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    Functionalized polymers, articles prepared therefrom, and methods for making the same
    2.
    发明授权
    Functionalized polymers, articles prepared therefrom, and methods for making the same 有权
    官能化聚合物，由其制备的制品及其制备方法

    公开(公告)号：US09000099B2

    公开(公告)日：2015-04-07

    申请号：US12669194

    申请日：2008-07-10

    申请人： William J. Harris ,  John D. Weaver ,  Nelson G. Rondan ,  Drew A. Davidock

    发明人： William J. Harris ,  John D. Weaver ,  Nelson G. Rondan ,  Drew A. Davidock

    IPC分类号： C08L53/00 ,  C08F255/02 ,  C08F255/04 ,  C08L51/06

    CPC分类号： C08F255/02 ,  C08F255/04 ,  C08L51/06 ,  C08F226/06 ,  C08F222/06 ,  C08L2666/02 ,  C08L2666/04

    摘要： The invention provides compositions comprising at least one propylene-based polymer, at least one peroxide and at least one coagent. In a preferred example, a composition comprising at least one propylene-based polymer, at least one peroxide, at least one grafting agent, and at least one coagent, and wherein the at least one coagent has a substituted carbon-carbon double bond structure selected from the group consisting of structures (I), (II), (III), (IV) and (V) as follows, including cis and trans isomers wherein D1, D2, D3 and D4 are each, independently, one of the following: (a) a hydrocarbon substituent containing a heteroatom with a nonbonding pair of electrons, and where the heteroatom with the nonbonding pair is directly attached to the carbon-carbon double bond, or (b) a hydrocarbon substituent containing a carbon-carbon pi bonding pair, and where the first carbon of the carbon-carbon pi bonding pair is directly bonded to the carbon-carbon double bond; and wherein the R1, R2 and R3 are each, independently, H, a hydrocarbon substituent, or a substituted hydrocarbon substituent; and wherein R1, R2 and R3, each, independently, does not have the same chemical structure as D1, D2, D3 or D4; and wherein the molar ratio of the “coagent(s)” to “free radicals formed from the peroxide(s)” is from 0.5:1 to 5:1; and wherein the coagent selected from structures (I)-(V) does not contain only one phenyl group, or does not contain only one furyl group.

    摘要翻译： 本发明提供了包含至少一种基于丙烯的聚合物，至少一种过氧化物和至少一种助剂的组合物。 在优选实例中，包含至少一种基于丙烯的聚合物，至少一种过氧化物，至少一种接枝剂和至少一种助剂的组合物，并且其中所述至少一种助剂具有取代的碳 - 碳双键结构 包括由以下结构（I），（II），（III），（IV）和（V）组成的组，包括顺式和反式异构体，其中D1，D2，D3和D4各自独立地为以下之一 （a）含有具有非键合电子对的杂原子的烃取代基，其中与非键合对的杂原子直接连接到碳 - 碳双键上，或（b）含有碳 - 碳键的烃取代基 并且其中碳 - 碳π键合对的第一个碳直接键合到碳 - 碳双键上; 并且其中R 1，R 2和R 3各自独立地为H，烃取代基或取代的烃取代基; 并且其中R1，R2和R3各自独立地不具有与D1，D2，D3或D4相同的化学结构; 并且其中“助剂”与“由过氧化物形成的自由基”的摩尔比为0.5:1至5:1; 并且其中选自结构（I） - （V）的助剂不仅含有一个苯基，或不含有一个呋喃基。

    FUNCTIONALIZED POLYMERS, ARTICLES PREPARED THEREFROM, AND METHODS FOR MAKING THE SAME
    5.
    发明申请
    FUNCTIONALIZED POLYMERS, ARTICLES PREPARED THEREFROM, AND METHODS FOR MAKING THE SAME 有权
    官能化聚合物，制备的制品及其制备方法

    公开(公告)号：US20100168343A1

    公开(公告)日：2010-07-01

    申请号：US12669194

    申请日：2008-07-10

    申请人： William J. Harris ,  John D. Weaver ,  Nelson G. Rondan ,  Drew A. Davidock

    发明人： William J. Harris ,  John D. Weaver ,  Nelson G. Rondan ,  Drew A. Davidock

    IPC分类号： C08L23/14 ,  C08L23/10

    CPC分类号： C08F255/02 ,  C08F255/04 ,  C08L51/06 ,  C08F226/06 ,  C08F222/06 ,  C08L2666/02 ,  C08L2666/04

    摘要： The invention provides compositions comprising at least one propylene-based polymer, at least one peroxide and at least one coagent. In a preferred example, a composition comprising at least one propylene-based polymer, at least one peroxide, at least one grafting agent, and at least one coagent, and wherein the at least one coagent has a substituted carbon-carbon double bond structure selected from the group consisting of structures (I), (II), (III), (IV) and (V) as follows, including cis and trans isomers wherein D1, D2, D3 and D4 are each, independently, one of the following: (a) a hydrocarbon substituent containing a heteroatom with a nonbonding pair of electrons, and where the heteroatom with the nonbonding pair is directly attached to the carbon-carbon double bond, or (b) a hydrocarbon substituent containing a carbon-carbon pi bonding pair, and where the first carbon of the carbon-carbon pi bonding pair is directly bonded to the carbon-carbon double bond; and wherein the R1, R2 and R3 are each, independently, H, a hydrocarbon substituent, or a substituted hydrocarbon substituent; and wherein R1, R2 and R3, each, independently, does not have the same chemical structure as D1, D2, D3 or D4; and wherein the molar ratio of the “coagent(s)” to “free radicals formed from the peroxide(s)” is from 0.5:1 to 5:1; and wherein the coagent selected from structures (I)-(V) does not contain only one phenyl group, or does not contain only one furyl group.

    摘要翻译： 本发明提供了包含至少一种基于丙烯的聚合物，至少一种过氧化物和至少一种助剂的组合物。 在优选实例中，包含至少一种基于丙烯的聚合物，至少一种过氧化物，至少一种接枝剂和至少一种助剂的组合物，并且其中所述至少一种助剂具有取代的碳 - 碳双键结构 包括由以下结构（I），（II），（III），（IV）和（V）组成的组，包括顺式和反式异构体，其中D1，D2，D3和D4各自独立地为以下之一 （a）含有具有非键合电子对的杂原子的烃取代基，其中与非键合对的杂原子直接连接到碳 - 碳双键上，或（b）含有碳 - 碳键的烃取代基 并且其中碳 - 碳π键合对的第一个碳直接键合到碳 - 碳双键上; 并且其中R 1，R 2和R 3各自独立地为H，烃取代基或取代的烃取代基; 并且其中R1，R2和R3各自独立地不具有与D1，D2，D3或D4相同的化学结构; 并且其中“助剂”与“由过氧化物形成的自由基”的摩尔比为0.5:1至5:1; 并且其中选自结构（I） - （V）的助剂不仅含有一个苯基，或不含有一个呋喃基。