by weight, 1 to 99% by weight and 0 to 98% by weight, respectively on the basis of total sum weight of the components (A), (B) and (C). There is further disclosed a molded product (film, sheet, thin wall hollow container, etc.). The above polyester based resin composition and a product molded therefrom are each excellent in transparency color tone, gas barrier properties, pinhole resistance and mechanical performance.

摘要翻译： 公开了包含聚酰胺树脂（A）和聚酯树脂（B）或聚酰胺树脂（A），聚酯树脂（B）和聚对苯二甲酸乙二醇酯树脂（C）的聚酯类树脂组合物（D） 其特征在于，所述聚酯树脂（B）通过含有0.5〜60摩尔％的具有环状缩醛骨架的二羧酸的二羧酸成分和/或含有0.5〜60摩尔％的二醇的二醇的缩聚得到，所述二醇具有 环状缩醛骨架，聚酰胺树脂（A），聚酯树脂（B）和聚对苯二甲酸乙二醇酯树脂（C）的配合比例分别为1〜99重量％，1〜99重量％ （A），（B）和（C）的总和重量分别为0〜98重量％。 进一步公开了成型品（膜，片，薄壁中空容器等）。 上述聚酯类树脂组合物和由其模塑的产品具有优异的透明色调，阻气性，针孔性和机械性能。

公开(公告)号：US20050075466A1

公开(公告)日：2005-04-07

申请号：US10499120

申请日：2002-12-20

申请人： Dai Oguro ,  Takeo Hayashi ,  Masahiro Kurokawa ,  Tsuyoshi Ikeda ,  Takeshi Hironake

发明人： Dai Oguro ,  Takeo Hayashi ,  Masahiro Kurokawa ,  Tsuyoshi Ikeda ,  Takeshi Hironake

IPC分类号： C08G63/672 ,  C08J5/18 ,  C08K3/00 ,  C08L67/02 ,  C08L69/00

CPC分类号： C08L67/02 ,  C08G63/672 ,  C08K3/013 ,  C08L67/025 ,  C08L69/00 ,  C08L2666/18 ,  C08L2666/02

摘要： The invention provides a thermoplastic resin composition which is excellent in transparency, heat resistance, resistance to chemicals, and mechanical strength as well as moldability, printability, etc. The thermoplastic resin composition containing a polycarbonate resin in an amount of 2 to 99.5 wt. % and a polyester resin in an amount of 98 to 0.5 wt. %, wherein the polyester resin (B) contains diol units each having a cyclic acetal skeleton in an amount of 20 to 60 mol % with respect to total diol structural units.

摘要翻译： 本发明提供透明性，耐热性，耐化学品性，机械强度以及成型性，印刷性等优异的热塑性树脂组合物。含有2〜99.5重量％的聚碳酸酯树脂的热塑性树脂组合物。 ％的聚酯树脂和98〜0.5重量％的聚酯树脂。 ％，其中聚酯树脂（B）含有相对于二醇结构单元为20〜60摩尔％的环状缩醛骨架的二醇单元。

公开(公告)号：US08846957B2

公开(公告)日：2014-09-30

申请号：US13143612

申请日：2010-01-07

申请人： Takuya Minezaki ,  Takeshi Hirokane ,  Dai Oguro

发明人： Takuya Minezaki ,  Takeshi Hirokane ,  Dai Oguro

IPC分类号： C07D319/06

CPC分类号： C07D319/06

摘要： Disclosed is a glycol compound which is useful as a raw material and an intermediate for synthetic resins, additives for synthetic resins, medicines, cosmetics, food additives, surfactants and the like, further disclosed is a method for producing the compound.The above glycol compound is represented by the following Formula (1): wherein A represents a divalent linkage group comprising a condensed aromatic ring selected from the group consisting of naphthalene, anthracene, phenanthrene and pyrene; R represents an alkyl group having 1 to 12 carbon atoms, a substituted or unsubstituted aryl group having 6 to 10 carbon atoms or a halogen atom; n represents an integer of 0 to 4; and when n represents an integer of 2 to 4, plural R may be the same or different from each other.

摘要翻译： 公开了可用作原料的二醇化合物和合成树脂的中间体，合成树脂的添加剂，药物，化妆品，食品添加剂，表面活性剂等，进一步公开了该化合物的制造方法。 上述二醇化合物由下式（1）表示：其中A表示包含选自萘，蒽，菲和芘的稠合芳环的二价连接基团; R表示碳原子数1〜12的烷基，取代或未取代的碳原子数6〜10的芳基或卤素原子; n表示0〜4的整数， 当n表示2〜4的整数时，多个R可以相同也可以不同。

公开(公告)号：US20110275840A1

公开(公告)日：2011-11-10

申请号：US13143612

申请日：2010-01-07

申请人： Takuya Minezaki ,  Takeshi Hirokane ,  Dai Oguro

发明人： Takuya Minezaki ,  Takeshi Hirokane ,  Dai Oguro

IPC分类号： C07D319/06

CPC分类号： C07D319/06

摘要： Disclosed is a glycol compound which is useful as a raw material and an intermediate for synthetic resins, additives for synthetic resins, medicines, cosmetics, food additives, surfactants and the like, further disclosed is a method for producing the compound.The above glycol compound is represented by the following Formula (1): wherein A represents a divalent linkage group comprising a condensed aromatic ring selected from the group consisting of naphthalene, anthracene, phenanthrene and pyrene; R represents an alkyl group having 1 to 12 carbon atoms, a substituted or unsubstituted aryl group having 6 to 10 carbon atoms or a halogen atom; n represents an integer of 0 to 4; and when n represents an integer of 2 to 4, plural R may be the same or different from each other.

摘要翻译： 公开了可用作原料的二醇化合物和合成树脂的中间体，合成树脂的添加剂，药物，化妆品，食品添加剂，表面活性剂等，进一步公开了该化合物的制造方法。 上述二醇化合物由下式（1）表示：其中A表示包含选自萘，蒽，菲和芘的稠合芳环的二价连接基团; R表示碳原子数1〜12的烷基，取代或未取代的碳原子数6〜10的芳基或卤素原子; n表示0〜4的整数， 当n表示2〜4的整数时，多个R可以相同也可以不同。

公开(公告)号：US20110269976A1

公开(公告)日：2011-11-03

申请号：US13143677

申请日：2010-01-07

申请人： Takuya Minezaki ,  Takeshi Hirokane ,  Dai Oguro

发明人： Takuya Minezaki ,  Takeshi Hirokane ,  Dai Oguro

IPC分类号： C07D319/06

CPC分类号： C07D319/06 ,  G02B1/041

摘要： Disclosed is a glycol compound which is useful as a raw material and an intermediate for synthetic resins, additives for synthetic resins, medicines, cosmetics, food additives, surfactants and the like, further disclosed is a method for producing the compound.The glycol compound is represented by the following Formula (1): wherein R represents an alkyl group having 1 to 12 carbon atoms, a substituted or unsubstituted aryl group having 6 to 10 carbon atoms or a halogen atom; n represents an integer of 1 to 4; and when n represents an integer of 2 to 4, plural R may be the same or different from each other.

摘要翻译： 公开了可用作原料的二醇化合物和合成树脂的中间体，合成树脂的添加剂，药物，化妆品，食品添加剂，表面活性剂等，进一步公开了该化合物的制造方法。 二醇化合物由下式（1）表示：其中R表示碳原子数1〜12的烷基，取代或未取代的碳原子数6〜10的芳基或卤素原子; n表示1〜4的整数， 当n表示2〜4的整数时，多个R可以相同也可以不同。

公开(公告)号：US08674054B2

公开(公告)日：2014-03-18

申请号：US13519694

申请日：2010-12-24

申请人： Takuya Minezaki ,  Takeshi Hirokane ,  Dai Oguro

发明人： Takuya Minezaki ,  Takeshi Hirokane ,  Dai Oguro

IPC分类号： C08G63/181 ,  C07D319/04

CPC分类号： G02B1/041 ,  C08G63/181 ,  C08G63/672 ,  C08K5/1575 ,  C08L67/02 ,  C08L67/03

摘要： A polyester resin having a diol unit containing a unit derived from ethylene glycol and a unit derived from a diol represented by the following formula (I), and a dicarboxylic acid unit containing a unit derived from an aromatic dicarboxylic acid in an amount of 50 mol % or more; wherein the entire diol unit contains the unit derived from ethylene glycol in an amount of 40 to 99 mol %, and the unit derived from a diol represented by formula (I) in an amount of 1 to 60 mol %: wherein A represents an aromatic ring selected from the group consisting of benzene, naphthalene, anthracene, phenanthrene and pyrene; R1 represents a C1 to C12 alkyl group, a substituted or unsubstituted C6 to C12 aryl group or a halogen atom; n represents an integer of 0 to 4; and when plural R1s are present, R1s may be the same as or different from each other.

摘要翻译： 具有含有来自乙二醇的单元的二醇单元和由下式（I）表示的二醇衍生的单元的二醇单元的聚酯树脂和含有来自芳族二羧酸的单元的二羧酸单元的量为50摩尔 ％ 或者更多; 其中，全部二醇单元含有40〜99摩尔％的来源于乙二醇的单元，和由式（I）表示的二醇衍生的单元的含量为1〜60摩尔％：其中，A表示芳香族 选自苯，萘，蒽，菲和芘的环; R1表示C1〜C12烷基，取代或未取代的C6〜C12芳基或卤素原子; n表示0〜4的整数， 并且当存在多个R 1时，R 1可以彼此相同或不同。

公开(公告)号：US08859787B2

公开(公告)日：2014-10-14

申请号：US13143677

申请日：2010-01-07

申请人： Takuya Minezaki ,  Takeshi Hirokane ,  Dai Oguro

发明人： Takuya Minezaki ,  Takeshi Hirokane ,  Dai Oguro

IPC分类号： C07D319/06 ,  G02B1/04

CPC分类号： C07D319/06 ,  G02B1/041

摘要： Disclosed is a glycol compound which is useful as a raw material and an intermediate for synthetic resins, additives for synthetic resins, medicines, cosmetics, food additives, surfactants and the like, further disclosed is a method for producing the compound.The glycol compound is represented by the following Formula (1): wherein R represents an alkyl group having 1 to 12 carbon atoms, a substituted or unsubstituted aryl group having 6 to 10 carbon atoms or a halogen atom; n represents an integer of 1 to 4; and when n represents an integer of 2 to 4, plural R may be the same or different from each other.

摘要翻译： 公开了可用作原料的二醇化合物和合成树脂的中间体，合成树脂的添加剂，药物，化妆品，食品添加剂，表面活性剂等，进一步公开了该化合物的制造方法。 二醇化合物由下式（1）表示：其中R表示碳原子数1〜12的烷基，取代或未取代的碳原子数6〜10的芳基或卤素原子; n表示1〜4的整数， 当n表示2〜4的整数时，多个R可以相同也可以不同。

公开(公告)号：US20120289676A1

公开(公告)日：2012-11-15

申请号：US13519694

申请日：2010-12-24

申请人： Takuya Minezaki ,  Takeshi Hirokane ,  Dai Oguro

发明人： Takuya Minezaki ,  Takeshi Hirokane ,  Dai Oguro

IPC分类号： C08G63/672 ,  B29D11/00

CPC分类号： G02B1/041 ,  C08G63/181 ,  C08G63/672 ,  C08K5/1575 ,  C08L67/02 ,  C08L67/03

摘要： A polyester resin having a diol unit containing a unit derived from ethylene glycol and a unit derived from a diol represented by the following formula (I), and a dicarboxylic acid unit containing a unit derived from an aromatic dicarboxylic acid in an amount of 50 mol % or more; wherein the entire diol unit contains the unit derived from ethylene glycol in an amount of 40 to 99 mol %, and the unit derived from a diol represented by formula (I) in an amount of 1 to 60 mol %: wherein A represents an aromatic ring selected from the group consisting of benzene, naphthalene, anthracene, phenanthrene and pyrene; R1 represents a C1 to C12 alkyl group, a substituted or unsubstituted C6 to C12 aryl group or a halogen atom; n represents an integer of 0 to 4; and when plural R1s are present, R1s may be the same as or different from each other.

摘要翻译： 具有含有来自乙二醇的单元的二醇单元和由下式（I）表示的二醇衍生的单元的二醇单元的聚酯树脂和含有来自芳族二羧酸的单元的二羧酸单元的量为50摩尔 ％ 或者更多; 其中，全部二醇单元含有40〜99摩尔％的来源于乙二醇的单元，和由式（I）表示的二醇衍生的单元的含量为1〜60摩尔％：其中，A表示芳香族 选自苯，萘，蒽，菲和芘的环; R1表示C1〜C12烷基，取代或未取代的C6〜C12芳基或卤素原子; n表示0〜4的整数， 并且当存在多个R 1时，R 1可以彼此相同或不同。