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    METHOD FOR CONTINUOUS SYNTHESIS OF METAL OXIDE POWDERS
    7.
    发明申请
    METHOD FOR CONTINUOUS SYNTHESIS OF METAL OXIDE POWDERS 有权
    用于连续合成金属氧化物粉末的方法

    公开(公告)号：US20140363365A1

    公开(公告)日：2014-12-11

    申请号：US14296643

    申请日：2014-06-05

    申请人： David A. Berry ,  Daniel J. Haynes ,  Dushyant Shekhawat ,  Mark W. Smith

    发明人： David A. Berry ,  Daniel J. Haynes ,  Dushyant Shekhawat ,  Mark W. Smith

    IPC分类号： C01B13/32

    CPC分类号： C01B13/34 ,  C01P2004/03 ,  C01P2004/32 ,  C01P2004/62

    摘要： A method for the rapid and continuous production of crystalline mixed-metal oxides from a precursor solution comprised of a polymerizing agent, chelated metal ions, and a solvent. The method discharges solution droplets of less than 500 μm diameter using an atomizing or spray-type process into a reactor having multiple temperature zones. Rapid evaporation occurs in a first zone, followed by mixed-metal organic foam formation in a second zone, followed by amorphous and partially crystalline oxide precursor formation in a third zone, followed by formation of the substantially crystalline mixed-metal oxide in a fourth zone. The method operates in a continuous rather than batch manner and the use of small droplets as the starting material for the temperature-based process allows relatively high temperature processing. In a particular embodiment, the first zone operates at 100-300° C., the second zone operates at 300-700° C., and the third operates at 700-1000° C., and fourth zone operates at at least 700° C. The resulting crystalline mixed-metal oxides display a high degree of crystallinity and sphericity with typical diameters on the order of 50 μm or less.

    摘要翻译： 一种从由聚合剂，螯合金属离子和溶剂组成的前体溶液中快速和连续地生产结晶混合金属氧化物的方法。 该方法使用雾化或喷雾式方法将小于500μm直径的溶液液滴放入具有多个温度区的反应器中。 在第一区域中发生快速蒸发，随后在第二区域中形成混合金属有机泡沫，随后在第三区域中形成无定形和部分结晶的氧化物前体，随后在第四区域中形成基本上结晶的混合金属氧化物 。 该方法以连续而不是间歇的方式操作，并且使用小液滴作为基于温度的方法的起始材料允许相对较高的温度处理。 在特定实施例中，第一区域在100-300℃下操作，第二区域工作在300-700℃，第三区域在700-1000℃下操作，第四区域在至少700° 所得到的结晶混合金属氧化物显示出高度的结晶度和球形度，典型直径为50μm以下。

    Method for continuous synthesis of metal oxide powders
    9.
    发明授权
    Method for continuous synthesis of metal oxide powders 有权
    连续合成金属氧化物粉末的方法

    公开(公告)号：US09126833B2

    公开(公告)日：2015-09-08

    申请号：US14296643

    申请日：2014-06-05

    申请人： David A. Berry ,  Daniel J. Haynes ,  Dushyant Shekhawat ,  Mark W. Smith

    发明人： David A. Berry ,  Daniel J. Haynes ,  Dushyant Shekhawat ,  Mark W. Smith

    IPC分类号： C01B13/00 ,  C01B13/34

    CPC分类号： C01B13/34 ,  C01P2004/03 ,  C01P2004/32 ,  C01P2004/62

    摘要： A method for the rapid and continuous production of crystalline mixed-metal oxides from a precursor solution comprised of a polymerizing agent, chelated metal ions, and a solvent. The method discharges solution droplets of less than 500 μm diameter using an atomizing or spray-type process into a reactor having multiple temperature zones. Rapid evaporation occurs in a first zone, followed by mixed-metal organic foam formation in a second zone, followed by amorphous and partially crystalline oxide precursor formation in a third zone, followed by formation of the substantially crystalline mixed-metal oxide in a fourth zone. The method operates in a continuous rather than batch manner and the use of small droplets as the starting material for the temperature-based process allows relatively high temperature processing. In a particular embodiment, the first zone operates at 100-300° C., the second zone operates at 300-700° C., and the third operates at 700-1000° C., and fourth zone operates at at least 700° C. The resulting crystalline mixed-metal oxides display a high degree of crystallinity and sphericity with typical diameters on the order of 50 μm or less.

    摘要翻译： 一种从由聚合剂，螯合金属离子和溶剂组成的前体溶液中快速和连续地生产结晶混合金属氧化物的方法。 该方法使用雾化或喷雾式方法将小于500μm直径的溶液液滴放入具有多个温度区的反应器中。 在第一区域中发生快速蒸发，随后在第二区域中形成混合金属有机泡沫，随后在第三区域中形成无定形和部分结晶的氧化物前体，随后在第四区域中形成基本上结晶的混合金属氧化物 。 该方法以连续而不是间歇的方式操作，并且使用小液滴作为基于温度的方法的起始材料允许相对较高的温度处理。 在特定实施例中，第一区域在100-300℃下操作，第二区域工作在300-700℃，第三区域在700-1000℃下操作，第四区域在至少700° 所得到的结晶混合金属氧化物显示出高度的结晶度和球形度，典型直径为50μm以下。

    Production of methane-rich syngas from hydrocarbon fuels using multi-functional catalyst/capture agent
    10.
    发明授权
    Production of methane-rich syngas from hydrocarbon fuels using multi-functional catalyst/capture agent 有权
    使用多功能催化剂/捕获剂从烃燃料生产富甲烷的合成气

    公开(公告)号：US08920526B1

    公开(公告)日：2014-12-30

    申请号：US13232018

    申请日：2011-09-14

    申请人： Nicholas S. Siefert ,  Dushyant Shekhawat ,  David A. Berry ,  Wayne A. Surdoval

    发明人： Nicholas S. Siefert ,  Dushyant Shekhawat ,  David A. Berry ,  Wayne A. Surdoval

    IPC分类号： C01B3/36

    CPC分类号： C01B3/348 ,  C01B2203/0233 ,  C01D7/07 ,  C10J3/57 ,  C10J2300/0986 ,  C10J2300/1653 ,  C10K3/04 ,  Y02E20/18

    摘要： The disclosure provides a gasification process for the production of a methane-rich syngas at temperatures exceeding 700° C. through the use of an alkali hydroxide MOH, using a gasification mixture comprised of at least 0.25 moles and less than 2 moles of water for each mole of carbon, and at least 0.15 moles and less than 2 moles of alkali hydroxide MOH for each mole of carbon. These relative amounts allow the production of a methane-rich syngas at temperatures exceeding 700° C. by enabling a series of reactions which generate H2 and CH4, and mitigate the reforming of methane. The process provides a methane-rich syngas comprised of roughly 20% (dry molar percentage) CH4 at temperatures above 700° C., and may effectively operate within an IGFC cycle at reactor temperatures between 700-900° C. and pressures in excess of 10 atmospheres.

    摘要翻译： 本公开提供了一种用于通过使用碱金属氢氧化物MOH在超过700℃的温度下生产甲烷富集合成气的气化方法，其使用由至少0.25摩尔和少于2摩尔水组成的气化混合物 摩尔碳，对于每摩尔碳，至少0.15摩尔和小于2摩尔碱金属氢氧化物MOH。 这些相对量允许在超过700℃的温度下生产富含甲烷的合成气，通过实现一系列产生H 2和CH 4的反应并减轻甲烷的重整。 该方法提供了在高于700℃的温度下由大约20％（干摩尔百分数）CH 4组成的富含甲烷的合成气，并且可以在反应器温度在700-900℃之间的IGFC循环内有效地运行，并且压力超过 10个大气压。